Screen-Printed Electrodes Modified with “Green” Metals for Electrochemical Stripping Analysis of Toxic Elements

This work reviews the field of screen-printed electrodes (SPEs) modified with “green” metals for electrochemical stripping analysis of toxic elements. Electrochemical stripping analysis has been established as a useful trace analysis technique offering many advantages compared to...

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Main Author: Anastasios Economou
Format: Article
Language:English
Published: MDPI AG 2018-03-01
Series:Sensors
Subjects:
Online Access:http://www.mdpi.com/1424-8220/18/4/1032
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author Anastasios Economou
author_facet Anastasios Economou
author_sort Anastasios Economou
collection DOAJ
description This work reviews the field of screen-printed electrodes (SPEs) modified with “green” metals for electrochemical stripping analysis of toxic elements. Electrochemical stripping analysis has been established as a useful trace analysis technique offering many advantages compared to competing optical techniques. Although mercury has been the preferred electrode material for stripping analysis, the toxicity of mercury and the associated legal requirements in its use and disposal have prompted research towards the development of “green” metals as alternative electrode materials. When combined with the screen-printing technology, such environment-friendly metals can lead to disposable sensors for trace metal analysis with excellent operational characteristics. This review focuses on SPEs modified with Au, Bi, Sb, and Sn for stripping analysis of toxic elements. Different modification approaches (electroplating, bulk modification, use of metal precursors, microengineering techniques) are considered and representative applications are described. A developing related field, namely biosensing based on stripping analysis of metallic nanoprobe labels, is also briefly mentioned.
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spelling doaj.art-2f113a1f6d5f4fe9ab22979222a460982022-12-22T02:20:10ZengMDPI AGSensors1424-82202018-03-01184103210.3390/s18041032s18041032Screen-Printed Electrodes Modified with “Green” Metals for Electrochemical Stripping Analysis of Toxic ElementsAnastasios Economou0Department of Chemistry, National and Kapodistrian University of Athens, Athens 157 71, GreeceThis work reviews the field of screen-printed electrodes (SPEs) modified with “green” metals for electrochemical stripping analysis of toxic elements. Electrochemical stripping analysis has been established as a useful trace analysis technique offering many advantages compared to competing optical techniques. Although mercury has been the preferred electrode material for stripping analysis, the toxicity of mercury and the associated legal requirements in its use and disposal have prompted research towards the development of “green” metals as alternative electrode materials. When combined with the screen-printing technology, such environment-friendly metals can lead to disposable sensors for trace metal analysis with excellent operational characteristics. This review focuses on SPEs modified with Au, Bi, Sb, and Sn for stripping analysis of toxic elements. Different modification approaches (electroplating, bulk modification, use of metal precursors, microengineering techniques) are considered and representative applications are described. A developing related field, namely biosensing based on stripping analysis of metallic nanoprobe labels, is also briefly mentioned.http://www.mdpi.com/1424-8220/18/4/1032screen-printed electrodes“green” metalsstripping analysistoxic elementsbismuthantimonytingold
spellingShingle Anastasios Economou
Screen-Printed Electrodes Modified with “Green” Metals for Electrochemical Stripping Analysis of Toxic Elements
Sensors
screen-printed electrodes
“green” metals
stripping analysis
toxic elements
bismuth
antimony
tin
gold
title Screen-Printed Electrodes Modified with “Green” Metals for Electrochemical Stripping Analysis of Toxic Elements
title_full Screen-Printed Electrodes Modified with “Green” Metals for Electrochemical Stripping Analysis of Toxic Elements
title_fullStr Screen-Printed Electrodes Modified with “Green” Metals for Electrochemical Stripping Analysis of Toxic Elements
title_full_unstemmed Screen-Printed Electrodes Modified with “Green” Metals for Electrochemical Stripping Analysis of Toxic Elements
title_short Screen-Printed Electrodes Modified with “Green” Metals for Electrochemical Stripping Analysis of Toxic Elements
title_sort screen printed electrodes modified with green metals for electrochemical stripping analysis of toxic elements
topic screen-printed electrodes
“green” metals
stripping analysis
toxic elements
bismuth
antimony
tin
gold
url http://www.mdpi.com/1424-8220/18/4/1032
work_keys_str_mv AT anastasioseconomou screenprintedelectrodesmodifiedwithgreenmetalsforelectrochemicalstrippinganalysisoftoxicelements