Serpentinites of Different Tectonic Origin in an Exhumed Subduction Complex (New Caledonia, SW Pacific)

Abstract Owing to the importance of serpentinites for planetary geochemical and geodynamic processes, there has been much work discerning the origins of their parent rocks, including distinguishing between serpentinites derived from a subducting plate versus overlying mantle in exhumed subduction co...

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Main Authors: Natalie H. Raia, Donna L. Whitney, Christian Teyssier, Stéphane Lesimple
Format: Article
Language:English
Published: Wiley 2022-08-01
Series:Geochemistry, Geophysics, Geosystems
Subjects:
Online Access:https://doi.org/10.1029/2022GC010395
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author Natalie H. Raia
Donna L. Whitney
Christian Teyssier
Stéphane Lesimple
author_facet Natalie H. Raia
Donna L. Whitney
Christian Teyssier
Stéphane Lesimple
author_sort Natalie H. Raia
collection DOAJ
description Abstract Owing to the importance of serpentinites for planetary geochemical and geodynamic processes, there has been much work discerning the origins of their parent rocks, including distinguishing between serpentinites derived from a subducting plate versus overlying mantle in exhumed subduction complexes. The island of New Caledonia (SW Pacific Ocean) provides a rare window into Cenozoic Pacific subduction processes. The island is unique in exposing both an exceptionally preserved high‐pressure, low‐temperature subduction complex and one of the largest supra‐subduction zone ophiolites in the world. Previous studies disagree on the origin of serpentinites in the subduction complex. In this study, we analyze 23 serpentinites from this complex for whole‐rock major and trace element geochemistry and stable isotope (δD, δ18O) compositions. Our data reveal two distinct groups of serpentinites: Group I samples in the northern portion of the complex are pervasively serpentinized, and exhibit enriched heavy rare earth element (REE) compositions and δ18O values between +6.7‰ and +10.2‰. In contrast, Group II serpentinites in the south preserve relict orthopyroxene and olivine, and show depleted trace element compositions and comparatively lower δ18O values between +5.1‰ and +8.0‰. We interpret Group I serpentinites to derive from downgoing plate mantle, whereas Group II serpentinites derive from overlying mantle wedge, exhibiting remarkable similarity to the REE geochemistry of the structurally overlying New Caledonia ophiolite. Our results establish the subduction complex in New Caledonia as an unusual natural record of the entrainment and exhumation of mantle from both the overlying mantle wedge and the downgoing plate in an oceanic subduction zone.
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spelling doaj.art-2d231bd0db9d4843a4053dcde4057bf32023-11-03T16:55:34ZengWileyGeochemistry, Geophysics, Geosystems1525-20272022-08-01238n/an/a10.1029/2022GC010395Serpentinites of Different Tectonic Origin in an Exhumed Subduction Complex (New Caledonia, SW Pacific)Natalie H. Raia0Donna L. Whitney1Christian Teyssier2Stéphane Lesimple3Department of Earth & Environmental Sciences University of Minnesota Minneapolis MN USADepartment of Earth & Environmental Sciences University of Minnesota Minneapolis MN USADepartment of Earth & Environmental Sciences University of Minnesota Minneapolis MN USAService Géologique de la Nouvelle‐Calédonie Direction de l’Industrie, des Mines et de l’Energie Nouméa New CaledoniaAbstract Owing to the importance of serpentinites for planetary geochemical and geodynamic processes, there has been much work discerning the origins of their parent rocks, including distinguishing between serpentinites derived from a subducting plate versus overlying mantle in exhumed subduction complexes. The island of New Caledonia (SW Pacific Ocean) provides a rare window into Cenozoic Pacific subduction processes. The island is unique in exposing both an exceptionally preserved high‐pressure, low‐temperature subduction complex and one of the largest supra‐subduction zone ophiolites in the world. Previous studies disagree on the origin of serpentinites in the subduction complex. In this study, we analyze 23 serpentinites from this complex for whole‐rock major and trace element geochemistry and stable isotope (δD, δ18O) compositions. Our data reveal two distinct groups of serpentinites: Group I samples in the northern portion of the complex are pervasively serpentinized, and exhibit enriched heavy rare earth element (REE) compositions and δ18O values between +6.7‰ and +10.2‰. In contrast, Group II serpentinites in the south preserve relict orthopyroxene and olivine, and show depleted trace element compositions and comparatively lower δ18O values between +5.1‰ and +8.0‰. We interpret Group I serpentinites to derive from downgoing plate mantle, whereas Group II serpentinites derive from overlying mantle wedge, exhibiting remarkable similarity to the REE geochemistry of the structurally overlying New Caledonia ophiolite. Our results establish the subduction complex in New Caledonia as an unusual natural record of the entrainment and exhumation of mantle from both the overlying mantle wedge and the downgoing plate in an oceanic subduction zone.https://doi.org/10.1029/2022GC010395serpentiniteNew Caledoniamantle wedgesubductionstable isotopefluid‐rock interaction
spellingShingle Natalie H. Raia
Donna L. Whitney
Christian Teyssier
Stéphane Lesimple
Serpentinites of Different Tectonic Origin in an Exhumed Subduction Complex (New Caledonia, SW Pacific)
Geochemistry, Geophysics, Geosystems
serpentinite
New Caledonia
mantle wedge
subduction
stable isotope
fluid‐rock interaction
title Serpentinites of Different Tectonic Origin in an Exhumed Subduction Complex (New Caledonia, SW Pacific)
title_full Serpentinites of Different Tectonic Origin in an Exhumed Subduction Complex (New Caledonia, SW Pacific)
title_fullStr Serpentinites of Different Tectonic Origin in an Exhumed Subduction Complex (New Caledonia, SW Pacific)
title_full_unstemmed Serpentinites of Different Tectonic Origin in an Exhumed Subduction Complex (New Caledonia, SW Pacific)
title_short Serpentinites of Different Tectonic Origin in an Exhumed Subduction Complex (New Caledonia, SW Pacific)
title_sort serpentinites of different tectonic origin in an exhumed subduction complex new caledonia sw pacific
topic serpentinite
New Caledonia
mantle wedge
subduction
stable isotope
fluid‐rock interaction
url https://doi.org/10.1029/2022GC010395
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