Application of X-ray Fluorescence Spectroscopy in Identification and Classification of Marble

The identification and classification of marble depended mainly on the identification of rock slices and the semi-quantitative detection of minerals by X-ray Diffraction (XRD). It was found that the results of identification of rock slices were not always consistent with those of the semi-quantitati...

Full description

Bibliographic Details
Main Authors: CHI Guang-cheng, WU Yue, WANG Hai-jiao, CHEN Ying-li, WANG Da-qian
Format: Article
Language:English
Published: Science Press, PR China 2018-01-01
Series:Yankuang ceshi
Subjects:
Online Access:http://www.ykcs.ac.cn/cn/article/doi/10.15898/j.cnki.11-2131/td.201611300176
_version_ 1811169410848653312
author CHI Guang-cheng
WU Yue
WANG Hai-jiao
CHEN Ying-li
WANG Da-qian
author_facet CHI Guang-cheng
WU Yue
WANG Hai-jiao
CHEN Ying-li
WANG Da-qian
author_sort CHI Guang-cheng
collection DOAJ
description The identification and classification of marble depended mainly on the identification of rock slices and the semi-quantitative detection of minerals by X-ray Diffraction (XRD). It was found that the results of identification of rock slices were not always consistent with those of the semi-quantitative detection by XRD. Therefore, it is necessary to introduce other techniques to verify the results of thin section observation and XRD semi-quantitative analysis. 32 marble samples were analyzed by X-ray Fluorescence Spectrometer, the results and finding of which are reported in this paper. Based on the chemical composition of rock, rock impurity, magnesite, and calcareous coefficients are used to classify the marble. The results show that magnesite coefficients of calcite marble, dolomite marble, and magnesite marble are 0.01-0.13, 0.40-0.46 and 0.97-0.98, respectively. Calcareous coefficients are 0.78-0.84, 0.30-0.49 and 0.01-0.02, respectively. Different types of marble have various magnesia and calcareous coefficients, which can be used as the main basis for the division of marble types. Only the contents of SiO<sub>2</sub>+Al<sub>2</sub>O<sub>3</sub> in rocks are less than 30% (impurity coefficient less than 1.00), then can be classified as marbles. The establishment and application of impurity, magnesia and calcareous coefficients in marble can be used to correct the inconsistent results between thin section observation and X-ray Powder Diffraction mineral semi-quantitative analysis, making marble classification more accurate.
first_indexed 2024-04-10T16:41:52Z
format Article
id doaj.art-2da75ee1b72740e1b7e0c0dc60bc86a7
institution Directory Open Access Journal
issn 0254-5357
language English
last_indexed 2024-04-10T16:41:52Z
publishDate 2018-01-01
publisher Science Press, PR China
record_format Article
series Yankuang ceshi
spelling doaj.art-2da75ee1b72740e1b7e0c0dc60bc86a72023-02-08T06:00:00ZengScience Press, PR ChinaYankuang ceshi0254-53572018-01-01371434910.15898/j.cnki.11-2131/td.201611300176ykcs-37-1-43Application of X-ray Fluorescence Spectroscopy in Identification and Classification of MarbleCHI Guang-cheng0WU Yue1WANG Hai-jiao2CHEN Ying-li3WANG Da-qian4Shenyang Geological Survey Center, China Geological Survey, Shenyang 110032, ChinaShenyang Geological Survey Center, China Geological Survey, Shenyang 110032, ChinaShenyang Geological Survey Center, China Geological Survey, Shenyang 110032, ChinaShenyang Geological Survey Center, China Geological Survey, Shenyang 110032, ChinaShenyang Geological Survey Center, China Geological Survey, Shenyang 110032, ChinaThe identification and classification of marble depended mainly on the identification of rock slices and the semi-quantitative detection of minerals by X-ray Diffraction (XRD). It was found that the results of identification of rock slices were not always consistent with those of the semi-quantitative detection by XRD. Therefore, it is necessary to introduce other techniques to verify the results of thin section observation and XRD semi-quantitative analysis. 32 marble samples were analyzed by X-ray Fluorescence Spectrometer, the results and finding of which are reported in this paper. Based on the chemical composition of rock, rock impurity, magnesite, and calcareous coefficients are used to classify the marble. The results show that magnesite coefficients of calcite marble, dolomite marble, and magnesite marble are 0.01-0.13, 0.40-0.46 and 0.97-0.98, respectively. Calcareous coefficients are 0.78-0.84, 0.30-0.49 and 0.01-0.02, respectively. Different types of marble have various magnesia and calcareous coefficients, which can be used as the main basis for the division of marble types. Only the contents of SiO<sub>2</sub>+Al<sub>2</sub>O<sub>3</sub> in rocks are less than 30% (impurity coefficient less than 1.00), then can be classified as marbles. The establishment and application of impurity, magnesia and calcareous coefficients in marble can be used to correct the inconsistent results between thin section observation and X-ray Powder Diffraction mineral semi-quantitative analysis, making marble classification more accurate.http://www.ykcs.ac.cn/cn/article/doi/10.15898/j.cnki.11-2131/td.201611300176marblex-ray fluorescence spectrometrymineral identificationimpurity coefficientmagnesia coefficientcalcareous coefficient
spellingShingle CHI Guang-cheng
WU Yue
WANG Hai-jiao
CHEN Ying-li
WANG Da-qian
Application of X-ray Fluorescence Spectroscopy in Identification and Classification of Marble
Yankuang ceshi
marble
x-ray fluorescence spectrometry
mineral identification
impurity coefficient
magnesia coefficient
calcareous coefficient
title Application of X-ray Fluorescence Spectroscopy in Identification and Classification of Marble
title_full Application of X-ray Fluorescence Spectroscopy in Identification and Classification of Marble
title_fullStr Application of X-ray Fluorescence Spectroscopy in Identification and Classification of Marble
title_full_unstemmed Application of X-ray Fluorescence Spectroscopy in Identification and Classification of Marble
title_short Application of X-ray Fluorescence Spectroscopy in Identification and Classification of Marble
title_sort application of x ray fluorescence spectroscopy in identification and classification of marble
topic marble
x-ray fluorescence spectrometry
mineral identification
impurity coefficient
magnesia coefficient
calcareous coefficient
url http://www.ykcs.ac.cn/cn/article/doi/10.15898/j.cnki.11-2131/td.201611300176
work_keys_str_mv AT chiguangcheng applicationofxrayfluorescencespectroscopyinidentificationandclassificationofmarble
AT wuyue applicationofxrayfluorescencespectroscopyinidentificationandclassificationofmarble
AT wanghaijiao applicationofxrayfluorescencespectroscopyinidentificationandclassificationofmarble
AT chenyingli applicationofxrayfluorescencespectroscopyinidentificationandclassificationofmarble
AT wangdaqian applicationofxrayfluorescencespectroscopyinidentificationandclassificationofmarble