3-Hydroxy-2-methoxybenzamide
The crystal structure of the title compound, C8H9NO3, features centrosymmetric dimers with two amide groups interconnected by a pair of almost linear N—H...O hydrogen bonds. Through intermolecular O—H...O interactions between phenolic hydroxy groups and carbonyl O atoms,...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812047769 |
| _version_ | 1819294639826403328 |
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| author | Sabine Wilbrand Christian Neis Kaspar Hegetschweiler |
| author_facet | Sabine Wilbrand Christian Neis Kaspar Hegetschweiler |
| author_sort | Sabine Wilbrand |
| collection | DOAJ |
| description | The crystal structure of the title compound, C8H9NO3, features centrosymmetric dimers with two amide groups interconnected by a pair of almost linear N—H...O hydrogen bonds. Through intermolecular O—H...O interactions between phenolic hydroxy groups and carbonyl O atoms, these dimers are assembled into undulating hydrogen-bonded layers parallel to the [101] plane. Additionally, the anti-H(—N) atom of the primary amide group forms an intramolecular hydrogen bond to the O atom of the methoxy group. The amide group froms a dihedral angle of 12.6 (1)° with the phenyl ring. |
| first_indexed | 2024-12-24T04:29:31Z |
| format | Article |
| id | doaj.art-2d3fb091c8c94be7ae44065a33e4edb2 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T04:29:31Z |
| publishDate | 2012-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-2d3fb091c8c94be7ae44065a33e4edb22022-12-21T17:15:27ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812o3494o349410.1107/S16005368120477693-Hydroxy-2-methoxybenzamideSabine WilbrandChristian NeisKaspar HegetschweilerThe crystal structure of the title compound, C8H9NO3, features centrosymmetric dimers with two amide groups interconnected by a pair of almost linear N—H...O hydrogen bonds. Through intermolecular O—H...O interactions between phenolic hydroxy groups and carbonyl O atoms, these dimers are assembled into undulating hydrogen-bonded layers parallel to the [101] plane. Additionally, the anti-H(—N) atom of the primary amide group forms an intramolecular hydrogen bond to the O atom of the methoxy group. The amide group froms a dihedral angle of 12.6 (1)° with the phenyl ring.http://scripts.iucr.org/cgi-bin/paper?S1600536812047769 |
| spellingShingle | Sabine Wilbrand Christian Neis Kaspar Hegetschweiler 3-Hydroxy-2-methoxybenzamide Acta Crystallographica Section E |
| title | 3-Hydroxy-2-methoxybenzamide |
| title_full | 3-Hydroxy-2-methoxybenzamide |
| title_fullStr | 3-Hydroxy-2-methoxybenzamide |
| title_full_unstemmed | 3-Hydroxy-2-methoxybenzamide |
| title_short | 3-Hydroxy-2-methoxybenzamide |
| title_sort | 3 hydroxy 2 methoxybenzamide |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812047769 |
| work_keys_str_mv | AT sabinewilbrand 3hydroxy2methoxybenzamide AT christianneis 3hydroxy2methoxybenzamide AT kasparhegetschweiler 3hydroxy2methoxybenzamide |