Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts
Glycerol, byproduct from the biodiesel production can be effectively utilized as the promising source of synthesis gas (syngas) through a dry reforming reaction. Combination of these waste materials with greenhouse gases which is carbon dioxide (CO2) will help to reduce environmental problem such as...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
2016-08-01
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| Series: | Bulletin of Chemical Reaction Engineering & Catalysis |
| Subjects: | |
| Online Access: | https://journal.bcrec.id/index.php/bcrec/article/view/551 |
| _version_ | 1827810217642950656 |
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| author | Nur Nabillah Mohd Arif Dai-Viet N. Vo Mohammad Tazli Azizan Sumaiya Zainal Abidin |
| author_facet | Nur Nabillah Mohd Arif Dai-Viet N. Vo Mohammad Tazli Azizan Sumaiya Zainal Abidin |
| author_sort | Nur Nabillah Mohd Arif |
| collection | DOAJ |
| description | Glycerol, byproduct from the biodiesel production can be effectively utilized as the promising source of synthesis gas (syngas) through a dry reforming reaction. Combination of these waste materials with greenhouse gases which is carbon dioxide (CO2) will help to reduce environmental problem such as global warming. This dry reforming reaction has been carried out in a fixed bed batch reactor at 700 °C under the atmospheric pressure for 3 hours. In this experiment, reforming reaction was carried out using Nickel (Ni) as based catalyst and supported with zirconium (ZrO2) and calcium (CaO) oxides. The catalysts were prepared by wet impregnation method and characterized using Bruanaer-Emmett-Teller (BET) surface area, Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), Thermo Gravimetric (TGA), and Temperature Programmed Reduction (TPR) analysis. Reaction studies show that 15% Ni/CaO give the highest hydrogen yield and glycerol conversion that peaked at 24.59% and 30.32%, respectively. This result is verified by XRD analysis where this catalyst shows low crystallinity and fine dispersion of Ni species resulted in high specific surface area which gives 44.93 m2/g that is validated by BET. |
| first_indexed | 2024-03-11T22:49:30Z |
| format | Article |
| id | doaj.art-2da39b3e04d5464083e76a2330056364 |
| institution | Directory Open Access Journal |
| issn | 1978-2993 |
| language | English |
| last_indexed | 2024-03-11T22:49:30Z |
| publishDate | 2016-08-01 |
| publisher | Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) |
| record_format | Article |
| series | Bulletin of Chemical Reaction Engineering & Catalysis |
| spelling | doaj.art-2da39b3e04d5464083e76a23300563642023-09-22T03:50:23ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932016-08-0111220020910.9767/bcrec.11.2.551.200-209427Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as CatalystsNur Nabillah Mohd Arif0Dai-Viet N. Vo1Mohammad Tazli Azizan2Sumaiya Zainal Abidin3Faculty of Chemical Engineering & Natural Resources, Universiti Malaysia Pahang, 26300 Gambang, Pahang,, MalaysiaFaculty of Chemical Engineering & Natural Resources, Universiti Malaysia Pahang, 26300 Gambang, Pahang,, MalaysiaDepartment of Chemical Engineering, Faculty of Engineering, Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, Perak Darul Ridzuan,, MalaysiaFaculty of Chemical Engineering & Natural Resources, Universiti Malaysia Pahang, 26300 Gambang, Pahang,, MalaysiaGlycerol, byproduct from the biodiesel production can be effectively utilized as the promising source of synthesis gas (syngas) through a dry reforming reaction. Combination of these waste materials with greenhouse gases which is carbon dioxide (CO2) will help to reduce environmental problem such as global warming. This dry reforming reaction has been carried out in a fixed bed batch reactor at 700 °C under the atmospheric pressure for 3 hours. In this experiment, reforming reaction was carried out using Nickel (Ni) as based catalyst and supported with zirconium (ZrO2) and calcium (CaO) oxides. The catalysts were prepared by wet impregnation method and characterized using Bruanaer-Emmett-Teller (BET) surface area, Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), Thermo Gravimetric (TGA), and Temperature Programmed Reduction (TPR) analysis. Reaction studies show that 15% Ni/CaO give the highest hydrogen yield and glycerol conversion that peaked at 24.59% and 30.32%, respectively. This result is verified by XRD analysis where this catalyst shows low crystallinity and fine dispersion of Ni species resulted in high specific surface area which gives 44.93 m2/g that is validated by BET.https://journal.bcrec.id/index.php/bcrec/article/view/551biodieselglyceroldry reformingsyngasni-based catalystni/zro2ni/cao |
| spellingShingle | Nur Nabillah Mohd Arif Dai-Viet N. Vo Mohammad Tazli Azizan Sumaiya Zainal Abidin Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts Bulletin of Chemical Reaction Engineering & Catalysis biodiesel glycerol dry reforming syngas ni-based catalyst ni/zro2 ni/cao |
| title | Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts |
| title_full | Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts |
| title_fullStr | Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts |
| title_full_unstemmed | Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts |
| title_short | Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts |
| title_sort | carbon dioxide dry reforming of glycerol for hydrogen production using ni zro2 and ni cao as catalysts |
| topic | biodiesel glycerol dry reforming syngas ni-based catalyst ni/zro2 ni/cao |
| url | https://journal.bcrec.id/index.php/bcrec/article/view/551 |
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