Tsuchime-like Aluminum Film to Enhance Absorption in Ultra-Thin Photovoltaic Cells

Ultra-thin solar cells enable materials to be saved, reduce deposition time, and promote carrier collection from materials with short diffusion lengths. However, light absorption efficiency in ultra-thin solar panels remains a limiting factor. Most methods to increase light absorption in ultra-thin...

Full description

Bibliographic Details
Main Authors: Mikita Marus, Yauhen Mukha, Him-Ting Wong, Tak-Lam Chan, Aliaksandr Smirnov, Aliaksandr Hubarevich, Haibo Hu
Format: Article
Language:English
Published: MDPI AG 2023-09-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/13/19/2650
_version_ 1797575431423000576
author Mikita Marus
Yauhen Mukha
Him-Ting Wong
Tak-Lam Chan
Aliaksandr Smirnov
Aliaksandr Hubarevich
Haibo Hu
author_facet Mikita Marus
Yauhen Mukha
Him-Ting Wong
Tak-Lam Chan
Aliaksandr Smirnov
Aliaksandr Hubarevich
Haibo Hu
author_sort Mikita Marus
collection DOAJ
description Ultra-thin solar cells enable materials to be saved, reduce deposition time, and promote carrier collection from materials with short diffusion lengths. However, light absorption efficiency in ultra-thin solar panels remains a limiting factor. Most methods to increase light absorption in ultra-thin solar cells are either technically challenging or costly, given the thinness of the functional layers involved. We propose a cost-efficient and lithography-free solution to enhance light absorption in ultra-thin solar cells—a Tsuchime-like self-forming nanocrater (T-NC) aluminum (Al) film. T-NC Al film can be produced by the electrochemical anodization of Al, followed by etching the nanoporous alumina. Theoretical studies show that T-NC film can increase the average absorbance by 80.3%, depending on the active layer’s thickness. The wavelength range of increased absorption varies with the active layer thickness, with the peak of absolute absorbance increase moving from 620 nm to 950 nm as the active layer thickness increases from 500 nm to 10 µm. We have also shown that the absorbance increase is retained regardless of the active layer material. Therefore, T-NC Al film significantly boosts absorbance in ultra-thin solar cells without requiring expensive lithography, and regardless of the active layer material.
first_indexed 2024-03-10T21:38:28Z
format Article
id doaj.art-2d32169c9dfd4f678a0b851f1ffe29a0
institution Directory Open Access Journal
issn 2079-4991
language English
last_indexed 2024-03-10T21:38:28Z
publishDate 2023-09-01
publisher MDPI AG
record_format Article
series Nanomaterials
spelling doaj.art-2d32169c9dfd4f678a0b851f1ffe29a02023-11-19T14:48:54ZengMDPI AGNanomaterials2079-49912023-09-011319265010.3390/nano13192650Tsuchime-like Aluminum Film to Enhance Absorption in Ultra-Thin Photovoltaic CellsMikita Marus0Yauhen Mukha1Him-Ting Wong2Tak-Lam Chan3Aliaksandr Smirnov4Aliaksandr Hubarevich5Haibo Hu6Centre for Advances in Reliability and Safety (CAiRS), Unit 1212–1213, 12/F, Building 19W, Hong Kong Science Park, Pak Shek Kok, New Territories, Hong Kong, ChinaLaboratory for Information Display and Processing Units, Belarusian State University of Informatics and Radioelectronics, 6 P. Brovki, 220013 Minsk, BelarusCentre for Advances in Reliability and Safety (CAiRS), Unit 1212–1213, 12/F, Building 19W, Hong Kong Science Park, Pak Shek Kok, New Territories, Hong Kong, ChinaCentre for Advances in Reliability and Safety (CAiRS), Unit 1212–1213, 12/F, Building 19W, Hong Kong Science Park, Pak Shek Kok, New Territories, Hong