Effect of pH and Gas Flow Rate on Ozone Mass Transfer of Κ-Carrageenan Solution in Bubble Column Reactor

This research was conducted to calculate the mass transfer coefficient value for ozonation reaction of κ-carrageenan solution in the bubble column reactor. Ozone gas was produced using ozone generator type corona discharge. In this study, operating conditions were regulated at ozone gas flow rate 2-...

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Main Authors: Aji Prasetyaningrum, Dyah Arum Kusumaningtyas, Purbo Suseno, Ratnawati Ratnawati
Format: Article
Language:English
Published: Diponegoro University 2019-03-01
Series:Reaktor
Online Access:https://ejournal.undip.ac.id/index.php/reaktor/article/view/16112
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author Aji Prasetyaningrum
Dyah Arum Kusumaningtyas
Purbo Suseno
Ratnawati Ratnawati
author_facet Aji Prasetyaningrum
Dyah Arum Kusumaningtyas
Purbo Suseno
Ratnawati Ratnawati
author_sort Aji Prasetyaningrum
collection DOAJ
description This research was conducted to calculate the mass transfer coefficient value for ozonation reaction of κ-carrageenan solution in the bubble column reactor. Ozone gas was produced using ozone generator type corona discharge. In this study, operating conditions were regulated at ozone gas flow rate 2- 5 L min-1, pH 4-10, and temperature 29 ± 1 oC. Samples were tested every 5 minutes to determine the dissolved ozone concentration. The results showed that dissolved ozone concentrations increased with increasing ozonation time and ozone gas flow rate. However, a very high gas flow rate can increase turbulence so that the mass transfer coefficient (kLa) value decreased. In alkaline conditions, the formation of free radicals (HO*) increases so that the amount of dissolved ozone decreases. The kLa value of ozone gas in κ-carrageenan solution is slightly lower than the kLa value of the ozone gas in the water. The results of this study indicate that (kLa) ozone gas in water is 0.131 / minute while the value (kLa) in κ-carrageenan solution is 0.128 / minute. Keywords: ozone; mass transfer; pH; flowrate
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spelling doaj.art-2e917d012e1f488890553f086eba93cc2022-12-21T19:24:58ZengDiponegoro UniversityReaktor0852-07982407-59732019-03-01180417718210.14710/reaktor.18.04.177-18214373Effect of pH and Gas Flow Rate on Ozone Mass Transfer of Κ-Carrageenan Solution in Bubble Column ReactorAji Prasetyaningrum0Dyah Arum Kusumaningtyas1Purbo Suseno2Ratnawati Ratnawati3Diponegoro UniversityDiponegoro UniversityDiponegoro UniversityDiponegoro UniversityThis research was conducted to calculate the mass transfer coefficient value for ozonation reaction of κ-carrageenan solution in the bubble column reactor. Ozone gas was produced using ozone generator type corona discharge. In this study, operating conditions were regulated at ozone gas flow rate 2- 5 L min-1, pH 4-10, and temperature 29 ± 1 oC. Samples were tested every 5 minutes to determine the dissolved ozone concentration. The results showed that dissolved ozone concentrations increased with increasing ozonation time and ozone gas flow rate. However, a very high gas flow rate can increase turbulence so that the mass transfer coefficient (kLa) value decreased. In alkaline conditions, the formation of free radicals (HO*) increases so that the amount of dissolved ozone decreases. The kLa value of ozone gas in κ-carrageenan solution is slightly lower than the kLa value of the ozone gas in the water. The results of this study indicate that (kLa) ozone gas in water is 0.131 / minute while the value (kLa) in κ-carrageenan solution is 0.128 / minute. Keywords: ozone; mass transfer; pH; flowratehttps://ejournal.undip.ac.id/index.php/reaktor/article/view/16112
spellingShingle Aji Prasetyaningrum
Dyah Arum Kusumaningtyas
Purbo Suseno
Ratnawati Ratnawati
Effect of pH and Gas Flow Rate on Ozone Mass Transfer of Κ-Carrageenan Solution in Bubble Column Reactor
Reaktor
title Effect of pH and Gas Flow Rate on Ozone Mass Transfer of Κ-Carrageenan Solution in Bubble Column Reactor
title_full Effect of pH and Gas Flow Rate on Ozone Mass Transfer of Κ-Carrageenan Solution in Bubble Column Reactor
title_fullStr Effect of pH and Gas Flow Rate on Ozone Mass Transfer of Κ-Carrageenan Solution in Bubble Column Reactor
title_full_unstemmed Effect of pH and Gas Flow Rate on Ozone Mass Transfer of Κ-Carrageenan Solution in Bubble Column Reactor
title_short Effect of pH and Gas Flow Rate on Ozone Mass Transfer of Κ-Carrageenan Solution in Bubble Column Reactor
title_sort effect of ph and gas flow rate on ozone mass transfer of κ carrageenan solution in bubble column reactor
url https://ejournal.undip.ac.id/index.php/reaktor/article/view/16112
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AT dyaharumkusumaningtyas effectofphandgasflowrateonozonemasstransferofkcarrageenansolutioninbubblecolumnreactor
AT purbosuseno effectofphandgasflowrateonozonemasstransferofkcarrageenansolutioninbubblecolumnreactor
AT ratnawatiratnawati effectofphandgasflowrateonozonemasstransferofkcarrageenansolutioninbubblecolumnreactor