Diacetonitrile(3-{2-[8-(2-bromoethoxy)-9,10-dioxoanthracen-1-yloxy]ethyl}-1-(2-pyridylmethyl)imidazolium)silver(I) bis(hexafluoridophosphate)
The title compound, [Ag(C27H23BrN3O4)(CH3CN)2](PF6)2, is a mononuclear salt species in which the silver(I) atom is coordinated by one ligand and two acetonitrile molecules and exhibits a distorted T-shaped coordination. The asymmetric unit contains one independent cation and two independent hexafluo...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810029739 |
| Summary: | The title compound, [Ag(C27H23BrN3O4)(CH3CN)2](PF6)2, is a mononuclear salt species in which the silver(I) atom is coordinated by one ligand and two acetonitrile molecules and exhibits a distorted T-shaped coordination. The asymmetric unit contains one independent cation and two independent hexafluoridophosphate anions, one of which is disordered over two positions in a 0.756 (11):0.244 (11) ratio. Weak π–π interactions between the anthraquinone ring systems [centroid–centroid distance = 3.676 (3) Å], intermolecular Ag–π interactions [Cg...Ag = 3.405 Å] and C—H...π interactions between pairs of adjacent molecules are observed. |
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| ISSN: | 1600-5368 |