Impact of Humidity on Quartz-Enhanced Photoacoustic Spectroscopy Based CO Detection Using a Near-IR Telecommunication Diode Laser

A near-IR CO trace gas sensor based on quartz-enhanced photoacoustic spectroscopy (QEPAS) is evaluated using humidified nitrogen samples. Relaxation processes in the CO-N2-H2O system are investigated. A simple kinetic model is used to predict the sensor performance at different gas pressures. The re...

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Main Authors: Xukun Yin, Lei Dong, Huadan Zheng, Xiaoli Liu, Hongpeng Wu, Yanfang Yang, Weiguang Ma, Lei Zhang, Wangbao Yin, Liantuan Xiao, Suotang Jia
Format: Article
Language:English
Published: MDPI AG 2016-01-01
Series:Sensors
Subjects:
Online Access:http://www.mdpi.com/1424-8220/16/2/162
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author Xukun Yin
Lei Dong
Huadan Zheng
Xiaoli Liu
Hongpeng Wu
Yanfang Yang
Weiguang Ma
Lei Zhang
Wangbao Yin
Liantuan Xiao
Suotang Jia
author_facet Xukun Yin
Lei Dong
Huadan Zheng
Xiaoli Liu
Hongpeng Wu
Yanfang Yang
Weiguang Ma
Lei Zhang
Wangbao Yin
Liantuan Xiao
Suotang Jia
author_sort Xukun Yin
collection DOAJ
description A near-IR CO trace gas sensor based on quartz-enhanced photoacoustic spectroscopy (QEPAS) is evaluated using humidified nitrogen samples. Relaxation processes in the CO-N2-H2O system are investigated. A simple kinetic model is used to predict the sensor performance at different gas pressures. The results show that CO has a ~3 and ~5 times slower relaxation time constant than CH4 and HCN, respectively, under dry conditions. However, with the presence of water, its relaxation time constant can be improved by three orders of magnitude. The experimentally determined normalized detection sensitivity for CO in humid gas is 1.556 × 10 − 8   W ⋅ cm − 1 / Hz 1 / 2 .
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spelling doaj.art-2ed3a5d99c50448a95efc4751c32f42e2022-12-22T02:57:17ZengMDPI AGSensors1424-82202016-01-0116216210.3390/s16020162s16020162Impact of Humidity on Quartz-Enhanced Photoacoustic Spectroscopy Based CO Detection Using a Near-IR Telecommunication Diode LaserXukun Yin0Lei Dong1Huadan Zheng2Xiaoli Liu3Hongpeng Wu4Yanfang Yang5Weiguang Ma6Lei Zhang7Wangbao Yin8Liantuan Xiao9Suotang Jia10State Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, ChinaState Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, ChinaState Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, ChinaState Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, ChinaState Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, ChinaState Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, ChinaState Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, ChinaState Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, ChinaState Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, ChinaState Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, ChinaState Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, ChinaA near-IR CO trace gas sensor based on quartz-enhanced photoacoustic spectroscopy (QEPAS) is evaluated using humidified nitrogen samples. Relaxation processes in the CO-N2-H2O system are investigated. A simple kinetic model is used to predict the sensor performance at different gas pressures. The results show that CO has a ~3 and ~5 times slower relaxation time constant than CH4 and HCN, respectively, under dry conditions. However, with the presence of water, its relaxation time constant can be improved by three orders of magnitude. The experimentally determined normalized detection sensitivity for CO in humid gas is 1.556 × 10 − 8   W ⋅ cm − 1 / Hz 1 / 2 .http://www.mdpi.com/1424-8220/16/2/162quartz enhanced photoacoustic spectroscopycarbon monoxidevibrational-to-translational (V–T) relaxationnear-IR telecommunication diode laser
spellingShingle Xukun Yin
Lei Dong
Huadan Zheng
Xiaoli Liu
Hongpeng Wu
Yanfang Yang
Weiguang Ma
Lei Zhang
Wangbao Yin
Liantuan Xiao
Suotang Jia
Impact of Humidity on Quartz-Enhanced Photoacoustic Spectroscopy Based CO Detection Using a Near-IR Telecommunication Diode Laser
Sensors
quartz enhanced photoacoustic spectroscopy
carbon monoxide
vibrational-to-translational (V–T) relaxation
near-IR telecommunication diode laser
title Impact of Humidity on Quartz-Enhanced Photoacoustic Spectroscopy Based CO Detection Using a Near-IR Telecommunication Diode Laser
title_full Impact of Humidity on Quartz-Enhanced Photoacoustic Spectroscopy Based CO Detection Using a Near-IR Telecommunication Diode Laser
title_fullStr Impact of Humidity on Quartz-Enhanced Photoacoustic Spectroscopy Based CO Detection Using a Near-IR Telecommunication Diode Laser
title_full_unstemmed Impact of Humidity on Quartz-Enhanced Photoacoustic Spectroscopy Based CO Detection Using a Near-IR Telecommunication Diode Laser
title_short Impact of Humidity on Quartz-Enhanced Photoacoustic Spectroscopy Based CO Detection Using a Near-IR Telecommunication Diode Laser
title_sort impact of humidity on quartz enhanced photoacoustic spectroscopy based co detection using a near ir telecommunication diode laser
topic quartz enhanced photoacoustic spectroscopy
carbon monoxide
vibrational-to-translational (V–T) relaxation
near-IR telecommunication diode laser
url http://www.mdpi.com/1424-8220/16/2/162
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