Effect of Sulfate Concentration on Chloride Diffusion of Concrete under Cyclic Load

The existence of chloride ions, sulfate ions, and vehicle dynamic loads may lead to a shortened service life and premature failure of the road and bridge structures in northwestern China. Immersed in a dual-salt solution while simultaneously applying cyclic flexural loads, the free chloride ion conc...

Full description

Bibliographic Details
Main Authors: Demei Yu, Chao Feng, Tengfei Fu, Aiqin Shen
Format: Article
Language:English
Published: MDPI AG 2022-03-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/15/6/2036
_version_ 1797445724366962688
author Demei Yu
Chao Feng
Tengfei Fu
Aiqin Shen
author_facet Demei Yu
Chao Feng
Tengfei Fu
Aiqin Shen
author_sort Demei Yu
collection DOAJ
description The existence of chloride ions, sulfate ions, and vehicle dynamic loads may lead to a shortened service life and premature failure of the road and bridge structures in northwestern China. Immersed in a dual-salt solution while simultaneously applying cyclic flexural loads, the free chloride ion concentration and erosion depth in concrete specimens were measured. The influence of the sulfate concentration on the apparent surface chloride concentration (<i>C</i><sub>s</sub>) and apparent diffusion coefficient (<i>D</i><sub>app</sub>) was studied. An exponential model was used to fit the <i>C</i><sub>s</sub>, and the influence of sulfate concentration on the <i>C</i><sub>s</sub> was analyzed. The result showed that cyclic loading and solution concentration were two primary factors affecting chloride diffusion. Meanwhile, compared with the emersion conditions, dynamic loading would induce significantly accelerated chloride ion penetration. Under the coupling effect of sulfate and dynamic loading, as the sulfate concentration increased, the chloride ion concentration and erosion depth were both decreased. The existence of sulfate ions improved the chloride ion penetration resistance of concrete. The results provide insight in designing concrete in regions where multiple salt ingression (sulfate and chloride) is a major durability issue of the structures.
first_indexed 2024-03-09T13:29:59Z
format Article
id doaj.art-2d3522ca9e354875b83f5dc793f90500
institution Directory Open Access Journal
issn 1996-1944
language English
last_indexed 2024-03-09T13:29:59Z
publishDate 2022-03-01
publisher MDPI AG
record_format Article
series Materials
spelling doaj.art-2d3522ca9e354875b83f5dc793f905002023-11-30T21:18:40ZengMDPI AGMaterials1996-19442022-03-01156203610.3390/ma15062036Effect of Sulfate Concentration on Chloride Diffusion of Concrete under Cyclic LoadDemei Yu0Chao Feng1Tengfei Fu2Aiqin Shen3College of Transportation and Civil Engineering, Fujian Agriculture and Forestry University, Fuzhou 350108, ChinaCollege of Transportation and Civil Engineering, Fujian Agriculture and Forestry University, Fuzhou 350108, ChinaCollege of Transportation and Civil Engineering, Fujian Agriculture and Forestry University, Fuzhou 350108, ChinaSchool of Highway, Chang’an University, Xi’an 710064, ChinaThe existence of chloride ions, sulfate ions, and vehicle dynamic loads may lead to a shortened service life and premature failure of the road and bridge structures in northwestern China. Immersed in a dual-salt solution while simultaneously applying cyclic flexural loads, the free chloride ion concentration and erosion depth in concrete specimens were measured. The influence of the sulfate concentration on the apparent surface chloride concentration (<i>C</i><sub>s</sub>) and apparent diffusion coefficient (<i>D</i><sub>app</sub>) was studied. An exponential model was used to fit the <i>C</i><sub>s</sub>, and the influence of sulfate concentration on the <i>C</i><sub>s</sub> was analyzed. The result showed that cyclic loading and solution concentration were two primary factors affecting chloride diffusion. Meanwhile, compared with the emersion conditions, dynamic loading would induce significantly accelerated chloride ion penetration. Under the coupling effect of sulfate and dynamic loading, as the sulfate concentration increased, the chloride ion concentration and erosion depth were both decreased. The existence of sulfate ions improved the chloride ion penetration resistance of concrete. The results provide insight in designing concrete in regions where multiple salt ingression (sulfate and chloride) is a major durability issue of the structures.https://www.mdpi.com/1996-1944/15/6/2036concretedynamic flexural loadingcyclicsulfatechlorideion transport
spellingShingle Demei Yu
Chao Feng
Tengfei Fu
Aiqin Shen
Effect of Sulfate Concentration on Chloride Diffusion of Concrete under Cyclic Load
Materials
concrete
dynamic flexural loading
cyclic
sulfate
chloride
ion transport
title Effect of Sulfate Concentration on Chloride Diffusion of Concrete under Cyclic Load
title_full Effect of Sulfate Concentration on Chloride Diffusion of Concrete under Cyclic Load
title_fullStr Effect of Sulfate Concentration on Chloride Diffusion of Concrete under Cyclic Load
title_full_unstemmed Effect of Sulfate Concentration on Chloride Diffusion of Concrete under Cyclic Load
title_short Effect of Sulfate Concentration on Chloride Diffusion of Concrete under Cyclic Load
title_sort effect of sulfate concentration on chloride diffusion of concrete under cyclic load
topic concrete
dynamic flexural loading
cyclic
sulfate
chloride
ion transport
url https://www.mdpi.com/1996-1944/15/6/2036
work_keys_str_mv AT demeiyu effectofsulfateconcentrationonchloridediffusionofconcreteundercyclicload
AT chaofeng effectofsulfateconcentrationonchloridediffusionofconcreteundercyclicload
AT tengfeifu effectofsulfateconcentrationonchloridediffusionofconcreteundercyclicload
AT aiqinshen effectofsulfateconcentrationonchloridediffusionofconcreteundercyclicload