Bis(μ-iminodiacetato)bis[(2,2′-diamino-4,4′-bi-1,3-thiazole)lead(II)] tetrahydrate
In the crystal structure of the title compound, [Pb2(C4H5NO4)2(C6H6N4S2)2]·4H2O, the dinuclear PbII complex molecule is centrosymmetric. The Pb atom is chelated by a tridentate iminodiacetate anion (IDA) and a diaminobithiazole (DABT) ligand, while a carboxylate O atom from an adjacent...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810006926 |
| _version_ | 1818894504905670656 |
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| author | Jing-Jing Nie Bing-Xin Liu Mei Du Duan-Jun Xu |
| author_facet | Jing-Jing Nie Bing-Xin Liu Mei Du Duan-Jun Xu |
| author_sort | Jing-Jing Nie |
| collection | DOAJ |
| description | In the crystal structure of the title compound, [Pb2(C4H5NO4)2(C6H6N4S2)2]·4H2O, the dinuclear PbII complex molecule is centrosymmetric. The Pb atom is chelated by a tridentate iminodiacetate anion (IDA) and a diaminobithiazole (DABT) ligand, while a carboxylate O atom from an adjacent IDA anion further bridges the Pb atom with a longer Pb—O bond [2.892 (3) Å]. The lone-pair electrons of the Pb atom occupy an axial site in the Ψ-pentagonal-bipyramidal coordination polyhedron. The IDA anion displays a facial configuration: its chelating five-membered rings assume an envelope configuration. Within the DABT ligand, the two thiazole rings are twisted relative to each other, making a dihedral angle of 9.51 (17)°. Extensive N—H...O, O—H...O and weak C—H...O hydrogen bonding helps to stabilize the crystal structure. |
| first_indexed | 2024-12-19T18:29:33Z |
| format | Article |
| id | doaj.art-2db7b3118b8f4f9ebcb360dcf5133f39 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T18:29:33Z |
| publishDate | 2010-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-2db7b3118b8f4f9ebcb360dcf5133f392022-12-21T20:10:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-03-01663m343m34410.1107/S1600536810006926Bis(μ-iminodiacetato)bis[(2,2′-diamino-4,4′-bi-1,3-thiazole)lead(II)] tetrahydrateJing-Jing NieBing-Xin LiuMei DuDuan-Jun XuIn the crystal structure of the title compound, [Pb2(C4H5NO4)2(C6H6N4S2)2]·4H2O, the dinuclear PbII complex molecule is centrosymmetric. The Pb atom is chelated by a tridentate iminodiacetate anion (IDA) and a diaminobithiazole (DABT) ligand, while a carboxylate O atom from an adjacent IDA anion further bridges the Pb atom with a longer Pb—O bond [2.892 (3) Å]. The lone-pair electrons of the Pb atom occupy an axial site in the Ψ-pentagonal-bipyramidal coordination polyhedron. The IDA anion displays a facial configuration: its chelating five-membered rings assume an envelope configuration. Within the DABT ligand, the two thiazole rings are twisted relative to each other, making a dihedral angle of 9.51 (17)°. Extensive N—H...O, O—H...O and weak C—H...O hydrogen bonding helps to stabilize the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536810006926 |
| spellingShingle | Jing-Jing Nie Bing-Xin Liu Mei Du Duan-Jun Xu Bis(μ-iminodiacetato)bis[(2,2′-diamino-4,4′-bi-1,3-thiazole)lead(II)] tetrahydrate Acta Crystallographica Section E |
| title | Bis(μ-iminodiacetato)bis[(2,2′-diamino-4,4′-bi-1,3-thiazole)lead(II)] tetrahydrate |
| title_full | Bis(μ-iminodiacetato)bis[(2,2′-diamino-4,4′-bi-1,3-thiazole)lead(II)] tetrahydrate |
| title_fullStr | Bis(μ-iminodiacetato)bis[(2,2′-diamino-4,4′-bi-1,3-thiazole)lead(II)] tetrahydrate |
| title_full_unstemmed | Bis(μ-iminodiacetato)bis[(2,2′-diamino-4,4′-bi-1,3-thiazole)lead(II)] tetrahydrate |
| title_short | Bis(μ-iminodiacetato)bis[(2,2′-diamino-4,4′-bi-1,3-thiazole)lead(II)] tetrahydrate |
| title_sort | bis amp 956 iminodiacetato bis 2 2 amp 8242 diamino 4 4 amp 8242 bi 1 3 thiazole lead ii tetrahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810006926 |
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