Stability of Non-Flexible vs. Flexible Inverted Bulk-Heterojunction Organic Solar Cells with ZnO as Electron Transport Layer Prepared by a Sol-Gel Spin Coating Method

In this research, inverted bulk heterojunction organic solar cells (BHJ OSC) with poly(3-hexylthiophene-2,5-diyl): (6,6)-phenyl C61 butyric acid methyl (P3HT:PCBM) as the active layer were fabricated by a sol-gel spin coating method using flexible PET and non-flexible glass as substrates. The power...

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Bibliographic Details
Main Authors: Mohammad-Reza Zamani-Meymian, Saeb Sheikholeslami, Milad Fallah
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Surfaces
Subjects:
Online Access:https://www.mdpi.com/2571-9637/3/3/23
Description
Summary:In this research, inverted bulk heterojunction organic solar cells (BHJ OSC) with poly(3-hexylthiophene-2,5-diyl): (6,6)-phenyl C61 butyric acid methyl (P3HT:PCBM) as the active layer were fabricated by a sol-gel spin coating method using flexible PET and non-flexible glass as substrates. The power conversion efficiency (PCE) and the stability of the cells were investigated. According to the results, the non-flexible device showed higher short circuit current (J<sub>sc</sub>) as well as open-circuit voltage (V<sub>oc</sub>) as compared to the flexible one so that 2.52% and 0.67% PCE for non-flexible and flexible cells were obtained, respectively. From the stability point of view, the non-flexible device maintained 51% of its initial efficiency after six weeks in a dark atmosphere, while it was about 19% for the flexible cell after four weeks. The most important reason for the higher PCE with the higher stability in the non-flexible cell can be attributed to its higher shunt resistance (R<sub>sh</sub>) and better interlayer connections at the electron collector side.
ISSN:2571-9637