Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridomercurate(II)
The crystal structure of the title compound, (C5H9N2)2[HgCl4], consists of discrete tetrachloridomercurate dications and discrete 2-methylimidazolium cations. In the complex anion, the mercury cations are coordinated by four chloride anions with distances between 2.4568 (14) and 2.4936...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811055371 |
| _version_ | 1818320900387241984 |
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| author | Run-Qiang Zhu |
| author_facet | Run-Qiang Zhu |
| author_sort | Run-Qiang Zhu |
| collection | DOAJ |
| description | The crystal structure of the title compound, (C5H9N2)2[HgCl4], consists of discrete tetrachloridomercurate dications and discrete 2-methylimidazolium cations. In the complex anion, the mercury cations are coordinated by four chloride anions with distances between 2.4568 (14) and 2.4936 (15) Å in a tetrahedral geometry. In the crystal, the cations and anions are connected by intermolecular N—H...Cl interactions. One C atom of the cations is disordered and was refined using a split model (occupancy ratio 0.75:0.25). |
| first_indexed | 2024-12-13T10:32:21Z |
| format | Article |
| id | doaj.art-2d60d9f64ae84c83a563e5b33c547d3c |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:32:21Z |
| publishDate | 2012-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-2d60d9f64ae84c83a563e5b33c547d3c2022-12-21T23:50:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m148m14810.1107/S1600536811055371Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridomercurate(II)Run-Qiang ZhuThe crystal structure of the title compound, (C5H9N2)2[HgCl4], consists of discrete tetrachloridomercurate dications and discrete 2-methylimidazolium cations. In the complex anion, the mercury cations are coordinated by four chloride anions with distances between 2.4568 (14) and 2.4936 (15) Å in a tetrahedral geometry. In the crystal, the cations and anions are connected by intermolecular N—H...Cl interactions. One C atom of the cations is disordered and was refined using a split model (occupancy ratio 0.75:0.25).http://scripts.iucr.org/cgi-bin/paper?S1600536811055371 |
| spellingShingle | Run-Qiang Zhu Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridomercurate(II) Acta Crystallographica Section E |
| title | Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridomercurate(II) |
| title_full | Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridomercurate(II) |
| title_fullStr | Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridomercurate(II) |
| title_full_unstemmed | Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridomercurate(II) |
| title_short | Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridomercurate(II) |
| title_sort | bis 2 ethyl 1h imidazol 3 ium tetrachloridomercurate ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811055371 |
| work_keys_str_mv | AT runqiangzhu bis2ethyl1himidazol3iumtetrachloridomercurateii |