Rearrangement of beta,gamma-unsaturated esters with thallium trinitrate: synthesis of indans bearing a beta-keto ester moiety

Rearrangement of beta,gamma-unsaturated esters with thallium trinitrate: synthesis of indans bearing a beta-keto ester moiety

The rearrangement of beta,gamma-unsaturated esters, such as 2-(3,4-dihydronaphthalen-1-yl)-propionic acid ethyl ester, with thallium trinitrate (TTN) in acetic acid leads to 3-indan-1-yl-2-methyl-3-oxo-propionic acid ethyl ester in good yield, through a ring contraction reaction. The new indans thus...

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Bibliographic Details
Main Authors:	Silva Jr. Luiz F., Pedrozo Eliane C., Ferraz Helena M. C.
Format:	Article
Language:	English
Published:	Sociedade Brasileira de Química 2006-01-01
Series:	Journal of the Brazilian Chemical Society
Subjects:	indan ring contraction thallium trinitrate beta-keto ester
Online Access:	http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532006000100029

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