4-[5-(4-Chlorophenyl)-3-methyl-1H-pyrazol-1-yl]benzenesulfonamide
In the title compound, C16H14ClN3O2S, the dihedral angle between the benzene and pyrazole rings is 52.75 (2)°, while that between the pyrazole and 4-chlorophenyl rings is 54.0 (3)°. The terminal sulfonamide group adopts an approximately tetrahedral geometry abou...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813002134 |
| _version_ | 1828129805162250240 |
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| author | Muhammad A. Farrukh Shaaban K. Mohamed Maqsood Ahmed Adel A. Marzouk Samir M. El-Moghazy |
| author_facet | Muhammad A. Farrukh Shaaban K. Mohamed Maqsood Ahmed Adel A. Marzouk Samir M. El-Moghazy |
| author_sort | Muhammad A. Farrukh |
| collection | DOAJ |
| description | In the title compound, C16H14ClN3O2S, the dihedral angle between the benzene and pyrazole rings is 52.75 (2)°, while that between the pyrazole and 4-chlorophenyl rings is 54.0 (3)°. The terminal sulfonamide group adopts an approximately tetrahedral geometry about the S atom with a C—S—N angle of 108.33 (10)°. In the crystal, pairs of N—H...N hydrogen bonds lead to the formation of inversion dimers. These dimers are linked via a second pair of N—H...N hydrogen bonds and C—H...O interactions, forming a two-dimensional network lying parallel to the bc plane. The two-dimensional networks are linked via C—H...Cl interactions, forming a three-dimensional structure. |
| first_indexed | 2024-04-11T16:25:24Z |
| format | Article |
| id | doaj.art-2e29b63e6d76429b858ccb77789ef63e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:25:24Z |
| publishDate | 2013-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-2e29b63e6d76429b858ccb77789ef63e2022-12-22T04:14:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-02-01692o295o29610.1107/S16005368130021344-[5-(4-Chlorophenyl)-3-methyl-1H-pyrazol-1-yl]benzenesulfonamideMuhammad A. FarrukhShaaban K. MohamedMaqsood AhmedAdel A. MarzoukSamir M. El-MoghazyIn the title compound, C16H14ClN3O2S, the dihedral angle between the benzene and pyrazole rings is 52.75 (2)°, while that between the pyrazole and 4-chlorophenyl rings is 54.0 (3)°. The terminal sulfonamide group adopts an approximately tetrahedral geometry about the S atom with a C—S—N angle of 108.33 (10)°. In the crystal, pairs of N—H...N hydrogen bonds lead to the formation of inversion dimers. These dimers are linked via a second pair of N—H...N hydrogen bonds and C—H...O interactions, forming a two-dimensional network lying parallel to the bc plane. The two-dimensional networks are linked via C—H...Cl interactions, forming a three-dimensional structure.http://scripts.iucr.org/cgi-bin/paper?S1600536813002134 |
| spellingShingle | Muhammad A. Farrukh Shaaban K. Mohamed Maqsood Ahmed Adel A. Marzouk Samir M. El-Moghazy 4-[5-(4-Chlorophenyl)-3-methyl-1H-pyrazol-1-yl]benzenesulfonamide Acta Crystallographica Section E |
| title | 4-[5-(4-Chlorophenyl)-3-methyl-1H-pyrazol-1-yl]benzenesulfonamide |
| title_full | 4-[5-(4-Chlorophenyl)-3-methyl-1H-pyrazol-1-yl]benzenesulfonamide |
| title_fullStr | 4-[5-(4-Chlorophenyl)-3-methyl-1H-pyrazol-1-yl]benzenesulfonamide |
| title_full_unstemmed | 4-[5-(4-Chlorophenyl)-3-methyl-1H-pyrazol-1-yl]benzenesulfonamide |
| title_short | 4-[5-(4-Chlorophenyl)-3-methyl-1H-pyrazol-1-yl]benzenesulfonamide |
| title_sort | 4 5 4 chlorophenyl 3 methyl 1h pyrazol 1 yl benzenesulfonamide |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813002134 |
| work_keys_str_mv | AT muhammadafarrukh 454chlorophenyl3methyl1hpyrazol1ylbenzenesulfonamide AT shaabankmohamed 454chlorophenyl3methyl1hpyrazol1ylbenzenesulfonamide AT maqsoodahmed 454chlorophenyl3methyl1hpyrazol1ylbenzenesulfonamide AT adelamarzouk 454chlorophenyl3methyl1hpyrazol1ylbenzenesulfonamide AT samirmelmoghazy 454chlorophenyl3methyl1hpyrazol1ylbenzenesulfonamide |