THE ELECTROCONDUCTIVITY OF THE LIQUID ALLOYS OF TRANSITION METALS

The concentration dependance of electroresistivity of the liquid binary alloys of transition metals Fe, Co and Ni is calculated. We considered the contribution to conductivity from the s-electrons, described within the model of nearly free electrons. The role of the partially occupied d-bands is red...

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Main Authors: V.T.Shvets, S.V.Savenko, S.V.Datsko
Format: Article
Language:English
Published: Institute for Condensed Matter Physics 2004-01-01
Series:Condensed Matter Physics
Subjects:
Online Access:http://dx.doi.org/10.5488/CMP.7.2.275
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author V.T.Shvets
S.V.Savenko
S.V.Datsko
author_facet V.T.Shvets
S.V.Savenko
S.V.Datsko
author_sort V.T.Shvets
collection DOAJ
description The concentration dependance of electroresistivity of the liquid binary alloys of transition metals Fe, Co and Ni is calculated. We considered the contribution to conductivity from the s-electrons, described within the model of nearly free electrons. The role of the partially occupied d-bands is reduced to resonance scattering of the s-electrons on d-states. The interaction of the s- and d-electrons is described by the hybridization potential of s- and d-states. The interaction with the ions, not including the partially occupied d-states, is described using the pseudopotential of the electron-ion interaction. The electroresistivity of the alloys is calculated in the second order of the perturbation theory in pseudopotential and hybridization potential. The concentration dependance of electroresistivity of the binary alloys approaches the linear regime as the resonance scattering of the s-electrons on d-states prevails over the scattering on the ions. The calculations exhibit good agreement with the experimental data.
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spelling doaj.art-2de8d7f7cef040dcb199985f5566690c2022-12-22T02:52:20ZengInstitute for Condensed Matter PhysicsCondensed Matter Physics1607-324X2004-01-017227528410.5488/CMP.7.2.275THE ELECTROCONDUCTIVITY OF THE LIQUID ALLOYS OF TRANSITION METALSV.T.ShvetsS.V.SavenkoS.V.DatskoThe concentration dependance of electroresistivity of the liquid binary alloys of transition metals Fe, Co and Ni is calculated. We considered the contribution to conductivity from the s-electrons, described within the model of nearly free electrons. The role of the partially occupied d-bands is reduced to resonance scattering of the s-electrons on d-states. The interaction of the s- and d-electrons is described by the hybridization potential of s- and d-states. The interaction with the ions, not including the partially occupied d-states, is described using the pseudopotential of the electron-ion interaction. The electroresistivity of the alloys is calculated in the second order of the perturbation theory in pseudopotential and hybridization potential. The concentration dependance of electroresistivity of the binary alloys approaches the linear regime as the resonance scattering of the s-electrons on d-states prevails over the scattering on the ions. The calculations exhibit good agreement with the experimental data.http://dx.doi.org/10.5488/CMP.7.2.275electroresistivity of alloysliquid transition metals
spellingShingle V.T.Shvets
S.V.Savenko
S.V.Datsko
THE ELECTROCONDUCTIVITY OF THE LIQUID ALLOYS OF TRANSITION METALS
Condensed Matter Physics
electroresistivity of alloys
liquid transition metals
title THE ELECTROCONDUCTIVITY OF THE LIQUID ALLOYS OF TRANSITION METALS
title_full THE ELECTROCONDUCTIVITY OF THE LIQUID ALLOYS OF TRANSITION METALS
title_fullStr THE ELECTROCONDUCTIVITY OF THE LIQUID ALLOYS OF TRANSITION METALS
title_full_unstemmed THE ELECTROCONDUCTIVITY OF THE LIQUID ALLOYS OF TRANSITION METALS
title_short THE ELECTROCONDUCTIVITY OF THE LIQUID ALLOYS OF TRANSITION METALS
title_sort electroconductivity of the liquid alloys of transition metals
topic electroresistivity of alloys
liquid transition metals
url http://dx.doi.org/10.5488/CMP.7.2.275
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