Optimization of All-Polymer Optical Fiber Oxygen Sensors with Antenna Dyes and Improved Solvent Selection Using Hansen Solubility Parameters

We present an all-polymer optical fiber sensor for the sensing of dissolved oxygen by phase-fluorometry. The sensing matrix is applied as a film on the fiber end-surface, and consists of poly-methylmethacrylate (PMMA), the oxygen quenchable luminophore platinum-octaethylporphyrin (PtOEP) and the lum...

Full description

Bibliographic Details
Main Authors: Rune Inglev, Emil Møller, Jonas Højgaard, Ole Bang, Jakob Janting
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/21/1/5
_version_ 1797543902134140928
author Rune Inglev
Emil Møller
Jonas Højgaard
Ole Bang
Jakob Janting
author_facet Rune Inglev
Emil Møller
Jonas Højgaard
Ole Bang
Jakob Janting
author_sort Rune Inglev
collection DOAJ
description We present an all-polymer optical fiber sensor for the sensing of dissolved oxygen by phase-fluorometry. The sensing matrix is applied as a film on the fiber end-surface, and consists of poly-methylmethacrylate (PMMA), the oxygen quenchable luminophore platinum-octaethylporphyrin (PtOEP) and the luminophore coumarin 545T for increasing the brightness of PtOEP by way of resonance energy transfer (RET), also called light harvesting. We show that by using Hansen Solubility Parameters (HSPs), it is possible to quantitatively formulate a solvent mixture with a good solubility of the polymer matrix and the luminophores simultaneously. Our approach can readily be extended to other polymers and luminophores and is therefore a valuable tool for researchers working with photoluminescence and polymeric matrices.
first_indexed 2024-03-10T13:52:03Z
format Article
id doaj.art-2e9c0d1955484f13b36e901d7443617a
institution Directory Open Access Journal
issn 1424-8220
language English
last_indexed 2024-03-10T13:52:03Z
publishDate 2020-12-01
publisher MDPI AG
record_format Article
series Sensors
spelling doaj.art-2e9c0d1955484f13b36e901d7443617a2023-11-21T01:59:41ZengMDPI AGSensors1424-82202020-12-01211510.3390/s21010005Optimization of All-Polymer Optical Fiber Oxygen Sensors with Antenna Dyes and Improved Solvent Selection Using Hansen Solubility ParametersRune Inglev0Emil Møller1Jonas Højgaard2Ole Bang3Jakob Janting4Department of Photonics, Danish Technical University, Ørsteds Plads bldg. 343, 2800 Kongens Lyngby, DenmarkPisco Group, Rønnegade 1, 3. th., 2100 Copenhagen Ø, DenmarkPisco Group, Rønnegade 1, 3. th., 2100 Copenhagen Ø, DenmarkDepartment of Photonics, Danish Technical University, Ørsteds Plads bldg. 343, 2800 Kongens Lyngby, DenmarkDepartment of Photonics, Danish Technical University, Ørsteds Plads bldg. 343, 2800 Kongens Lyngby, DenmarkWe present an all-polymer optical fiber sensor for the sensing of dissolved oxygen by phase-fluorometry. The sensing matrix is applied as a film on the fiber end-surface, and consists of poly-methylmethacrylate (PMMA), the oxygen quenchable luminophore platinum-octaethylporphyrin (PtOEP) and the luminophore coumarin 545T for increasing the brightness of PtOEP by way of resonance energy transfer (RET), also called light harvesting. We show that by using Hansen Solubility Parameters (HSPs), it is possible to quantitatively formulate a solvent mixture with a good solubility of the polymer matrix and the luminophores simultaneously. Our approach can readily be extended to other polymers and luminophores and is therefore a valuable tool for researchers working with photoluminescence and polymeric matrices.https://www.mdpi.com/1424-8220/21/1/5polymer optical fibers (POF)photoluminescenceHansen Solubility Parameters (HSP)
spellingShingle Rune Inglev
Emil Møller
Jonas Højgaard
Ole Bang
Jakob Janting
Optimization of All-Polymer Optical Fiber Oxygen Sensors with Antenna Dyes and Improved Solvent Selection Using Hansen Solubility Parameters
Sensors
polymer optical fibers (POF)
photoluminescence
Hansen Solubility Parameters (HSP)
title Optimization of All-Polymer Optical Fiber Oxygen Sensors with Antenna Dyes and Improved Solvent Selection Using Hansen Solubility Parameters
title_full Optimization of All-Polymer Optical Fiber Oxygen Sensors with Antenna Dyes and Improved Solvent Selection Using Hansen Solubility Parameters
title_fullStr Optimization of All-Polymer Optical Fiber Oxygen Sensors with Antenna Dyes and Improved Solvent Selection Using Hansen Solubility Parameters
title_full_unstemmed Optimization of All-Polymer Optical Fiber Oxygen Sensors with Antenna Dyes and Improved Solvent Selection Using Hansen Solubility Parameters
title_short Optimization of All-Polymer Optical Fiber Oxygen Sensors with Antenna Dyes and Improved Solvent Selection Using Hansen Solubility Parameters
title_sort optimization of all polymer optical fiber oxygen sensors with antenna dyes and improved solvent selection using hansen solubility parameters
topic polymer optical fibers (POF)
photoluminescence
Hansen Solubility Parameters (HSP)
url https://www.mdpi.com/1424-8220/21/1/5
work_keys_str_mv AT runeinglev optimizationofallpolymeropticalfiberoxygensensorswithantennadyesandimprovedsolventselectionusinghansensolubilityparameters
AT emilmøller optimizationofallpolymeropticalfiberoxygensensorswithantennadyesandimprovedsolventselectionusinghansensolubilityparameters
AT jonashøjgaard optimizationofallpolymeropticalfiberoxygensensorswithantennadyesandimprovedsolventselectionusinghansensolubilityparameters
AT olebang optimizationofallpolymeropticalfiberoxygensensorswithantennadyesandimprovedsolventselectionusinghansensolubilityparameters
AT jakobjanting optimizationofallpolymeropticalfiberoxygensensorswithantennadyesandimprovedsolventselectionusinghansensolubilityparameters