Electrocoagulation vs. Integrate Electrocoagulation-Natural Zeolite for Treatment of Biowaste Compost Leachate—Whether the Optimum Is Truly Optimal

Natural zeolites are well-known materials widely applied in the environmental remediation treatment process. However, the integration of various treatment methods is exceedingly investigated for achieving satisfactory effluent quality. In this paper, the integration of electrocoagulation and natural...

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Main Authors: Nediljka Vukojević Medvidović, Ladislav Vrsalović, Sandra Svilović, Anđela Bobanović
Format: Article
Language:English
Published: MDPI AG 2022-04-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/12/4/442
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author Nediljka Vukojević Medvidović
Ladislav Vrsalović
Sandra Svilović
Anđela Bobanović
author_facet Nediljka Vukojević Medvidović
Ladislav Vrsalović
Sandra Svilović
Anđela Bobanović
author_sort Nediljka Vukojević Medvidović
collection DOAJ
description Natural zeolites are well-known materials widely applied in the environmental remediation treatment process. However, the integration of various treatment methods is exceedingly investigated for achieving satisfactory effluent quality. In this paper, the integration of electrocoagulation and natural zeolite was evaluated in the treatment of biowaste compost leachate in a single step. The influence of different distances of electrodes (1.5, 3, and 4.5 cm), stirring speed (70, 200, and 400 rpm), the addition of natural zeolite and electrolyte NaCl on the efficiency of treatment of biowaste compost leachate has been carried out. Process efficiency was evaluated by measuring the change of pH value, electrical conductivity, temperature, turbidity, chemical oxygen demand (COD), total Kjeldahl nitrogen (TN<sub>K</sub>), total solids, and sludge settling test. The Taguchi method was applied to optimize biowaste compost leachate treatment. Experiments are planned according to Taguchi’s L8 (2<sup>4</sup> 4<sup>1</sup>) orthogonal array. The stirring speed, electrode distance, electrolyte and zeolite addition, solution initial pH adjustment were chosen as controllable factors, and their impact on COD, turbidity, TN<sub>K</sub>, settling rate, and electrode consumption were studied. Results show that optimal conditions depend on the parameter of interest and that optimal values for a particular parameter are not always the optimum if the desired goal is considered.
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spelling doaj.art-2e0c4c1ee3e94f5d846b82b1fa1513c52023-12-01T21:15:34ZengMDPI AGMinerals2075-163X2022-04-0112444210.3390/min12040442Electrocoagulation vs. Integrate Electrocoagulation-Natural Zeolite for Treatment of Biowaste Compost Leachate—Whether the Optimum Is Truly OptimalNediljka Vukojević Medvidović0Ladislav Vrsalović1Sandra Svilović2Anđela Bobanović3Department of Environmental Engineering, Faculty of Chemistry and Technology, University of Split, 21000 Split, CroatiaDepartment of Electrochemistry and Materials Protection, Faculty of Chemistry and Technology, University of Split, 21000 Split, CroatiaDepartment of Chemical Engineering, Faculty of Chemistry and Technology, University of Split, 21000 Split, CroatiaŽuvela d.o.o., 21450 Hvar, CroatiaNatural zeolites are well-known materials widely applied in the environmental remediation treatment process. However, the integration of various treatment methods is exceedingly investigated for achieving satisfactory effluent quality. In this paper, the integration of electrocoagulation and natural zeolite was evaluated in the treatment of biowaste compost leachate in a single step. The influence of different distances of electrodes (1.5, 3, and 4.5 cm), stirring speed (70, 200, and 400 rpm), the addition of natural zeolite and electrolyte NaCl on the efficiency of treatment of biowaste compost leachate has been carried out. Process efficiency was evaluated by measuring the change of pH value, electrical conductivity, temperature, turbidity, chemical oxygen demand (COD), total Kjeldahl nitrogen (TN<sub>K</sub>), total solids, and sludge settling test. The Taguchi method was applied to optimize biowaste compost leachate treatment. Experiments are planned according to Taguchi’s L8 (2<sup>4</sup> 4<sup>1</sup>) orthogonal array. The stirring speed, electrode distance, electrolyte and zeolite addition, solution initial pH adjustment were chosen as controllable factors, and their impact on COD, turbidity, TN<sub>K</sub>, settling rate, and electrode consumption were studied. Results show that optimal conditions depend on the parameter of interest and that optimal values for a particular parameter are not always the optimum if the desired goal is considered.https://www.mdpi.com/2075-163X/12/4/442natural zeoliteintegration of zeolite with electrocoagulationbiowaste compost leachateremoval efficiencyTaguchi optimization
spellingShingle Nediljka Vukojević Medvidović
Ladislav Vrsalović
Sandra Svilović
Anđela Bobanović
Electrocoagulation vs. Integrate Electrocoagulation-Natural Zeolite for Treatment of Biowaste Compost Leachate—Whether the Optimum Is Truly Optimal
Minerals
natural zeolite
integration of zeolite with electrocoagulation
biowaste compost leachate
removal efficiency
Taguchi optimization
title Electrocoagulation vs. Integrate Electrocoagulation-Natural Zeolite for Treatment of Biowaste Compost Leachate—Whether the Optimum Is Truly Optimal
title_full Electrocoagulation vs. Integrate Electrocoagulation-Natural Zeolite for Treatment of Biowaste Compost Leachate—Whether the Optimum Is Truly Optimal
title_fullStr Electrocoagulation vs. Integrate Electrocoagulation-Natural Zeolite for Treatment of Biowaste Compost Leachate—Whether the Optimum Is Truly Optimal
title_full_unstemmed Electrocoagulation vs. Integrate Electrocoagulation-Natural Zeolite for Treatment of Biowaste Compost Leachate—Whether the Optimum Is Truly Optimal
title_short Electrocoagulation vs. Integrate Electrocoagulation-Natural Zeolite for Treatment of Biowaste Compost Leachate—Whether the Optimum Is Truly Optimal
title_sort electrocoagulation vs integrate electrocoagulation natural zeolite for treatment of biowaste compost leachate whether the optimum is truly optimal
topic natural zeolite
integration of zeolite with electrocoagulation
biowaste compost leachate
removal efficiency
Taguchi optimization
url https://www.mdpi.com/2075-163X/12/4/442
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AT sandrasvilovic electrocoagulationvsintegrateelectrocoagulationnaturalzeolitefortreatmentofbiowastecompostleachatewhethertheoptimumistrulyoptimal
AT anđelabobanovic electrocoagulationvsintegrateelectrocoagulationnaturalzeolitefortreatmentofbiowastecompostleachatewhethertheoptimumistrulyoptimal