Crystal structure of 5-chloro-N1-(5-phenyl-1H-pyrazol-3-yl)benzene-1,2-diamine

Crystal structure of 5-chloro-N1-(5-phenyl-1H-pyrazol-3-yl)benzene-1,2-diamine

The title compound, C15H13ClN4, crystallizes with two independent molecules (A and B) in the asymmetric unit, which are far from planar as a result of steric repulsion between the rings. The benzene and phenyl rings are inclined to the central pyrazole ring by 46.64 (10) and 17.87 (10)° in molecule...

Full description

Bibliographic Details
Main Authors:	Yegor Yartsev, Vitaliy Palchikov, Alexandr Gaponov, Svitlana Shishkina
Format:	Article
Language:	English
Published:	International Union of Crystallography 2017-06-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	crystal structure pyrazol-3-amine steric repulsion hydrogen bonding
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2056989017007381

Similar Items

5-Chloro-4-iodo-1,3-dimethyl-1H-pyrazole
by: Gytė Vilkauskaitė, et al.
Published: (2009-09-01)

Antimicrobial screening and one-pot synthesis of 4-(substituted-anilinomethyl)-3-(2-naphthyl)-1-phenyl-1H-pyrazole derivatives
by: Neelima Goel, et al.
Published: (2014-01-01)

Synthesis, Crystal Structure, and Supramolecular Understanding of 1,3,5-Tris(1-phenyl-1H-pyrazol-5-yl)benzenes
by: Marcos A. P. Martins, et al.
Published: (2017-12-01)

Crystal structure of 5-[4-(dimethylamino)phenyl]-3-(4-methylphenyl)-4,5-dihydro-1H-pyrazole-1-carbaldehyde
by: Farook Adam, et al.
Published: (2015-12-01)

3-(3,5-Difluorophenyl)-1-phenyl-1H-pyrazole-4-carbaldehyde
by: Naveen Kumar, et al.
Published: (2018-08-01)

5-(2,3-Dichlorophenyl)-3-(4-methoxyphenyl)-1-phenyl-4,5-dihydro-1H-pyrazole
by: D. M. Lokeshwari, et al.
Published: (2017-01-01)

3-Methyl-5-(4-methylphenoxy)-1-phenyl-1H-pyrazole-4-carbaldehyde
by: Sreeramapura D. Archana, et al.
Published: (2022-09-01)

Synthesis, Characterization and Biological Activity of Some New 4-Substituted-phenyl-3-chloro-1-{5-[(3, 5-dimethyl-1H-pyrazol-1- yl) methyl]-1, 3, 4-thiadiazol-2-yl} azetidin-2-one
by: Rafah Fadhil Al-Smaisim
Published: (2012-12-01)

3-Methyl-5-(4-methylpiperazin-1-yl)-1-phenyl-1H-pyrazole-4-carbaldehyde
by: V. M. Sunitha, et al.
Published: (2016-11-01)

Design, Synthesis and Anti-Tobacco Mosaic Virus (TMV) Activity of 5-Chloro-N-(4-cyano-1-aryl-1H-pyrazol-5-yl)-1-aryl-3-methyl-1H-pyrazole-4-carboxamide Derivatives
by: Jin-Jing Xiao, et al.
Published: (2015-01-01)

2-(5-Chloro-3-methyl-1-phenyl-1H-pyrazol-4-yl)-6-(4-nitrophenyl)-4-phenyl-1,3-diazabicyclo[3.1.0]hex-3-ene
by: Hamzeh Kiyani, et al.
Published: (2013-07-01)

Low-temperature crystal structure of 4-chloro-1H-pyrazole
by: Kelly Rue, et al.
Published: (2021-09-01)

4-{[(3,5-dimethyl-1H-pyrazol-1-yl)methyl]amino}benzoic acid
by: Abdelkrim Ramdani, et al.
Published: (2004-02-01)

1-(2-ethoxy-2-oxoethyl)-5-methyl-1H-pyrazole-3-methyl carboxylate
by: Maryse Bacquet, et al.
Published: (2007-05-01)

1-(2-ethoxy-2-oxoethyl)-5-methyl-1H-pyrazole-3-ethyl carboxylate
by: Maryse Bacquet, et al.
Published: (2007-05-01)

1,2,3,5-Tetramethyl-1H-pyrazol-2-ium triiodide
by: Stefan Oberparleiter, et al.
Published: (2016-08-01)

3-(4-Chlorophenyl)-5-[4-(methylsulfanyl)phenyl]-1H-pyrazole
by: Ganesan Suresh, et al.
Published: (2016-04-01)

5-Methyl-4-(3-methyl-1-phenyl-1H-pyrazol-4-yl)-2-phenyl-2,3-dihydro-1H-pyrazol-3-one
by: Ismail Ghandour, et al.
Published: (2017-06-01)

