Crystal structure of octa-μ3-selenido-(p-toluenesulfonato-κO)pentakis(triethylphosphane-κP)-octahedro-hexarhenium(III) p-toluenesulfonate dichloromethane disolvate

Crystal structure of octa-μ3-selenido-(p-toluenesulfonato-κO)pentakis(triethylphosphane-κP)-octahedro-hexarhenium(III) p-toluenesulfonate dichloromethane disolvate

The title compound, [Re6Se8{O3SC6H4(CH3)}{P(C2H5)3}5](CH3C6H4SO3)·2CH2Cl2, contains the face-capped hexanuclear [Re6(μ3-Se)8]2+ cluster core. The [Re6Se8]2+ cluster core displays a non-crystallographic center of symmetry and is bonded through the ReIII atoms to five triethylphosphane ligands and one...

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Bibliographic Details
Main Authors: Julia A. Edwards, Robert McDonald, Lisa F. Szczepura
Format: Article
Language:English
Published: International Union of Crystallography 2015-09-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
rhenium complex
[Re6(μ3-Se)8]2+ cluster core
tosylate
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015014334

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