Photovoltaic Wafering Silicon Kerf Loss as Raw Material: Example of Negative Electrode for Lithium‐Ion Battery**

Abstract Silicon powder kerf loss from diamond wire sawing in the photovoltaic wafering industry is a highly appealing source material for use in lithium‐ion battery negative electrodes. Here, it is demonstrated for the first time that the kerf particles from three independent sources contain ~50 %...

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Detalhes bibliográficos
Principais autores: Dr. Mads C. Heintz, Dr. Jekabs Grins, Dr. Aleksander Jaworski, Prof. Gunnar Svensson, Dr. Thomas Thersleff, Dr. William R. Brant, Dr. Rebecka Lindblad, Dr. Andrew J. Naylor, Prof. Kristina Edström, Dr. Guiomar Hernández
Formato: Artigo
Idioma:English
Publicado em: Wiley-VCH 2023-10-01
coleção:ChemElectroChem
Assuntos:
Acesso em linha:https://doi.org/10.1002/celc.202300331
Descrição
Resumo:Abstract Silicon powder kerf loss from diamond wire sawing in the photovoltaic wafering industry is a highly appealing source material for use in lithium‐ion battery negative electrodes. Here, it is demonstrated for the first time that the kerf particles from three independent sources contain ~50 % amorphous silicon. The crystalline phase is in the shape of nano‐scale crystalline inclusions in an amorphous matrix. From literature on wafering technology looking at wafer quality, the origin and mechanisms responsible for the amorphous content in the kerf loss powder are explained. In order to better understand for which applications the material could be a valuable raw material, the amorphicity and other relevant features are thoroughly investigated by a large amount of experimental methods. Furthermore, the kerf powder was crystallized and compared to the partly amorphous sample by operando X‐ray powder diffraction experiments during battery cycling, demonstrating that the powders are relevant for further investigation and development for battery applications.
ISSN:2196-0216