N-(5-Phenyl-1H-pyrazol-3-yl)benzene-1,2-diamine
by: Mohamadou Lamine Doumbia, et al.
Published: (2010-04-01)

5-(2,4-Dichlorophenoxy)-3-methyl-1-phenyl-1H-pyrazole-4-carbaldehyde
by: S. Madan Kumar, et al.
Published: (2016-07-01)

Synthesis and Herbicidal Activity of 5-Heterocycloxy-3-methyl-1-substituted-1H-pyrazoles
by: Jing Kang, et al.
Published: (2015-12-01)

Synthesis of tridentate Nitrogen Ligand : N,N-bis-(3,5-dimethylpyrazol-1-ylmethyl)benzylamine (NNNN)
by: Mohamed Mchich, et al.
Published: (2006-02-01)

One-Pot Synthesis and Crystal Structure of Methyl 5-Hydroxy-1-phenyl-1H-pyrazole-3-carboxylate
by: Aamer Saeed, et al.
Published: (2012-08-01)

3,4,5,6,7,8,9-Heptachlorophenaleno[1,9-bc]pyrazole
by: Polina K. Demetriadou, et al.
Published: (2009-10-01)

Ethyl 3-methyl-1-phenyl-5-(p-tolyl)-1H-pyrazole-4-carboxylate
by: S. Naveen, et al.
Published: (2016-12-01)

5-Acetamido-1H-pyrazole-4-carboxamide monohydrate
by: Lhoussaine El Ghayati, et al.
Published: (2016-06-01)

Synthesis and biological evaluation of 1-(5-(2-chloroquinolin-3-yl)-3-phenyl-1H-pyrazol-1-yl)ethanone derivatives as potential antimicrobial agents
by: Pankaj B. Miniyar, et al.
Published: (2015-11-01)

(3,5-Di-<i>tert</i>-butylphenyl)(1<i>H</i>-pyrazol-1-yl)methanone
by: Katrina E. Doherty, et al.
Published: (2022-10-01)

(4S,5R)-3-(4-Chlorophenyl)-5-(4-methoxyphenyl)-4-methyl-1-phenyl-4,5-dihydro-1H-pyrazole
by: Yahya Ben Soumane, et al.
Published: (2016-06-01)

N-{2-[2-(5-Methyl-1H-pyrazol-3-yl)acetamido]phenyl}benzamide monohydrate
by: Karim Chkirate, et al.
Published: (2017-02-01)

Crystal structure of 3-(4-methylphenyl)-1-phenyl-5-[(E)-2-phenylethenyl]-1H-pyrazole
by: Farook Adam, et al.
Published: (2015-12-01)

Crystal structure of 3-methyl-1-phenyl-5-(1H-pyrrol-1-yl)-1H-pyrazole-4-carbaldehyde
by: Joel T. Mague, et al.
Published: (2014-10-01)

5-[(4-Chlorophenyl)diazenyl]-2-[5-(4-fluorophenyl)-3-(furan-2-yl)-4,5-dihydro-1H-pyrazol-1-yl]-4-methylthiazole
by: Gamal A El-Hiti, et al.
Published: (2019-02-01)

N′-[(1E)-4-Bromobenzylidene]-5-phenyl-1H-pyrazole-3-carbohydrazide
by: Khalid Karrouchi, et al.
Published: (2016-05-01)

5-(4-Methoxyphenyl)-1-[4-(4-methoxyphenyl)thiazol-2-yl]-3-[4-(prop-2-ynyloxy)phenyl]-4,5-dihydro-1H-pyrazole
by: Sreeramapura D. Archana, et al.
Published: (2022-11-01)

Does the Presence of a Bond Path Really Mean Interatomic Stabilization? The Case of the Ng@Superphane (Ng = He, Ne, Ar, and Kr) Endohedral Complexes
by: Mirosław Jabłoński
Published: (2021-11-01)

4-(3-Methylphenyl)-3-[(3-methyl-5-phenyl-1H-pyrazol-1-yl)methyl]-4,5-dihydro-1H-1,2,4-triazole-5-thione
by: Joel T. Mague, et al.
Published: (2017-02-01)

Antipyretic and antioxidant activities of 5-trifluoromethyl-4,5-dihydro-1H-pyrazoles in rats
by: J.S.M. Pasin, et al.
Published: (2010-12-01)

Crystal structure of 1-(2,4-dinitrophenyl)-3,5-diphenyl-1H-pyrazole
by: Shaaban K. Mohamed, et al.
Published: (2015-12-01)

3-(2,5-Dichlorothiophen-3-yl)-5-(2,4-dimethoxyphenyl)-1-methyl-4,5-dihydro-1H-pyrazole
by: Mohammad M. Ibrahim, et al.
Published: (2019-07-01)