Zn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds
Selective cleavage of C-C bonds is very important in organic chemistry, but remains challenging because of their inert chemical nature. Here, the authors report that Zn2+ coordinated with N species on N-doped carbon catalysts can catalyze the aerobic oxidative cleavage and esterification of C(CO)-C...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2021-08-01
|
| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-021-25118-0 |
| _version_ | 1818694516296646656 |
|---|---|
| author | Chao Xie Longfei Lin Liang Huang Zixin Wang Zhiwei Jiang Zehui Zhang Buxing Han |
| author_facet | Chao Xie Longfei Lin Liang Huang Zixin Wang Zhiwei Jiang Zehui Zhang Buxing Han |
| author_sort | Chao Xie |
| collection | DOAJ |
| description | Selective cleavage of C-C bonds is very important in organic chemistry, but remains challenging because of their inert chemical nature. Here, the authors report that Zn2+ coordinated with N species on N-doped carbon catalysts can catalyze the aerobic oxidative cleavage and esterification of C(CO)-C bonds with high efficiency and activity. |
| first_indexed | 2024-12-17T13:30:49Z |
| format | Article |
| id | doaj.art-2dd1a821edf24b8ba22b396262c2f43e |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-17T13:30:49Z |
| publishDate | 2021-08-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-2dd1a821edf24b8ba22b396262c2f43e2022-12-21T21:46:34ZengNature PortfolioNature Communications2041-17232021-08-0112111210.1038/s41467-021-25118-0Zn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bondsChao Xie0Longfei Lin1Liang Huang2Zixin Wang3Zhiwei Jiang4Zehui Zhang5Buxing Han6Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education & Hubei Key Laboratory of Catalysis and Materials Science, South-Central University for NationalitiesBeijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of SciencesThe State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and TechnologyKey Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education & Hubei Key Laboratory of Catalysis and Materials Science, South-Central University for NationalitiesKey Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education & Hubei Key Laboratory of Catalysis and Materials Science, South-Central University for NationalitiesKey Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education & Hubei Key Laboratory of Catalysis and Materials Science, South-Central University for NationalitiesBeijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of SciencesSelective cleavage of C-C bonds is very important in organic chemistry, but remains challenging because of their inert chemical nature. Here, the authors report that Zn2+ coordinated with N species on N-doped carbon catalysts can catalyze the aerobic oxidative cleavage and esterification of C(CO)-C bonds with high efficiency and activity.https://doi.org/10.1038/s41467-021-25118-0 |
| spellingShingle | Chao Xie Longfei Lin Liang Huang Zixin Wang Zhiwei Jiang Zehui Zhang Buxing Han Zn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds Nature Communications |
| title | Zn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds |
| title_full | Zn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds |
| title_fullStr | Zn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds |
| title_full_unstemmed | Zn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds |
| title_short | Zn-Nx sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds |
| title_sort | zn nx sites on n doped carbon for aerobic oxidative cleavage and esterification of c co c bonds |
| url | https://doi.org/10.1038/s41467-021-25118-0 |
| work_keys_str_mv | AT chaoxie znnxsitesonndopedcarbonforaerobicoxidativecleavageandesterificationofccocbonds AT longfeilin znnxsitesonndopedcarbonforaerobicoxidativecleavageandesterificationofccocbonds AT lianghuang znnxsitesonndopedcarbonforaerobicoxidativecleavageandesterificationofccocbonds AT zixinwang znnxsitesonndopedcarbonforaerobicoxidativecleavageandesterificationofccocbonds AT zhiweijiang znnxsitesonndopedcarbonforaerobicoxidativecleavageandesterificationofccocbonds AT zehuizhang znnxsitesonndopedcarbonforaerobicoxidativecleavageandesterificationofccocbonds AT buxinghan znnxsitesonndopedcarbonforaerobicoxidativecleavageandesterificationofccocbonds |