Double Carbon Networks Reinforce the Thermal Storage and Thermal Transfer Properties of 1-Octadecanol Phase Change Materials

Using thermal storage materials with excellent thermal properties in the energy utilization system enables efficient use of renewable energy sources. Organic phase change materials (PCMs) have the advantages of high heat storage density, no corrosion, and low cost, but low thermal conductivity and i...

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Main Authors: Xiuli Wang, Qingmeng Wang, Xiaomin Cheng, Xiaolan Chen, Mingjun Bai
Format: Article
Language:English
Published: MDPI AG 2023-11-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/22/7067
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author Xiuli Wang
Qingmeng Wang
Xiaomin Cheng
Xiaolan Chen
Mingjun Bai
author_facet Xiuli Wang
Qingmeng Wang
Xiaomin Cheng
Xiaolan Chen
Mingjun Bai
author_sort Xiuli Wang
collection DOAJ
description Using thermal storage materials with excellent thermal properties in the energy utilization system enables efficient use of renewable energy sources. Organic phase change materials (PCMs) have the advantages of high heat storage density, no corrosion, and low cost, but low thermal conductivity and insufficient heat transfer capacity have always been the bottlenecks in their application. In this paper, melamine foam@ reduction graphene oxide (MF@rGO) and carbon foam@ reduction graphene oxide (CF@rGO) composite foams with double carbon networks were prepared by self-assembly method and further employed in 1-octadecinal (OD) PCMs. The microstructure, chemical composition, phase change behavior, thermal conductivity, and photothermal conversion performance of MF@rGO/OD and CF@rGO/OD were studied in detail using SEM, FTIR, Raman DSC, and LFA. The melting and solidification enthalpies of CF@rGO/OD composite PCMs were 208.3 J/g and 191.4 J/g, respectively, its thermal conductivity increased to 1.54 W/m·K, which is 6.42 times that of pure OD. The porous structure and high thermal conductivity of the double carbon network substantially enhance the efficiency of energy storage and release in composite PCMs. CF@rGO/OD composite PCMs have excellent heat storage performance and heat transfer capacity, and a wide range of application prospects in the fields of low-temperature solar heat storage, precision instrument temperature control, and intelligent buildings.
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spelling doaj.art-2ed737fa16e644ba9268c7354055c0742023-11-24T14:53:18ZengMDPI AGMaterials1996-19442023-11-011622706710.3390/ma16227067Double Carbon Networks Reinforce the Thermal Storage and Thermal Transfer Properties of 1-Octadecanol Phase Change MaterialsXiuli Wang0Qingmeng Wang1Xiaomin Cheng2Xiaolan Chen3Mingjun Bai4School of Mechatronics and Intelligent Manufacturing, Huanggang Normal University, Huanggang 438000, ChinaSchool of Mechatronics and Intelligent Manufacturing, Huanggang Normal University, Huanggang 438000, ChinaSchool of Mechatronics and Intelligent Manufacturing, Huanggang Normal University, Huanggang 438000, ChinaSchool of Mechatronics and Intelligent Manufacturing, Huanggang Normal University, Huanggang 438000, ChinaHubei Noble Vacuum Technology Co., Ltd., Huanggang 438000, ChinaUsing thermal storage materials with excellent thermal properties in the energy utilization system enables efficient use of renewable energy sources. Organic phase change materials (PCMs) have the advantages of high heat storage density, no corrosion, and low cost, but low thermal conductivity and insufficient heat transfer capacity have always been the bottlenecks in their application. In this paper, melamine foam@ reduction graphene oxide (MF@rGO) and carbon foam@ reduction graphene oxide (CF@rGO) composite foams with double carbon networks were prepared by self-assembly method and further employed in 1-octadecinal (OD) PCMs. The microstructure, chemical composition, phase change behavior, thermal conductivity, and photothermal conversion performance of MF@rGO/OD and CF@rGO/OD were studied in detail using SEM, FTIR, Raman DSC, and LFA. The melting and solidification enthalpies of CF@rGO/OD composite PCMs were 208.3 J/g and 191.4 J/g, respectively, its thermal conductivity increased to 1.54 W/m·K, which is 6.42 times that of pure OD. The porous structure and high thermal conductivity of the double carbon network substantially enhance the efficiency of energy storage and release in composite PCMs. CF@rGO/OD composite PCMs have excellent heat storage performance and heat transfer capacity, and a wide range of application prospects in the fields of low-temperature solar heat storage, precision instrument temperature control, and intelligent buildings.https://www.mdpi.com/1996-1944/16/22/7067double carbon network1-octadecanolphase change thermal storage materialsheat transfer efficiencyphotothermal conversion
spellingShingle Xiuli Wang
Qingmeng Wang
Xiaomin Cheng
Xiaolan Chen
Mingjun Bai
Double Carbon Networks Reinforce the Thermal Storage and Thermal Transfer Properties of 1-Octadecanol Phase Change Materials
Materials
double carbon network
1-octadecanol
phase change thermal storage materials
heat transfer efficiency
photothermal conversion
title Double Carbon Networks Reinforce the Thermal Storage and Thermal Transfer Properties of 1-Octadecanol Phase Change Materials
title_full Double Carbon Networks Reinforce the Thermal Storage and Thermal Transfer Properties of 1-Octadecanol Phase Change Materials
title_fullStr Double Carbon Networks Reinforce the Thermal Storage and Thermal Transfer Properties of 1-Octadecanol Phase Change Materials
title_full_unstemmed Double Carbon Networks Reinforce the Thermal Storage and Thermal Transfer Properties of 1-Octadecanol Phase Change Materials
title_short Double Carbon Networks Reinforce the Thermal Storage and Thermal Transfer Properties of 1-Octadecanol Phase Change Materials
title_sort double carbon networks reinforce the thermal storage and thermal transfer properties of 1 octadecanol phase change materials
topic double carbon network
1-octadecanol
phase change thermal storage materials
heat transfer efficiency
photothermal conversion
url https://www.mdpi.com/1996-1944/16/22/7067
work_keys_str_mv AT xiuliwang doublecarbonnetworksreinforcethethermalstorageandthermaltransferpropertiesof1octadecanolphasechangematerials
AT qingmengwang doublecarbonnetworksreinforcethethermalstorageandthermaltransferpropertiesof1octadecanolphasechangematerials
AT xiaomincheng doublecarbonnetworksreinforcethethermalstorageandthermaltransferpropertiesof1octadecanolphasechangematerials
AT xiaolanchen doublecarbonnetworksreinforcethethermalstorageandthermaltransferpropertiesof1octadecanolphasechangematerials
AT mingjunbai doublecarbonnetworksreinforcethethermalstorageandthermaltransferpropertiesof1octadecanolphasechangematerials