Low-temperature sintering of Li4SiO4 spheres with high crushing load using mesoporous silica as Si sources
Li4SiO4 has been widely studied as tritium breeder and high temperature CO2 capture material. Tritium breeding rate and CO2 adsorption capacity are closely related to lithium content and microstructure. Since high sintering temperatures result in grain coarsening and lithium sublimation, it is a gre...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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University of Novi Sad
2023-03-01
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| Series: | Processing and Application of Ceramics |
| Subjects: | |
| Online Access: | https://www.doiserbia.nb.rs/img/doi/1820-6131/2023/1820-61312301055G.pdf |
| _version_ | 1797842628552687616 |
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| author | Gong Yichao Chen Xin Kang Kun Wang Yuefei Na Qingze Ren Shuai Zhang Guojun |
| author_facet | Gong Yichao Chen Xin Kang Kun Wang Yuefei Na Qingze Ren Shuai Zhang Guojun |
| author_sort | Gong Yichao |
| collection | DOAJ |
| description | Li4SiO4 has been widely studied as tritium breeder and high temperature CO2 capture material. Tritium breeding rate and CO2 adsorption capacity are closely related to lithium content and microstructure. Since high sintering temperatures result in grain coarsening and lithium sublimation, it is a great challenge to prepare Li4SiO4 ceramics with a satisfactory mechanical strength at low sintering temperature. In this work, mesoporous silica was used as Si source to prepare Li4SiO4 spheres. The mesoporous structure might provide more reaction sites for lithium ions, thereby facilitating the reaction between LiOH and mesoporous silica. The sintering temperature of Li4SiO4 spheres was greatly reduced by using mesoporous silica as Si source. The Li4SiO4 spheres with a homogenous fine-grained microstructure (the average grain size of 2.2 μm) and high crushing load (41.65N) could be obtained at 675°C. |
| first_indexed | 2024-04-09T16:51:01Z |
| format | Article |
| id | doaj.art-2d3d0c657f1541939c5137c58a3ce823 |
| institution | Directory Open Access Journal |
| issn | 1820-6131 2406-1034 |
| language | English |
| last_indexed | 2024-04-09T16:51:01Z |
| publishDate | 2023-03-01 |
| publisher | University of Novi Sad |
| record_format | Article |
| series | Processing and Application of Ceramics |
| spelling | doaj.art-2d3d0c657f1541939c5137c58a3ce8232023-04-21T11:06:41ZengUniversity of Novi SadProcessing and Application of Ceramics1820-61312406-10342023-03-01171556010.2298/PAC2301055GLow-temperature sintering of Li4SiO4 spheres with high crushing load using mesoporous silica as Si sourcesGong Yichao0Chen Xin1Kang Kun2Wang Yuefei3Na Qingze4Ren Shuai5Zhang Guojun6School of Materials Science and Engineering, Xi’an University of Technology, Xi’an, ChinaSchool of Materials Science and Engineering, Xi’an University of Technology, Xi’an, ChinaSchool of Materials Science and Engineering, Xi’an University of Technology, Xi’an, ChinaSchool of Materials Science and Engineering, Xi’an University of Technology, Xi’an, ChinaSchool of Materials Science and Engineering, Xi’an University of Technology, Xi’an, ChinaSchool of Materials Science and Engineering, Xi’an University of Technology, Xi’an, ChinaSchool of Materials Science and Engineering, Xi’an University of Technology, Xi’an, ChinaLi4SiO4 has been widely studied as tritium breeder and high temperature CO2 capture material. Tritium breeding rate and CO2 adsorption capacity are closely related to lithium content and microstructure. Since high sintering temperatures result in grain coarsening and lithium sublimation, it is a great challenge to prepare Li4SiO4 ceramics with a satisfactory mechanical strength at low sintering temperature. In this work, mesoporous silica was used as Si source to prepare Li4SiO4 spheres. The mesoporous structure might provide more reaction sites for lithium ions, thereby facilitating the reaction between LiOH and mesoporous silica. The sintering temperature of Li4SiO4 spheres was greatly reduced by using mesoporous silica as Si source. The Li4SiO4 spheres with a homogenous fine-grained microstructure (the average grain size of 2.2 μm) and high crushing load (41.65N) could be obtained at 675°C.https://www.doiserbia.nb.rs/img/doi/1820-6131/2023/1820-61312301055G.pdfli4sio4 pelletslow-temperature sinteringmesoporous silicacrushing load |
| spellingShingle | Gong Yichao Chen Xin Kang Kun Wang Yuefei Na Qingze Ren Shuai Zhang Guojun Low-temperature sintering of Li4SiO4 spheres with high crushing load using mesoporous silica as Si sources Processing and Application of Ceramics li4sio4 pellets low-temperature sintering mesoporous silica crushing load |
| title | Low-temperature sintering of Li4SiO4 spheres with high crushing load using mesoporous silica as Si sources |
| title_full | Low-temperature sintering of Li4SiO4 spheres with high crushing load using mesoporous silica as Si sources |
| title_fullStr | Low-temperature sintering of Li4SiO4 spheres with high crushing load using mesoporous silica as Si sources |
| title_full_unstemmed | Low-temperature sintering of Li4SiO4 spheres with high crushing load using mesoporous silica as Si sources |
| title_short | Low-temperature sintering of Li4SiO4 spheres with high crushing load using mesoporous silica as Si sources |
| title_sort | low temperature sintering of li4sio4 spheres with high crushing load using mesoporous silica as si sources |
| topic | li4sio4 pellets low-temperature sintering mesoporous silica crushing load |
| url | https://www.doiserbia.nb.rs/img/doi/1820-6131/2023/1820-61312301055G.pdf |
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