Preparation and Photocatalytic Properties of Metal-Doped ZnO Nanofilms Grown on Graphene-Coated Flexible Substrates

A series of metal element (Al, Fe, Mg and Ni)-doped ZnO (M-ZnO) photocatalysts have been successfully synthesized on graphene-coated polyethylene terephthalate (GPET) flexible substrate via the hydrothermal method. The effects of doped metals in ZnO were also studied on the crystal structure, morpho...

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Main Authors: Ping Rong, Shuai Ren, Jianchao Jiang, Qi Yu, Liyun Jiang, Yonghong Zhang
Format: Article
Language:English
Published: MDPI AG 2020-08-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/16/3589
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author Ping Rong
Shuai Ren
Jianchao Jiang
Qi Yu
Liyun Jiang
Yonghong Zhang
author_facet Ping Rong
Shuai Ren
Jianchao Jiang
Qi Yu
Liyun Jiang
Yonghong Zhang
author_sort Ping Rong
collection DOAJ
description A series of metal element (Al, Fe, Mg and Ni)-doped ZnO (M-ZnO) photocatalysts have been successfully synthesized on graphene-coated polyethylene terephthalate (GPET) flexible substrate via the hydrothermal method. The effects of doped metals in ZnO were also studied on the crystal structure, morphology and photocatalytic performance. The photocatalytic experiment results indicated that, compared with Al-, Mg- and Fe-ZnO/GPET photocatalysts under ultraviolet (UV) light irradiation, Ni-ZnO/GPET had better photocatalytic activity, and the degradation rate of methylene blue (MB) was 81.17%. Meanwhile, the mechanism of enhancing the photocatalytic activity of metal element-doped ZnO is also discussed. It is concluded that, after doping with metal elements, electrons and holes are prevented from recombination by trapping electrons of the ZnO/GPET conductive band, thereby improving the photocatalytic activity.
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spelling doaj.art-2d10aa3bd015414fac2d499bbefc0aa62023-11-20T10:07:26ZengMDPI AGMaterials1996-19442020-08-011316358910.3390/ma13163589Preparation and Photocatalytic Properties of Metal-Doped ZnO Nanofilms Grown on Graphene-Coated Flexible SubstratesPing Rong0Shuai Ren1Jianchao Jiang2Qi Yu3Liyun Jiang4Yonghong Zhang5School of Materials Science and Engineering, Institute of Graphene at Shaanxi Key Laboratory of Catalysis, Shaanxi University of Technology, Hanzhong 723001, ChinaSchool of Materials Science and Engineering, Institute of Graphene at Shaanxi Key Laboratory of Catalysis, Shaanxi University of Technology, Hanzhong 723001, ChinaSchool of Materials Science and Engineering, Institute of Graphene at Shaanxi Key Laboratory of Catalysis, Shaanxi University of Technology, Hanzhong 723001, ChinaSchool of Materials Science and Engineering, Institute of Graphene at Shaanxi Key Laboratory of Catalysis, Shaanxi University of Technology, Hanzhong 723001, ChinaSchool of Physics and Telecommunication Engineering, Shaanxi University of Technology, Hanzhong 723001, ChinaSchool of Materials Science and Engineering, Institute of Graphene at Shaanxi Key Laboratory of Catalysis, Shaanxi University of Technology, Hanzhong 723001, ChinaA series of metal element (Al, Fe, Mg and Ni)-doped ZnO (M-ZnO) photocatalysts have been successfully synthesized on graphene-coated polyethylene terephthalate (GPET) flexible substrate via the hydrothermal method. The effects of doped metals in ZnO were also studied on the crystal structure, morphology and photocatalytic performance. The photocatalytic experiment results indicated that, compared with Al-, Mg- and Fe-ZnO/GPET photocatalysts under ultraviolet (UV) light irradiation, Ni-ZnO/GPET had better photocatalytic activity, and the degradation rate of methylene blue (MB) was 81.17%. Meanwhile, the mechanism of enhancing the photocatalytic activity of metal element-doped ZnO is also discussed. It is concluded that, after doping with metal elements, electrons and holes are prevented from recombination by trapping electrons of the ZnO/GPET conductive band, thereby improving the photocatalytic activity.https://www.mdpi.com/1996-1944/13/16/3589ZnOphotocatalyticdopedgraphenenanofilms
spellingShingle Ping Rong
Shuai Ren
Jianchao Jiang
Qi Yu
Liyun Jiang
Yonghong Zhang
Preparation and Photocatalytic Properties of Metal-Doped ZnO Nanofilms Grown on Graphene-Coated Flexible Substrates
Materials
ZnO
photocatalytic
doped
graphene
nanofilms
title Preparation and Photocatalytic Properties of Metal-Doped ZnO Nanofilms Grown on Graphene-Coated Flexible Substrates
title_full Preparation and Photocatalytic Properties of Metal-Doped ZnO Nanofilms Grown on Graphene-Coated Flexible Substrates
title_fullStr Preparation and Photocatalytic Properties of Metal-Doped ZnO Nanofilms Grown on Graphene-Coated Flexible Substrates
title_full_unstemmed Preparation and Photocatalytic Properties of Metal-Doped ZnO Nanofilms Grown on Graphene-Coated Flexible Substrates
title_short Preparation and Photocatalytic Properties of Metal-Doped ZnO Nanofilms Grown on Graphene-Coated Flexible Substrates
title_sort preparation and photocatalytic properties of metal doped zno nanofilms grown on graphene coated flexible substrates
topic ZnO
photocatalytic
doped
graphene
nanofilms
url https://www.mdpi.com/1996-1944/13/16/3589
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