Finite-time quantum Stirling heat engine

We study the thermodynamic performance of a finite-time non-regenerative quantum Stirling-like cycle used as a heat engine. We consider specifically the case in which the working substance (WS) is a two-level system (TLS). The Stirling cycle is made of two isochoric transformations separated by a co...

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Main Authors: S Hamedani Raja, S Maniscalco, G S Paraoanu, J P Pekola, N Lo Gullo
Format: Article
Language:English
Published: IOP Publishing 2021-01-01
Series:New Journal of Physics
Subjects:
Online Access:https://doi.org/10.1088/1367-2630/abe9d7
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author S Hamedani Raja
S Maniscalco
G S Paraoanu
J P Pekola
N Lo Gullo
author_facet S Hamedani Raja
S Maniscalco
G S Paraoanu
J P Pekola
N Lo Gullo
author_sort S Hamedani Raja
collection DOAJ
description We study the thermodynamic performance of a finite-time non-regenerative quantum Stirling-like cycle used as a heat engine. We consider specifically the case in which the working substance (WS) is a two-level system (TLS). The Stirling cycle is made of two isochoric transformations separated by a compression and an expansion stroke during which the WS is in contact with a thermal reservoir. To describe these two strokes we derive a non-Markovian master equation which allows to study the real-time dynamics of a driven open quantum system with arbitrary fast driving. Following the real-time dynamics of the WS using this master equation, the endpoints of the isotherms can deviate from the equilibrium thermal states. The role of this deviation in the performance of the heat engine is addressed. We found that the finite-time dynamics and thermodynamics of the cycle depend non-trivially on the different time scales at play. In particular, driving the WS at a time scale comparable to the resonance time of the bath enhances the performance of the cycle and allows for an efficiency higher than the efficiency of the quasistatic cycle, but still below the Carnot bound. However, by adding thermalization of the WS with the baths at the end of compression/expansion processes one recovers the conventional scenario in which efficiency decreases by speeding up the processes. In addition, the performance of the cycle is dependent on the compression/expansion speeds asymmetrically, which suggests new freedom in optimizing quantum heat engines. The maximum output power and the maximum efficiency are obtained almost simultaneously when the real-time endpoints of the compression/expansion processes are considered instead of the equilibrium thermal endpoint states. However, the net extractable work always declines by speeding up the drive.
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spelling doaj.art-2d8ff2660ef7411eb3306b5abf657fa32023-08-08T15:33:40ZengIOP PublishingNew Journal of Physics1367-26302021-01-0123303303410.1088/1367-2630/abe9d7Finite-time quantum Stirling heat engineS Hamedani Raja0https://orcid.org/0000-0002-7881-1247S Maniscalco1G S Paraoanu2https://orcid.org/0000-0003-0057-7275J P Pekola3N Lo Gullo4https://orcid.org/0000-0002-8178-9570QTF Centre of Excellence, Turku Centre for Quantum Physics, Department of Physics and Astronomy, University of Turku , 20014 Turku, Finland; QTF Centre of Excellence, Department of Applied Physics, Aalto University , FI-00076 Aalto, FinlandQTF Centre of Excellence, Turku Centre for Quantum Physics, Department of Physics and Astronomy, University of Turku , 20014 Turku, Finland; QTF Centre of Excellence, Department of Applied Physics, Aalto University , FI-00076 Aalto, Finland; QTF Centre of Excellence, Department of Physics, PO Box 43, FI-00014, University of Helsinki , FinlandQTF Centre of Excellence, Department of Applied Physics, Aalto University , FI-00076 Aalto, FinlandQTF Centre of Excellence, Department of Applied Physics, Aalto University , FI-00076 Aalto, FinlandQTF Centre of Excellence, Turku Centre for Quantum Physics, Department of Physics and Astronomy, University of Turku , 20014 Turku, FinlandWe study the thermodynamic performance of a finite-time non-regenerative quantum Stirling-like cycle used as a heat engine. We consider specifically the case in which the working substance (WS) is a two-level system (TLS). The Stirling cycle is made of two isochoric transformations separated by a compression and an expansion stroke during which the WS is in contact with a thermal reservoir. To describe these two strokes we derive a non-Markovian master equation which allows to study the real-time dynamics of a driven open quantum system with arbitrary fast driving. Following the real-time dynamics of the WS using this master equation, the endpoints of the isotherms can deviate from the equilibrium thermal states. The role of this deviation in the performance of the heat engine is addressed. We found that the finite-time dynamics and thermodynamics of the cycle depend non-trivially on the different time scales at play. In particular, driving the WS at a time scale comparable to the resonance time of the bath enhances the performance of the cycle and allows for an efficiency higher than the efficiency of the quasistatic cycle, but still below the Carnot bound. However, by adding thermalization of the WS with the baths at the end of compression/expansion processes one recovers the conventional scenario in which efficiency decreases by speeding up the processes. In addition, the performance of the cycle is dependent on the compression/expansion speeds asymmetrically, which suggests new freedom in optimizing quantum heat engines. The maximum output power and the maximum efficiency are obtained almost simultaneously when the real-time endpoints of the compression/expansion processes are considered instead of the equilibrium thermal endpoint states. However, the net extractable work always declines by speeding up the drive.https://doi.org/10.1088/1367-2630/abe9d7quantum thermodynamicsfinite-time quantum heat enginesStirling cycle
spellingShingle S Hamedani Raja
S Maniscalco
G S Paraoanu
J P Pekola
N Lo Gullo
Finite-time quantum Stirling heat engine
New Journal of Physics
quantum thermodynamics
finite-time quantum heat engines
Stirling cycle
title Finite-time quantum Stirling heat engine
title_full Finite-time quantum Stirling heat engine
title_fullStr Finite-time quantum Stirling heat engine
title_full_unstemmed Finite-time quantum Stirling heat engine
title_short Finite-time quantum Stirling heat engine
title_sort finite time quantum stirling heat engine
topic quantum thermodynamics
finite-time quantum heat engines
Stirling cycle
url https://doi.org/10.1088/1367-2630/abe9d7
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