Enantiomers of 2,2'-Spirobichromenes: Energy Barrier for Thermal Racemization during HPLC on Tribenzoylcellulose

As a first case in the field of spirochromenes, the energy barrier for thermally reversible ring opening of 2,2'-spirobichromenes (Scheme) is measured by racemization of preparatively enriched enantiomers. In addition, this barrier is estimated via racemization during HPLC (Fig.) on tribenzoyl...

Full description

Bibliographic Details
Main Authors: Barbara Stephan, Herbert Zinner, Fritz Kastner, Albrecht Mannschreck
Format: Article
Language:deu
Published: Swiss Chemical Society 1990-10-01
Series:CHIMIA
Online Access:https://ojs.chimia.ch/chimia/article/view/1955