Effect of additive content on the mechanical and thermal properties of pressureless liquid-phase sintered SiC

Pressureless liquid-phase sintered SiC (LPS-SiC) ceramics fabricated from β-SiC and 1 vol% α-SiC seeds with 3–15 vol% Al2O3-Y2O3-CaO additives were prepared to investigate the effects of additive content on the mechanical and thermal properties. All the specimens consisted primarily of elongated α-S...

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Main Authors: Rohit Malik, Yong-Hyeon Kim, Young-Wook Kim
Format: Article
Language:English
Published: Taylor & Francis Group 2020-04-01
Series:Journal of Asian Ceramic Societies
Subjects:
Online Access:http://dx.doi.org/10.1080/21870764.2020.1749376
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author Rohit Malik
Yong-Hyeon Kim
Young-Wook Kim
author_facet Rohit Malik
Yong-Hyeon Kim
Young-Wook Kim
author_sort Rohit Malik
collection DOAJ
description Pressureless liquid-phase sintered SiC (LPS-SiC) ceramics fabricated from β-SiC and 1 vol% α-SiC seeds with 3–15 vol% Al2O3-Y2O3-CaO additives were prepared to investigate the effects of additive content on the mechanical and thermal properties. All the specimens consisted primarily of elongated α-SiC grains that were predominantly formed via β to α phase transformation and via the growth of the initially added α-SiC seeds during the sintering. The grain growth and polytypic transformation exhibited diffusion-controlled kinetics. The highest value for fracture toughness (5.4 MPa·m1/2) was exhibited at an additive content level of 7 vol%; this was attributable to the optimal interfacial strength and well-interlocked elongated grains with active crack–microstructure interaction. The specimen with 7 vol% additive content exhibited the highest flexural strength (686 MPa) among the reported pressureless LPS-SiC ceramics, and this was attributable to its high density and the optimal content of soft intergranular phase (IGP). The hardness and thermal conductivity decreased gradually with the increase in additive content, owing to the increased volume fraction of the soft IGP with low thermal conductivity.
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spelling doaj.art-2d456591747c4f559307f40f3fe8c1202022-12-21T22:33:25ZengTaylor & Francis GroupJournal of Asian Ceramic Societies2187-07642020-04-018244845910.1080/21870764.2020.17493761749376Effect of additive content on the mechanical and thermal properties of pressureless liquid-phase sintered SiCRohit Malik0Yong-Hyeon Kim1Young-Wook Kim2The University of SeoulThe University of SeoulThe University of SeoulPressureless liquid-phase sintered SiC (LPS-SiC) ceramics fabricated from β-SiC and 1 vol% α-SiC seeds with 3–15 vol% Al2O3-Y2O3-CaO additives were prepared to investigate the effects of additive content on the mechanical and thermal properties. All the specimens consisted primarily of elongated α-SiC grains that were predominantly formed via β to α phase transformation and via the growth of the initially added α-SiC seeds during the sintering. The grain growth and polytypic transformation exhibited diffusion-controlled kinetics. The highest value for fracture toughness (5.4 MPa·m1/2) was exhibited at an additive content level of 7 vol%; this was attributable to the optimal interfacial strength and well-interlocked elongated grains with active crack–microstructure interaction. The specimen with 7 vol% additive content exhibited the highest flexural strength (686 MPa) among the reported pressureless LPS-SiC ceramics, and this was attributable to its high density and the optimal content of soft intergranular phase (IGP). The hardness and thermal conductivity decreased gradually with the increase in additive content, owing to the increased volume fraction of the soft IGP with low thermal conductivity.http://dx.doi.org/10.1080/21870764.2020.1749376sicpressureless sinteringmechanical propertiesthermal conductivityadditive content
spellingShingle Rohit Malik
Yong-Hyeon Kim
Young-Wook Kim
Effect of additive content on the mechanical and thermal properties of pressureless liquid-phase sintered SiC
Journal of Asian Ceramic Societies
sic
pressureless sintering
mechanical properties
thermal conductivity
additive content
title Effect of additive content on the mechanical and thermal properties of pressureless liquid-phase sintered SiC
title_full Effect of additive content on the mechanical and thermal properties of pressureless liquid-phase sintered SiC
title_fullStr Effect of additive content on the mechanical and thermal properties of pressureless liquid-phase sintered SiC
title_full_unstemmed Effect of additive content on the mechanical and thermal properties of pressureless liquid-phase sintered SiC
title_short Effect of additive content on the mechanical and thermal properties of pressureless liquid-phase sintered SiC
title_sort effect of additive content on the mechanical and thermal properties of pressureless liquid phase sintered sic
topic sic
pressureless sintering
mechanical properties
thermal conductivity
additive content
url http://dx.doi.org/10.1080/21870764.2020.1749376
work_keys_str_mv AT rohitmalik effectofadditivecontentonthemechanicalandthermalpropertiesofpressurelessliquidphasesinteredsic
AT yonghyeonkim effectofadditivecontentonthemechanicalandthermalpropertiesofpressurelessliquidphasesinteredsic
AT youngwookkim effectofadditivecontentonthemechanicalandthermalpropertiesofpressurelessliquidphasesinteredsic