Combined Functionalization of Carbon Nanotubes (CNT) Fibers with H<sub>2</sub>SO<sub>4</sub>/HNO<sub>3</sub> and Ca(OH)<sub>2</sub> for Addition in Cementitious Matrix

Acid treatment is commonly used to improve the dispersion of carbon nanotubes (CNT) in a cementitious matrix, but it causes undesired delay on cement hydration kinetics. This work reports a combined CNT functionalization method with H<sub>2</sub>SO<sub>4</sub>/HNO<sub>3...

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Bibliographic Details
Main Authors: Eduardo Batiston, Paulo Ricardo de Matos, Philippe Jean Paul Gleize, Roman Fediuk, Sergey Klyuev, Nikolai Vatin, Maria Karelina
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Fibers
Subjects:
Online Access:https://www.mdpi.com/2079-6439/9/3/14
Description
Summary:Acid treatment is commonly used to improve the dispersion of carbon nanotubes (CNT) in a cementitious matrix, but it causes undesired delay on cement hydration kinetics. This work reports a combined CNT functionalization method with H<sub>2</sub>SO<sub>4</sub>/HNO<sub>3</sub> and Ca(OH)<sub>2</sub> for addition in a cementitious matrix. Results showed that the Ca(OH)<sub>2</sub> exposure neutralized the active sites generated by acid exposure, compensating the delay in hydration. As a result, CNT exposed to H<sub>2</sub>SO<sub>4</sub>/HNO<sub>3</sub> for 9 h and further Ca(OH)<sub>2</sub> treatment led to equivalent hydration kinetics than un-treated CNT did with improved stability.
ISSN:2079-6439