Ba2-x PbxCa2Cu3O8+δ Superconductors Up 99K

In the present study the effect of replacement of Pb at the Ba place in the oxygen deficient BaO layer of Ba2-x PbxCa2Cu3O8+δ with (0≤x≤0.3) cuprate superconductor has been investigated. Bulk polycrystalline specimens have been prepared by the solid state reaction process. Four probes technique is u...

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Main Author: Shatha Hashim Mahdi
Format: Article
Language:English
Published: Unviversity of Technology- Iraq 2016-04-01
Series:Engineering and Technology Journal
Subjects:
Online Access:https://etj.uotechnology.edu.iq/article_116213_27dbb8a1c44df68eafa4c9cff680d08a.pdf
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author Shatha Hashim Mahdi
author_facet Shatha Hashim Mahdi
author_sort Shatha Hashim Mahdi
collection DOAJ
description In the present study the effect of replacement of Pb at the Ba place in the oxygen deficient BaO layer of Ba2-x PbxCa2Cu3O8+δ with (0≤x≤0.3) cuprate superconductor has been investigated. Bulk polycrystalline specimens have been prepared by the solid state reaction process. Four probes technique is used to find the Tc. The highest Tc(offset) were 88, <77, 97and 99 K for all specimens with x = 0.0, 0.1, 0.2, and 0.3 respectively.The optimum Tc(off) of ~ 99 K and Tc(onset) ~ 106.38K has been found for the composition Ba1.7 Pb0.3Ca2Cu3O8+δ. X-ray diffraction analysis showed an orthorhombic arrangement with an increase of the c-axis for the specimens substitution with Pb as compared with those of no Pb content. The change of thePb content of all specimens created a change in the volume of the unit cell which has an important effect to obtain the superconductor state.
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spelling doaj.art-2dba339461b342b28f46c7fa56505eee2024-02-04T17:27:33ZengUnviversity of Technology- IraqEngineering and Technology Journal1681-69002412-07582016-04-01344B56056510.30684/etj.34.4B.14116213Ba2-x PbxCa2Cu3O8+δ Superconductors Up 99KShatha Hashim MahdiIn the present study the effect of replacement of Pb at the Ba place in the oxygen deficient BaO layer of Ba2-x PbxCa2Cu3O8+δ with (0≤x≤0.3) cuprate superconductor has been investigated. Bulk polycrystalline specimens have been prepared by the solid state reaction process. Four probes technique is used to find the Tc. The highest Tc(offset) were 88, <77, 97and 99 K for all specimens with x = 0.0, 0.1, 0.2, and 0.3 respectively.The optimum Tc(off) of ~ 99 K and Tc(onset) ~ 106.38K has been found for the composition Ba1.7 Pb0.3Ca2Cu3O8+δ. X-ray diffraction analysis showed an orthorhombic arrangement with an increase of the c-axis for the specimens substitution with Pb as compared with those of no Pb content. The change of thePb content of all specimens created a change in the volume of the unit cell which has an important effect to obtain the superconductor state.https://etj.uotechnology.edu.iq/article_116213_27dbb8a1c44df68eafa4c9cff680d08a.pdfsuperconducting transition temperature tcelectrical resistivitypb contentx pbxca
spellingShingle Shatha Hashim Mahdi
Ba2-x PbxCa2Cu3O8+δ Superconductors Up 99K
Engineering and Technology Journal
superconducting transition temperature tc
electrical resistivity
pb content
x pbxca
title Ba2-x PbxCa2Cu3O8+δ Superconductors Up 99K
title_full Ba2-x PbxCa2Cu3O8+δ Superconductors Up 99K
title_fullStr Ba2-x PbxCa2Cu3O8+δ Superconductors Up 99K
title_full_unstemmed Ba2-x PbxCa2Cu3O8+δ Superconductors Up 99K
title_short Ba2-x PbxCa2Cu3O8+δ Superconductors Up 99K
title_sort ba2 x pbxca2cu3o8 δ superconductors up 99k
topic superconducting transition temperature tc
electrical resistivity
pb content
x pbxca
url https://etj.uotechnology.edu.iq/article_116213_27dbb8a1c44df68eafa4c9cff680d08a.pdf
work_keys_str_mv AT shathahashimmahdi ba2xpbxca2cu3o8dsuperconductorsup99k