Diacetonitrile(3-{2-[8-(2-bromoethoxy)-9,10-dioxoanthracen-1-yloxy]ethyl}-1-(2-pyridylmethyl)imidazolium)silver(I) bis(hexafluoridophosphate)
The title compound, [Ag(C27H23BrN3O4)(CH3CN)2](PF6)2, is a mononuclear salt species in which the silver(I) atom is coordinated by one ligand and two acetonitrile molecules and exhibits a distorted T-shaped coordination. The asymmetric unit contains one independent cation and two independent hexafluo...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810029739 |
| _version_ | 1819279707092287488 |
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| author | Qing-Song Wen Cheng-Lin Zhou Da-Bin Qin |
| author_facet | Qing-Song Wen Cheng-Lin Zhou Da-Bin Qin |
| author_sort | Qing-Song Wen |
| collection | DOAJ |
| description | The title compound, [Ag(C27H23BrN3O4)(CH3CN)2](PF6)2, is a mononuclear salt species in which the silver(I) atom is coordinated by one ligand and two acetonitrile molecules and exhibits a distorted T-shaped coordination. The asymmetric unit contains one independent cation and two independent hexafluoridophosphate anions, one of which is disordered over two positions in a 0.756 (11):0.244 (11) ratio. Weak π–π interactions between the anthraquinone ring systems [centroid–centroid distance = 3.676 (3) Å], intermolecular Ag–π interactions [Cg...Ag = 3.405 Å] and C—H...π interactions between pairs of adjacent molecules are observed. |
| first_indexed | 2024-12-24T00:32:10Z |
| format | Article |
| id | doaj.art-2ebb30821eb3467cb108fad4e7dd805f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:32:10Z |
| publishDate | 2010-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-2ebb30821eb3467cb108fad4e7dd805f2022-12-21T17:24:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m1030m103010.1107/S1600536810029739Diacetonitrile(3-{2-[8-(2-bromoethoxy)-9,10-dioxoanthracen-1-yloxy]ethyl}-1-(2-pyridylmethyl)imidazolium)silver(I) bis(hexafluoridophosphate)Qing-Song WenCheng-Lin ZhouDa-Bin QinThe title compound, [Ag(C27H23BrN3O4)(CH3CN)2](PF6)2, is a mononuclear salt species in which the silver(I) atom is coordinated by one ligand and two acetonitrile molecules and exhibits a distorted T-shaped coordination. The asymmetric unit contains one independent cation and two independent hexafluoridophosphate anions, one of which is disordered over two positions in a 0.756 (11):0.244 (11) ratio. Weak π–π interactions between the anthraquinone ring systems [centroid–centroid distance = 3.676 (3) Å], intermolecular Ag–π interactions [Cg...Ag = 3.405 Å] and C—H...π interactions between pairs of adjacent molecules are observed.http://scripts.iucr.org/cgi-bin/paper?S1600536810029739 |
| spellingShingle | Qing-Song Wen Cheng-Lin Zhou Da-Bin Qin Diacetonitrile(3-{2-[8-(2-bromoethoxy)-9,10-dioxoanthracen-1-yloxy]ethyl}-1-(2-pyridylmethyl)imidazolium)silver(I) bis(hexafluoridophosphate) Acta Crystallographica Section E |
| title | Diacetonitrile(3-{2-[8-(2-bromoethoxy)-9,10-dioxoanthracen-1-yloxy]ethyl}-1-(2-pyridylmethyl)imidazolium)silver(I) bis(hexafluoridophosphate) |
| title_full | Diacetonitrile(3-{2-[8-(2-bromoethoxy)-9,10-dioxoanthracen-1-yloxy]ethyl}-1-(2-pyridylmethyl)imidazolium)silver(I) bis(hexafluoridophosphate) |
| title_fullStr | Diacetonitrile(3-{2-[8-(2-bromoethoxy)-9,10-dioxoanthracen-1-yloxy]ethyl}-1-(2-pyridylmethyl)imidazolium)silver(I) bis(hexafluoridophosphate) |
| title_full_unstemmed | Diacetonitrile(3-{2-[8-(2-bromoethoxy)-9,10-dioxoanthracen-1-yloxy]ethyl}-1-(2-pyridylmethyl)imidazolium)silver(I) bis(hexafluoridophosphate) |
| title_short | Diacetonitrile(3-{2-[8-(2-bromoethoxy)-9,10-dioxoanthracen-1-yloxy]ethyl}-1-(2-pyridylmethyl)imidazolium)silver(I) bis(hexafluoridophosphate) |
| title_sort | diacetonitrile 3 2 8 2 bromoethoxy 9 10 dioxoanthracen 1 yloxy ethyl 1 2 pyridylmethyl imidazolium silver i bis hexafluoridophosphate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810029739 |
| work_keys_str_mv | AT qingsongwen diacetonitrile3282bromoethoxy910dioxoanthracen1yloxyethyl12pyridylmethylimidazoliumsilveribishexafluoridophosphate AT chenglinzhou diacetonitrile3282bromoethoxy910dioxoanthracen1yloxyethyl12pyridylmethylimidazoliumsilveribishexafluoridophosphate AT dabinqin diacetonitrile3282bromoethoxy910dioxoanthracen1yloxyethyl12pyridylmethylimidazoliumsilveribishexafluoridophosphate |