Surface Modification of Zinc Oxide by 3-aminopropyltiethoxysilane and a Comparative Study of Effect of Corrosion on Carbon Steel With Epoxy Containing Graphene Oxide-Zinc Oxide (GO-ZnO) Hybrids
The use of coupling agent, 3-aminopropyltiethoxysilane (APTES) in the silanization reaction with metal oxides plays an important role to ensure that additional chemical modification can successfully be achieved. Studies have shown that introducing metal oxides onto graphene oxide sheets can improve...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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EDP Sciences
2018-01-01
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| Series: | MATEC Web of Conferences |
| Online Access: | https://doi.org/10.1051/matecconf/201822501002 |
| _version_ | 1818873964402835456 |
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| author | Husna Othman Nurul Mazli Mustapha Mokhtar Che Ismail |
| author_facet | Husna Othman Nurul Mazli Mustapha Mokhtar Che Ismail |
| author_sort | Husna Othman Nurul |
| collection | DOAJ |
| description | The use of coupling agent, 3-aminopropyltiethoxysilane (APTES) in the silanization reaction with metal oxides plays an important role to ensure that additional chemical modification can successfully be achieved. Studies have shown that introducing metal oxides onto graphene oxide sheets can improve the dispersion of sheets in a polymeric matrix, contributing to its excellent anti-corrosion properties. Hence, two methods of APTES attachment has been explored, where the first method utilizes a reflux process to introduce siloxane bonds to the ZnO NP surface; the latter usesuse of ultrasonication to stimulate the functionalization of ZnO NPs. Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) were employed to characterize the APTES-Functionalized ZnO and the precipitation on the surface of GO sheets. The effect of GO-ZnO produced by the different types of functionalized ZnO on the corrosion protection and barrier performance of epoxy coating was investigated by electrochemical impedence spectroscopy (EIS). The results revealed that the long duration of reaction time provided by the reflux method managed to increase the number of siloxane bonds on the ZnO surface, allowing more amine groups to be attached onto the GO sheets and thus improve the corrosion resistance of epoxy. |
| first_indexed | 2024-12-19T13:03:04Z |
| format | Article |
| id | doaj.art-2f04b233136b484792a11988c2465b3f |
| institution | Directory Open Access Journal |
| issn | 2261-236X |
| language | English |
| last_indexed | 2024-12-19T13:03:04Z |
| publishDate | 2018-01-01 |
| publisher | EDP Sciences |
| record_format | Article |
| series | MATEC Web of Conferences |
| spelling | doaj.art-2f04b233136b484792a11988c2465b3f2022-12-21T20:20:10ZengEDP SciencesMATEC Web of Conferences2261-236X2018-01-012250100210.1051/matecconf/201822501002matecconf_ses2018_01002Surface Modification of Zinc Oxide by 3-aminopropyltiethoxysilane and a Comparative Study of Effect of Corrosion on Carbon Steel With Epoxy Containing Graphene Oxide-Zinc Oxide (GO-ZnO) HybridsHusna Othman NurulMazli MustaphaMokhtar Che IsmailThe use of coupling agent, 3-aminopropyltiethoxysilane (APTES) in the silanization reaction with metal oxides plays an important role to ensure that additional chemical modification can successfully be achieved. Studies have shown that introducing metal oxides onto graphene oxide sheets can improve the dispersion of sheets in a polymeric matrix, contributing to its excellent anti-corrosion properties. Hence, two methods of APTES attachment has been explored, where the first method utilizes a reflux process to introduce siloxane bonds to the ZnO NP surface; the latter usesuse of ultrasonication to stimulate the functionalization of ZnO NPs. Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) were employed to characterize the APTES-Functionalized ZnO and the precipitation on the surface of GO sheets. The effect of GO-ZnO produced by the different types of functionalized ZnO on the corrosion protection and barrier performance of epoxy coating was investigated by electrochemical impedence spectroscopy (EIS). The results revealed that the long duration of reaction time provided by the reflux method managed to increase the number of siloxane bonds on the ZnO surface, allowing more amine groups to be attached onto the GO sheets and thus improve the corrosion resistance of epoxy.https://doi.org/10.1051/matecconf/201822501002 |
| spellingShingle | Husna Othman Nurul Mazli Mustapha Mokhtar Che Ismail Surface Modification of Zinc Oxide by 3-aminopropyltiethoxysilane and a Comparative Study of Effect of Corrosion on Carbon Steel With Epoxy Containing Graphene Oxide-Zinc Oxide (GO-ZnO) Hybrids MATEC Web of Conferences |
| title | Surface Modification of Zinc Oxide by 3-aminopropyltiethoxysilane and a Comparative Study of Effect of Corrosion on Carbon Steel With Epoxy Containing Graphene Oxide-Zinc Oxide (GO-ZnO) Hybrids |
| title_full | Surface Modification of Zinc Oxide by 3-aminopropyltiethoxysilane and a Comparative Study of Effect of Corrosion on Carbon Steel With Epoxy Containing Graphene Oxide-Zinc Oxide (GO-ZnO) Hybrids |
| title_fullStr | Surface Modification of Zinc Oxide by 3-aminopropyltiethoxysilane and a Comparative Study of Effect of Corrosion on Carbon Steel With Epoxy Containing Graphene Oxide-Zinc Oxide (GO-ZnO) Hybrids |
| title_full_unstemmed | Surface Modification of Zinc Oxide by 3-aminopropyltiethoxysilane and a Comparative Study of Effect of Corrosion on Carbon Steel With Epoxy Containing Graphene Oxide-Zinc Oxide (GO-ZnO) Hybrids |
| title_short | Surface Modification of Zinc Oxide by 3-aminopropyltiethoxysilane and a Comparative Study of Effect of Corrosion on Carbon Steel With Epoxy Containing Graphene Oxide-Zinc Oxide (GO-ZnO) Hybrids |
| title_sort | surface modification of zinc oxide by 3 aminopropyltiethoxysilane and a comparative study of effect of corrosion on carbon steel with epoxy containing graphene oxide zinc oxide go zno hybrids |
| url | https://doi.org/10.1051/matecconf/201822501002 |
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