Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)]
The title compound, [Mn2(HO3PCH2CH2COO)2(C8H8N2)2(H2O)2], was obtained by hydrothermal synthesis. The manganese(II) ions are six-coordinate and are linked by two 2-carboxyethylphosphonate ligands, forming a centrosymmetric dimer. The Mn ions adopts a distorted octahedral coordination geometry. The d...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807065142 |
| _version_ | 1831691468460261376 |
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| author | Shao-Ming Ying Yun Chen Qiu-Yan Luo Ya-Ping Xv Dong-Sheng Liu |
| author_facet | Shao-Ming Ying Yun Chen Qiu-Yan Luo Ya-Ping Xv Dong-Sheng Liu |
| author_sort | Shao-Ming Ying |
| collection | DOAJ |
| description | The title compound, [Mn2(HO3PCH2CH2COO)2(C8H8N2)2(H2O)2], was obtained by hydrothermal synthesis. The manganese(II) ions are six-coordinate and are linked by two 2-carboxyethylphosphonate ligands, forming a centrosymmetric dimer. The Mn ions adopts a distorted octahedral coordination geometry. The dimers are further linked by O—H...O hydrogen bonds and π–π stacking interactions [centroid–centroid distance 4.2754 (4) Å]. |
| first_indexed | 2024-12-20T11:31:21Z |
| format | Article |
| id | doaj.art-2e384324b6c74656b1a176241cecf8ee |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:31:21Z |
| publishDate | 2008-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-2e384324b6c74656b1a176241cecf8ee2022-12-21T19:42:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m166m16610.1107/S1600536807065142Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)]Shao-Ming YingYun ChenQiu-Yan LuoYa-Ping XvDong-Sheng LiuThe title compound, [Mn2(HO3PCH2CH2COO)2(C8H8N2)2(H2O)2], was obtained by hydrothermal synthesis. The manganese(II) ions are six-coordinate and are linked by two 2-carboxyethylphosphonate ligands, forming a centrosymmetric dimer. The Mn ions adopts a distorted octahedral coordination geometry. The dimers are further linked by O—H...O hydrogen bonds and π–π stacking interactions [centroid–centroid distance 4.2754 (4) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536807065142 |
| spellingShingle | Shao-Ming Ying Yun Chen Qiu-Yan Luo Ya-Ping Xv Dong-Sheng Liu Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)] Acta Crystallographica Section E |
| title | Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)] |
| title_full | Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)] |
| title_fullStr | Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)] |
| title_full_unstemmed | Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)] |
| title_short | Bis(μ-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)manganese(II)] |
| title_sort | bis 956 carboxylatoethylphosphonato bis aqua 2 2 8242 bipyridine manganese ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536807065142 |
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