Phosphate Coatings: EIS and SEM Applied to Evaluate the Corrosion Behavior of Steel in Fire Extinguishing Solution

Phosphate coatings are one of the most important methods in preventing metal corrosion, especially iron alloys. The high interest in this method for industrial applications is mainly due to the low costs associated with the phosphating solution component and technological process. Considering this a...

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Main Authors: Diana-Petronela Burduhos-Nergis, Gabriel Dragos Vasilescu, Dumitru-Doru Burduhos-Nergis, Ramona Cimpoesu, Costica Bejinariu
Format: Article
Language:English
Published: MDPI AG 2021-08-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/11/17/7802
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author Diana-Petronela Burduhos-Nergis
Gabriel Dragos Vasilescu
Dumitru-Doru Burduhos-Nergis
Ramona Cimpoesu
Costica Bejinariu
author_facet Diana-Petronela Burduhos-Nergis
Gabriel Dragos Vasilescu
Dumitru-Doru Burduhos-Nergis
Ramona Cimpoesu
Costica Bejinariu
author_sort Diana-Petronela Burduhos-Nergis
collection DOAJ
description Phosphate coatings are one of the most important methods in preventing metal corrosion, especially iron alloys. The high interest in this method for industrial applications is mainly due to the low costs associated with the phosphating solution component and technological process. Considering this aspect and the advantages offered to the materials (corrosion resistance, good adhesion, wear resistance), this study evaluates the potential of using the phosphate coating method in health and safety applications. Therefore, the deposition of a layer of zinc phosphate on the steel surface used in the manufacture of components for personal protective equipment was approached. Firefighters, during rescue/evacuation operations, use protective equipment for fall arrest, whose accessories (hooks, carabiners) are made of steel. Due to the low corrosion resistance property of carbon steel, these accessories must be replaced frequently. This paper aims to analyze the possibility of improving the corrosion resistance of carbon steel in a fire extinguishing solution. Accordingly, the electrochemical behavior of two different types of coatings was studied by electrochemical impedance spectroscopy (EIS) and scanning electron microscope (SEM). In the literature, different corrosion evaluating methods or systems have been considered, and up until now, there has been no previous study to have approached the corrosive behavior of C45, phosphate C45, and painted phosphate C45 immersed in fire extinguishing solution.
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spelling doaj.art-2e9801a7086f4dc79fdbb489a46473de2023-11-22T10:16:38ZengMDPI AGApplied Sciences2076-34172021-08-011117780210.3390/app11177802Phosphate Coatings: EIS and SEM Applied to Evaluate the Corrosion Behavior of Steel in Fire Extinguishing SolutionDiana-Petronela Burduhos-Nergis0Gabriel Dragos Vasilescu1Dumitru-Doru Burduhos-Nergis2Ramona Cimpoesu3Costica Bejinariu4Faculty of Materials Science and Engineering, “Gheorghe Asachi” Technical University, 700050 Iasi, RomaniaNational Institute for Research and Development in Mine Safety and Protection to Explosion—INSEMEX, 332047 Petrosani, RomaniaFaculty of Materials Science and Engineering, “Gheorghe Asachi” Technical University, 700050 Iasi, RomaniaFaculty of Materials Science and Engineering, “Gheorghe Asachi” Technical University, 700050 Iasi, RomaniaFaculty of Materials Science and Engineering, “Gheorghe Asachi” Technical University, 700050 Iasi, RomaniaPhosphate coatings are one of the most important methods in preventing metal corrosion, especially iron alloys. The high interest in this method for industrial applications is mainly due to the low costs associated with the phosphating solution component and technological process. Considering this aspect and the advantages offered to the materials (corrosion resistance, good adhesion, wear resistance), this study evaluates the potential of using the phosphate coating method in health and safety applications. Therefore, the deposition of a layer of zinc phosphate on the steel surface used in the manufacture of components for personal protective equipment was approached. Firefighters, during rescue/evacuation operations, use protective equipment for fall arrest, whose accessories (hooks, carabiners) are made of steel. Due to the low corrosion resistance property of carbon steel, these accessories must be replaced frequently. This paper aims to analyze the possibility of improving the corrosion resistance of carbon steel in a fire extinguishing solution. Accordingly, the electrochemical behavior of two different types of coatings was studied by electrochemical impedance spectroscopy (EIS) and scanning electron microscope (SEM). In the literature, different corrosion evaluating methods or systems have been considered, and up until now, there has been no previous study to have approached the corrosive behavior of C45, phosphate C45, and painted phosphate C45 immersed in fire extinguishing solution.https://www.mdpi.com/2076-3417/11/17/7802fire extinguishing solutioncorrosion resistancezinc phosphateelectrochemical impedance spectroscopySEM
spellingShingle Diana-Petronela Burduhos-Nergis
Gabriel Dragos Vasilescu
Dumitru-Doru Burduhos-Nergis
Ramona Cimpoesu
Costica Bejinariu
Phosphate Coatings: EIS and SEM Applied to Evaluate the Corrosion Behavior of Steel in Fire Extinguishing Solution
Applied Sciences
fire extinguishing solution
corrosion resistance
zinc phosphate
electrochemical impedance spectroscopy
SEM
title Phosphate Coatings: EIS and SEM Applied to Evaluate the Corrosion Behavior of Steel in Fire Extinguishing Solution
title_full Phosphate Coatings: EIS and SEM Applied to Evaluate the Corrosion Behavior of Steel in Fire Extinguishing Solution
title_fullStr Phosphate Coatings: EIS and SEM Applied to Evaluate the Corrosion Behavior of Steel in Fire Extinguishing Solution
title_full_unstemmed Phosphate Coatings: EIS and SEM Applied to Evaluate the Corrosion Behavior of Steel in Fire Extinguishing Solution
title_short Phosphate Coatings: EIS and SEM Applied to Evaluate the Corrosion Behavior of Steel in Fire Extinguishing Solution
title_sort phosphate coatings eis and sem applied to evaluate the corrosion behavior of steel in fire extinguishing solution
topic fire extinguishing solution
corrosion resistance
zinc phosphate
electrochemical impedance spectroscopy
SEM
url https://www.mdpi.com/2076-3417/11/17/7802
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