Kong, ChinaLaboratory for Information Display and Processing Units, Belarusian State University of Informatics and Radioelectronics, 6 P. Brovki, 220013 Minsk, BelarusLaboratory for Information Display and Processing Units, Belarusian State University of Informatics and Radioelectronics, 6 P. Brovki, 220013 Minsk, BelarusCentre for Advances in Reliability and Safety (CAiRS), Unit 1212–1213, 12/F, Building 19W, Hong Kong Science Park, Pak Shek Kok, New Territories, Hong Kong, ChinaUltra-thin solar cells enable materials to be saved, reduce deposition time, and promote carrier collection from materials with short diffusion lengths. However, light absorption efficiency in ultra-thin solar panels remains a limiting factor. Most methods to increase light absorption in ultra-thin solar cells are either technically challenging or costly, given the thinness of the functional layers involved. We propose a cost-efficient and lithography-free solution to enhance light absorption in ultra-thin solar cells—a Tsuchime-like self-forming nanocrater (T-NC) aluminum (Al) film. T-NC Al film can be produced by the electrochemical anodization of Al, followed by etching the nanoporous alumina. Theoretical studies show that T-NC film can increase the average absorbance by 80.3%, depending on the active layer’s thickness. The wavelength range of increased absorption varies with the active layer thickness, with the peak of absolute absorbance increase moving from 620 nm to 950 nm as the active layer thickness increases from 500 nm to 10 µm. We have also shown that the absorbance increase is retained regardless of the active layer material. Therefore, T-NC Al film significantly boosts absorbance in ultra-thin solar cells without requiring expensive lithography, and regardless of the active layer material.https://www.mdpi.com/2079-4991/13/19/2650thin filmnanostructuresolar energy harvestingsolar cellsnanomaterial
spellingShingle Mikita Marus
Yauhen Mukha
Him-Ting Wong
Tak-Lam Chan
Aliaksandr Smirnov
Aliaksandr Hubarevich
Haibo Hu
Tsuchime-like Aluminum Film to Enhance Absorption in Ultra-Thin Photovoltaic Cells
Nanomaterials
thin film
nanostructure
solar energy harvesting
solar cells
nanomaterial
title Tsuchime-like Aluminum Film to Enhance Absorption in Ultra-Thin Photovoltaic Cells
title_full Tsuchime-like Aluminum Film to Enhance Absorption in Ultra-Thin Photovoltaic Cells
title_fullStr Tsuchime-like Aluminum Film to Enhance Absorption in Ultra-Thin Photovoltaic Cells
title_full_unstemmed Tsuchime-like Aluminum Film to Enhance Absorption in Ultra-Thin Photovoltaic Cells
title_short Tsuchime-like Aluminum Film to Enhance Absorption in Ultra-Thin Photovoltaic Cells
title_sort tsuchime like aluminum film to enhance absorption in ultra thin photovoltaic cells
topic thin film
nanostructure
solar energy harvesting
solar cells
nanomaterial
url https://www.mdpi.com/2079-4991/13/19/2650
work_keys_str_mv AT mikitamarus tsuchimelikealuminumfilmtoenhanceabsorptioninultrathinphotovoltaiccells
AT yauhenmukha tsuchimelikealuminumfilmtoenhanceabsorptioninultrathinphotovoltaiccells
AT himtingwong tsuchimelikealuminumfilmtoenhanceabsorptioninultrathinphotovoltaiccells
AT taklamchan tsuchimelikealuminumfilmtoenhanceabsorptioninultrathinphotovoltaiccells
AT aliaksandrsmirnov tsuchimelikealuminumfilmtoenhanceabsorptioninultrathinphotovoltaiccells
AT aliaksandrhubarevich tsuchimelikealuminumfilmtoenhanceabsorptioninultrathinphotovoltaiccells
AT haibohu tsuchimelikealuminumfilmtoenhanceabsorptioninultrathinphotovoltaiccells