(1,10-Phenanthroline-κ2N,N′)bis(2-thioxo-1,2-dihydropyridine-3-carboxylato-κ2O,S)manganese(II)
In the title complex, [Mn(C6H4NO2S)2(C12H8N2)] or [MnL2(phen)] (L = 2-mercaptonicotinate and phen = 1,10-phenanthroline), the central MnII atom is coordinated by two carboxylic O atoms and two thiolate S atoms of two L ligands and two N atoms from one phen molecule, giving a distorted octahedral geo...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681001514X |
| _version_ | 1818907595982766080 |
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| author | Wei-Qi Li |
| author_facet | Wei-Qi Li |
| author_sort | Wei-Qi Li |
| collection | DOAJ |
| description | In the title complex, [Mn(C6H4NO2S)2(C12H8N2)] or [MnL2(phen)] (L = 2-mercaptonicotinate and phen = 1,10-phenanthroline), the central MnII atom is coordinated by two carboxylic O atoms and two thiolate S atoms of two L ligands and two N atoms from one phen molecule, giving a distorted octahedral geometry. The pyridyl H atoms form strong N—H...O hydrogen bonds with the carbonyl O atoms of the adjacent molecules, generating a chain structure propagating in [100]. |
| first_indexed | 2024-12-19T21:57:38Z |
| format | Article |
| id | doaj.art-2d90d75c178b47ba8c7209f03048cb5f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T21:57:38Z |
| publishDate | 2010-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-2d90d75c178b47ba8c7209f03048cb5f2022-12-21T20:04:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666m646m64610.1107/S160053681001514X(1,10-Phenanthroline-κ2N,N′)bis(2-thioxo-1,2-dihydropyridine-3-carboxylato-κ2O,S)manganese(II)Wei-Qi LiIn the title complex, [Mn(C6H4NO2S)2(C12H8N2)] or [MnL2(phen)] (L = 2-mercaptonicotinate and phen = 1,10-phenanthroline), the central MnII atom is coordinated by two carboxylic O atoms and two thiolate S atoms of two L ligands and two N atoms from one phen molecule, giving a distorted octahedral geometry. The pyridyl H atoms form strong N—H...O hydrogen bonds with the carbonyl O atoms of the adjacent molecules, generating a chain structure propagating in [100].http://scripts.iucr.org/cgi-bin/paper?S160053681001514X |
| spellingShingle | Wei-Qi Li (1,10-Phenanthroline-κ2N,N′)bis(2-thioxo-1,2-dihydropyridine-3-carboxylato-κ2O,S)manganese(II) Acta Crystallographica Section E |
| title | (1,10-Phenanthroline-κ2N,N′)bis(2-thioxo-1,2-dihydropyridine-3-carboxylato-κ2O,S)manganese(II) |
| title_full | (1,10-Phenanthroline-κ2N,N′)bis(2-thioxo-1,2-dihydropyridine-3-carboxylato-κ2O,S)manganese(II) |
| title_fullStr | (1,10-Phenanthroline-κ2N,N′)bis(2-thioxo-1,2-dihydropyridine-3-carboxylato-κ2O,S)manganese(II) |
| title_full_unstemmed | (1,10-Phenanthroline-κ2N,N′)bis(2-thioxo-1,2-dihydropyridine-3-carboxylato-κ2O,S)manganese(II) |
| title_short | (1,10-Phenanthroline-κ2N,N′)bis(2-thioxo-1,2-dihydropyridine-3-carboxylato-κ2O,S)manganese(II) |
| title_sort | 1 10 phenanthroline amp 954 2n n amp 8242 bis 2 thioxo 1 2 dihydropyridine 3 carboxylato amp 954 2o s manganese ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681001514X |
| work_keys_str_mv | AT weiqili 110phenanthrolineamp9542nnamp8242bis2thioxo12dihydropyridine3carboxylatoamp9542osmanganeseii |