Double Carbon Networks Reinforce the Thermal Storage and Thermal Transfer Properties of 1-Octadecanol Phase Change Materials
Using thermal storage materials with excellent thermal properties in the energy utilization system enables efficient use of renewable energy sources. Organic phase change materials (PCMs) have the advantages of high heat storage density, no corrosion, and low cost, but low thermal conductivity and i...
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MDPI AG
2023-11-01
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Online Access: | https://www.mdpi.com/1996-1944/16/22/7067 |
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author | Xiuli Wang Qingmeng Wang Xiaomin Cheng Xiaolan Chen Mingjun Bai |
author_facet | Xiuli Wang Qingmeng Wang Xiaomin Cheng Xiaolan Chen Mingjun Bai |
author_sort | Xiuli Wang |
collection | DOAJ |
description | Using thermal storage materials with excellent thermal properties in the energy utilization system enables efficient use of renewable energy sources. Organic phase change materials (PCMs) have the advantages of high heat storage density, no corrosion, and low cost, but low thermal conductivity and insufficient heat transfer capacity have always been the bottlenecks in their application. In this paper, melamine foam@ reduction graphene oxide (MF@rGO) and carbon foam@ reduction graphene oxide (CF@rGO) composite foams with double carbon networks were prepared by self-assembly method and further employed in 1-octadecinal (OD) PCMs. The microstructure, chemical composition, phase change behavior, thermal conductivity, and photothermal conversion performance of MF@rGO/OD and CF@rGO/OD were studied in detail using SEM, FTIR, Raman DSC, and LFA. The melting and solidification enthalpies of CF@rGO/OD composite PCMs were 208.3 J/g and 191.4 J/g, respectively, its thermal conductivity increased to 1.54 W/m·K, which is 6.42 times that of pure OD. The porous structure and high thermal conductivity of the double carbon network substantially enhance the efficiency of energy storage and release in composite PCMs. CF@rGO/OD composite PCMs have excellent heat storage performance and heat transfer capacity, and a wide range of application prospects in the fields of low-temperature solar heat storage, precision instrument temperature control, and intelligent buildings. |
first_indexed | 2024-03-09T16:38:55Z |
format | Article |
id | doaj.art-2ed737fa16e644ba9268c7354055c074 |
institution | Directory Open Access Journal |
issn | 1996-1944 |
language | English |
last_indexed | 2024-03-09T16:38:55Z |
publishDate | 2023-11-01 |
publisher | MDPI AG |
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series | Materials |
spelling | doaj.art-2ed737fa16e644ba9268c7354055c0742023-11-24T14:53:18ZengMDPI AGMaterials1996-19442023-11-011622706710.3390/ma16227067Double Carbon Networks Reinforce the Thermal Storage and Thermal Transfer Properties of 1-Octadecanol Phase Change MaterialsXiuli Wang0Qingmeng Wang1Xiaomin Cheng2Xiaolan Chen3Mingjun Bai4School of Mechatronics and Intelligent Manufacturing, Huanggang Normal University, Huanggang 438000, ChinaSchool of Mechatronics and Intelligent Manufacturing, Huanggang Normal University, Huanggang 438000, ChinaSchool of Mechatronics and Intelligent Manufacturing, Huanggang Normal University, Huanggang 438000, ChinaSchool of Mechatronics and Intelligent Manufacturing, Huanggang Normal University, Huanggang 438000, ChinaHubei Noble Vacuum Technology Co., Ltd., Huanggang 438000, ChinaUsing thermal storage materials with excellent thermal properties in the energy utilization system enables efficient use of renewable energy sources. Organic phase change materials (PCMs) have the advantages of high heat storage density, no corrosion, and low cost, but low thermal conductivity and insufficient heat transfer capacity have always been the bottlenecks in their application. In this paper, melamine foam@ reduction graphene oxide (MF@rGO) and carbon foam@ reduction graphene oxide (CF@rGO) composite foams with double carbon networks were prepared by self-assembly method and further employed in 1-octadecinal (OD) PCMs. The microstructure, chemical composition, phase change behavior, thermal conductivity, and photothermal conversion performance of MF@rGO/OD and CF@rGO/OD were studied in detail using SEM, FTIR, Raman DSC, and LFA. The melting and solidification enthalpies of CF@rGO/OD composite PCMs were 208.3 J/g and 191.4 J/g, respectively, its thermal conductivity increased to 1.54 W/m·K, which is 6.42 times that of pure OD. The porous structure and high thermal conductivity of the double carbon network substantially enhance the efficiency of energy storage and release in composite PCMs. CF@rGO/OD composite PCMs have excellent heat storage performance and heat transfer capacity, and a wide range of application prospects in the fields of low-temperature solar heat storage, precision instrument temperature control, and intelligent buildings.https://www.mdpi.com/1996-1944/16/22/7067double carbon network1-octadecanolphase change thermal storage materialsheat transfer efficiencyphotothermal conversion |
spellingShingle | Xiuli Wang Qingmeng Wang Xiaomin Cheng Xiaolan Chen Mingjun Bai Double Carbon Networks Reinforce the Thermal Storage and Thermal Transfer Properties of 1-Octadecanol Phase Change Materials Materials double carbon network 1-octadecanol phase change thermal storage materials heat transfer efficiency photothermal conversion |
title | Double Carbon Networks Reinforce the Thermal Storage and Thermal Transfer Properties of 1-Octadecanol Phase Change Materials |
title_full | Double Carbon Networks Reinforce the Thermal Storage and Thermal Transfer Properties of 1-Octadecanol Phase Change Materials |
title_fullStr | Double Carbon Networks Reinforce the Thermal Storage and Thermal Transfer Properties of 1-Octadecanol Phase Change Materials |
title_full_unstemmed | Double Carbon Networks Reinforce the Thermal Storage and Thermal Transfer Properties of 1-Octadecanol Phase Change Materials |
title_short | Double Carbon Networks Reinforce the Thermal Storage and Thermal Transfer Properties of 1-Octadecanol Phase Change Materials |
title_sort | double carbon networks reinforce the thermal storage and thermal transfer properties of 1 octadecanol phase change materials |
topic | double carbon network 1-octadecanol phase change thermal storage materials heat transfer efficiency photothermal conversion |
url | https://www.mdpi.com/1996-1944/16/22/7067 |
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