Study of mechanical properties of epoxy/graphene and epoxy/halloysite nanocomposites

This article aimed to compare various mechanical properties of epoxy/graphene and epoxy/halloysite nanocomposites. Graphene nanoplatelets (GnPs) and halloysite nanotubes (HNTs) were used as fillers at different concentrations. The studied fillers were dispersed in the epoxy resin matrices. Elastic–p...

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Main Authors: Lapčík Lubomír, Sepetcioğlu Harun, Murtaja Yousef, Lapčíková Barbora, Vašina Martin, Ovsík Martin, Staněk Michal, Gautam Shweta
Format: Article
Language:English
Published: De Gruyter 2023-03-01
Series:Nanotechnology Reviews
Subjects:
Online Access:https://doi.org/10.1515/ntrev-2022-0520
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author Lapčík Lubomír
Sepetcioğlu Harun
Murtaja Yousef
Lapčíková Barbora
Vašina Martin
Ovsík Martin
Staněk Michal
Gautam Shweta
author_facet Lapčík Lubomír
Sepetcioğlu Harun
Murtaja Yousef
Lapčíková Barbora
Vašina Martin
Ovsík Martin
Staněk Michal
Gautam Shweta
author_sort Lapčík Lubomír
collection DOAJ
description This article aimed to compare various mechanical properties of epoxy/graphene and epoxy/halloysite nanocomposites. Graphene nanoplatelets (GnPs) and halloysite nanotubes (HNTs) were used as fillers at different concentrations. The studied fillers were dispersed in the epoxy resin matrices. Elastic–plastic mechanical behavior modulation was observed utilizing the fillers’ nanoparticles and carboxyl-terminated butadiene–acrylonitrile copolymer rubber-modified epoxy resin. The hypothesis of the possible preceding inter-particle gliding of the individual GnPs in the complex resin nanocomposite matrix during mechanical testings was also confirmed. Increased ductility (elongation at break increased from 0.33 mm [neat matrix] to 0.46 mm [1 wt% GnPs] [39% increase]) and plasticity of the GnP nanocomposite samples were observed. In contrast, the decreasing mechanical stiffness as reflected in the decreased Young’s modulus of elasticity (from 3.4 to 2.7 GPa [20% decrease]) was found for the epoxy/HNT nanocomposites. The obtained dynamic stiffness of the investigated nanocomposites confirmed the complexity of the mechanical response of the studied material systems as a combination of the ductile and brittle phenomena.
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spelling doaj.art-2d2d2f13239f4f1ab5ca9b32a78cb75c2023-04-11T17:07:18ZengDe GruyterNanotechnology Reviews2191-90972023-03-011212742710.1515/ntrev-2022-0520Study of mechanical properties of epoxy/graphene and epoxy/halloysite nanocompositesLapčík Lubomír0Sepetcioğlu Harun1Murtaja Yousef2Lapčíková Barbora3Vašina Martin4Ovsík Martin5Staněk Michal6Gautam Shweta7Department of Physical Chemistry, Faculty of Science, Palacky University, 17. Listopadu 12, 771 46Olomouc, Czech RepublicDepartment of Metallurgy and Mechanical Engineering, Technology Faculty, Selçuk University, Konya42075, TurkeyDepartment of Physical Chemistry, Faculty of Science, Palacky University, 17. Listopadu 12, 771 46Olomouc, Czech RepublicDepartment of Physical Chemistry, Faculty of Science, Palacky University, 17. Listopadu 12, 771 46Olomouc, Czech RepublicFaculty of Technology, Tomas Bata University in Zlin, Nam. T.G. Masaryka 275, 760 01Zlin, Czech RepublicFaculty of Technology, Tomas Bata University in Zlin, Nam. T.G. Masaryka 275, 760 01Zlin, Czech RepublicFaculty of Technology, Tomas Bata University in Zlin, Nam. T.G. Masaryka 275, 760 01Zlin, Czech RepublicFaculty of Technology, Tomas Bata University in Zlin, Nam. T.G. Masaryka 275, 760 01Zlin, Czech RepublicThis article aimed to compare various mechanical properties of epoxy/graphene and epoxy/halloysite nanocomposites. Graphene nanoplatelets (GnPs) and halloysite nanotubes (HNTs) were used as fillers at different concentrations. The studied fillers were dispersed in the epoxy resin matrices. Elastic–plastic mechanical behavior modulation was observed utilizing the fillers’ nanoparticles and carboxyl-terminated butadiene–acrylonitrile copolymer rubber-modified epoxy resin. The hypothesis of the possible preceding inter-particle gliding of the individual GnPs in the complex resin nanocomposite matrix during mechanical testings was also confirmed. Increased ductility (elongation at break increased from 0.33 mm [neat matrix] to 0.46 mm [1 wt% GnPs] [39% increase]) and plasticity of the GnP nanocomposite samples were observed. In contrast, the decreasing mechanical stiffness as reflected in the decreased Young’s modulus of elasticity (from 3.4 to 2.7 GPa [20% decrease]) was found for the epoxy/HNT nanocomposites. The obtained dynamic stiffness of the investigated nanocomposites confirmed the complexity of the mechanical response of the studied material systems as a combination of the ductile and brittle phenomena.https://doi.org/10.1515/ntrev-2022-0520graphenehalloysitenanocompositesepoxy polymerctbn rubbermechanical testing
spellingShingle Lapčík Lubomír
Sepetcioğlu Harun
Murtaja Yousef
Lapčíková Barbora
Vašina Martin
Ovsík Martin
Staněk Michal
Gautam Shweta
Study of mechanical properties of epoxy/graphene and epoxy/halloysite nanocomposites
Nanotechnology Reviews
graphene
halloysite
nanocomposites
epoxy polymer
ctbn rubber
mechanical testing
title Study of mechanical properties of epoxy/graphene and epoxy/halloysite nanocomposites
title_full Study of mechanical properties of epoxy/graphene and epoxy/halloysite nanocomposites
title_fullStr Study of mechanical properties of epoxy/graphene and epoxy/halloysite nanocomposites
title_full_unstemmed Study of mechanical properties of epoxy/graphene and epoxy/halloysite nanocomposites
title_short Study of mechanical properties of epoxy/graphene and epoxy/halloysite nanocomposites
title_sort study of mechanical properties of epoxy graphene and epoxy halloysite nanocomposites
topic graphene
halloysite
nanocomposites
epoxy polymer
ctbn rubber
mechanical testing
url https://doi.org/10.1515/ntrev-2022-0520
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