Crystal Growth and Glass-Like Thermal Conductivity of Ca3RE2(BO3)4 (RE = Y, Gd, Nd) Single Crystals
Crystal growth and thermal properties of binary borates, Ca3RE2(BO3)4 (RE = Y, Gd, Nd), are considered promising crystals for laser applications. These single crystals were grown by the Czochralski method. The crystal and defect structure were characterized. Volumetric chemical methods without prior...
Main Authors: | , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2017-03-01
|
Series: | Crystals |
Subjects: | |
Online Access: | http://www.mdpi.com/2073-4352/7/3/88 |
_version_ | 1811187312102473728 |
---|---|
author | L. V. Gudzenko M. B. Kosmyna A. N. Shekhovtsov W. Paszkowicz A. Sulich J. Z. Domagała P. A. Popov S. A. Skrobov |
author_facet | L. V. Gudzenko M. B. Kosmyna A. N. Shekhovtsov W. Paszkowicz A. Sulich J. Z. Domagała P. A. Popov S. A. Skrobov |
author_sort | L. V. Gudzenko |
collection | DOAJ |
description | Crystal growth and thermal properties of binary borates, Ca3RE2(BO3)4 (RE = Y, Gd, Nd), are considered promising crystals for laser applications. These single crystals were grown by the Czochralski method. The crystal and defect structure were characterized. Volumetric chemical methods without prior separation of the components were developed and applied for the determination of the dependence of chemical compositions of the crystals on the growth conditions. The thermal conductivity was investigated in the 50–300 K range. The character of the temperature dependence of thermal conductivity was found to be similar to that of glass. The possible reasons of the observed features of the thermal conductivity were analyzed. |
first_indexed | 2024-04-11T14:01:16Z |
format | Article |
id | doaj.art-2e5a0a563cce4647b24d17e5313a4c9f |
institution | Directory Open Access Journal |
issn | 2073-4352 |
language | English |
last_indexed | 2024-04-11T14:01:16Z |
publishDate | 2017-03-01 |
publisher | MDPI AG |
record_format | Article |
series | Crystals |
spelling | doaj.art-2e5a0a563cce4647b24d17e5313a4c9f2022-12-22T04:20:07ZengMDPI AGCrystals2073-43522017-03-01738810.3390/cryst7030088cryst7030088Crystal Growth and Glass-Like Thermal Conductivity of Ca3RE2(BO3)4 (RE = Y, Gd, Nd) Single CrystalsL. V. Gudzenko0M. B. Kosmyna1A. N. Shekhovtsov2W. Paszkowicz3A. Sulich4J. Z. Domagała5P. A. Popov6S. A. Skrobov7Institute for Single Crystals, NASU, Nauki Ave. 60, 61001 Kharkov, UkraineInstitute for Single Crystals, NASU, Nauki Ave. 60, 61001 Kharkov, UkraineInstitute for Single Crystals, NASU, Nauki Ave. 60, 61001 Kharkov, UkraineInstitute of Physics, PAS, Aleja Lotników 32/46, PL- 02668 Warsaw, PolandInstitute of Physics, PAS, Aleja Lotników 32/46, PL- 02668 Warsaw, PolandInstitute of Physics, PAS, Aleja Lotników 32/46, PL- 02668 Warsaw, PolandDepartment of Exper. and Theor. Physics, Petrovsky Bryansk State University, Bezhitskaya Str. 14, 241036 Bryansk, RussiaDepartment of Exper. and Theor. Physics, Petrovsky Bryansk State University, Bezhitskaya Str. 14, 241036 Bryansk, RussiaCrystal growth and thermal properties of binary borates, Ca3RE2(BO3)4 (RE = Y, Gd, Nd), are considered promising crystals for laser applications. These single crystals were grown by the Czochralski method. The crystal and defect structure were characterized. Volumetric chemical methods without prior separation of the components were developed and applied for the determination of the dependence of chemical compositions of the crystals on the growth conditions. The thermal conductivity was investigated in the 50–300 K range. The character of the temperature dependence of thermal conductivity was found to be similar to that of glass. The possible reasons of the observed features of the thermal conductivity were analyzed.http://www.mdpi.com/2073-4352/7/3/88binary borateCzochralski methodcrystal compositionthermal conductivity |
spellingShingle | L. V. Gudzenko M. B. Kosmyna A. N. Shekhovtsov W. Paszkowicz A. Sulich J. Z. Domagała P. A. Popov S. A. Skrobov Crystal Growth and Glass-Like Thermal Conductivity of Ca3RE2(BO3)4 (RE = Y, Gd, Nd) Single Crystals Crystals binary borate Czochralski method crystal composition thermal conductivity |
title | Crystal Growth and Glass-Like Thermal Conductivity of Ca3RE2(BO3)4 (RE = Y, Gd, Nd) Single Crystals |
title_full | Crystal Growth and Glass-Like Thermal Conductivity of Ca3RE2(BO3)4 (RE = Y, Gd, Nd) Single Crystals |
title_fullStr | Crystal Growth and Glass-Like Thermal Conductivity of Ca3RE2(BO3)4 (RE = Y, Gd, Nd) Single Crystals |
title_full_unstemmed | Crystal Growth and Glass-Like Thermal Conductivity of Ca3RE2(BO3)4 (RE = Y, Gd, Nd) Single Crystals |
title_short | Crystal Growth and Glass-Like Thermal Conductivity of Ca3RE2(BO3)4 (RE = Y, Gd, Nd) Single Crystals |
title_sort | crystal growth and glass like thermal conductivity of ca3re2 bo3 4 re y gd nd single crystals |
topic | binary borate Czochralski method crystal composition thermal conductivity |
url | http://www.mdpi.com/2073-4352/7/3/88 |
work_keys_str_mv | AT lvgudzenko crystalgrowthandglasslikethermalconductivityofca3re2bo34reygdndsinglecrystals AT mbkosmyna crystalgrowthandglasslikethermalconductivityofca3re2bo34reygdndsinglecrystals AT anshekhovtsov crystalgrowthandglasslikethermalconductivityofca3re2bo34reygdndsinglecrystals AT wpaszkowicz crystalgrowthandglasslikethermalconductivityofca3re2bo34reygdndsinglecrystals AT asulich crystalgrowthandglasslikethermalconductivityofca3re2bo34reygdndsinglecrystals AT jzdomagała crystalgrowthandglasslikethermalconductivityofca3re2bo34reygdndsinglecrystals AT papopov crystalgrowthandglasslikethermalconductivityofca3re2bo34reygdndsinglecrystals AT saskrobov crystalgrowthandglasslikethermalconductivityofca3re2bo34reygdndsinglecrystals |