(Acetone-κO){6,6′-di-tert-butyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}zinc(II)
The molecule of the title compound, [Zn(C28H30N2O2)(CH3COCH3)], lies across a mirror plane with the ZnII ion and the acetone molecule on the mirror plane. The ZnII ion is in a five-coordinate distorted square-pyramidal N2O3 environment, with the two imine N and two phenolic O atoms of the tetradenta...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808011215 |
| _version_ | 1819290898282840064 |
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| author | Rohana Adnan Hoong-Kun Fun Suchada Chantrapromma Siang Guan Teoh Naser Eltaher Eltayeb |
| author_facet | Rohana Adnan Hoong-Kun Fun Suchada Chantrapromma Siang Guan Teoh Naser Eltaher Eltayeb |
| author_sort | Rohana Adnan |
| collection | DOAJ |
| description | The molecule of the title compound, [Zn(C28H30N2O2)(CH3COCH3)], lies across a mirror plane with the ZnII ion and the acetone molecule on the mirror plane. The ZnII ion is in a five-coordinate distorted square-pyramidal N2O3 environment, with the two imine N and two phenolic O atoms of the tetradentate Schiff base dianion in the basal plane and the acetone molecule in the apical position. The central benzene ring makes a dihedral angle of 16.5 (2)° with the two outer phenolate rings. In the crystal structure, the molecules are arranged into antiparallel columns along the a axis. |
| first_indexed | 2024-12-24T03:30:03Z |
| format | Article |
| id | doaj.art-2e30005275d948baa829cd18e474ba48 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:30:03Z |
| publishDate | 2008-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-2e30005275d948baa829cd18e474ba482022-12-21T17:17:13ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-05-01645m738m73910.1107/S1600536808011215(Acetone-κO){6,6′-di-tert-butyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}zinc(II)Rohana AdnanHoong-Kun FunSuchada ChantraprommaSiang Guan TeohNaser Eltaher EltayebThe molecule of the title compound, [Zn(C28H30N2O2)(CH3COCH3)], lies across a mirror plane with the ZnII ion and the acetone molecule on the mirror plane. The ZnII ion is in a five-coordinate distorted square-pyramidal N2O3 environment, with the two imine N and two phenolic O atoms of the tetradentate Schiff base dianion in the basal plane and the acetone molecule in the apical position. The central benzene ring makes a dihedral angle of 16.5 (2)° with the two outer phenolate rings. In the crystal structure, the molecules are arranged into antiparallel columns along the a axis.http://scripts.iucr.org/cgi-bin/paper?S1600536808011215 |
| spellingShingle | Rohana Adnan Hoong-Kun Fun Suchada Chantrapromma Siang Guan Teoh Naser Eltaher Eltayeb (Acetone-κO){6,6′-di-tert-butyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}zinc(II) Acta Crystallographica Section E |
| title | (Acetone-κO){6,6′-di-tert-butyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}zinc(II) |
| title_full | (Acetone-κO){6,6′-di-tert-butyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}zinc(II) |
| title_fullStr | (Acetone-κO){6,6′-di-tert-butyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}zinc(II) |
| title_full_unstemmed | (Acetone-κO){6,6′-di-tert-butyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}zinc(II) |
| title_short | (Acetone-κO){6,6′-di-tert-butyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}zinc(II) |
| title_sort | acetone 954 o 6 6 8242 di tert butyl 2 2 8242 1 2 phenylenebis nitrilomethylidyne diphenolato 954 4o n n 8242 o 8242 zinc ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808011215 |
| work_keys_str_mv | AT rohanaadnan acetone954o668242ditertbutyl22824212phenylenebisnitrilomethylidynediphenolato9544onn8242o8242zincii AT hoongkunfun acetone954o668242ditertbutyl22824212phenylenebisnitrilomethylidynediphenolato9544onn8242o8242zincii AT suchadachantrapromma acetone954o668242ditertbutyl22824212phenylenebisnitrilomethylidynediphenolato9544onn8242o8242zincii AT siangguanteoh acetone954o668242ditertbutyl22824212phenylenebisnitrilomethylidynediphenolato9544onn8242o8242zincii AT nasereltahereltayeb acetone954o668242ditertbutyl22824212phenylenebisnitrilomethylidynediphenolato9544onn8242o8242zincii |