Study on the nonlinear viscoelastic behavior of rubber composites filled with silica
Silica-filled rubber composites exhibit nonlinear viscoelastic behavior depending on filler dispersion and matrix interaction. This study investigated the effects of silane treatment on dynamic mechanical properties of precipitated and fumed silica-reinforced polybutadiene rubber composites. The sil...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Elsevier
2024-06-01
|
Series: | Alexandria Engineering Journal |
Subjects: | |
Online Access: | http://www.sciencedirect.com/science/article/pii/S1110016824003260 |
_version_ | 1797203082808918016 |
---|---|
author | Pan Wang Peijin Liu Wen Ao |
author_facet | Pan Wang Peijin Liu Wen Ao |
author_sort | Pan Wang |
collection | DOAJ |
description | Silica-filled rubber composites exhibit nonlinear viscoelastic behavior depending on filler dispersion and matrix interaction. This study investigated the effects of silane treatment on dynamic mechanical properties of precipitated and fumed silica-reinforced polybutadiene rubber composites. The silane coupling agent improved filler dispersion and interfacial adhesion as characterized by microscopy and bound rubber content. Payne effect measurements showed enhanced storage modulus and network stability for silanized composites due to better filler networking. Cyclic tensile loading displayed reduced stress-softening in treated composites attributable to minimized damage formation. Modeling using Kraus and damage mechanics approaches provided quantitative correlations between the microstructure and magnitude of nonlinear response. The results demonstrate that silane treatment optimizes the viscoelastic performance of silica-filled rubber composites. |
first_indexed | 2024-04-24T08:13:41Z |
format | Article |
id | doaj.art-2f2a7ae80fbc42808003ca7ad61445b5 |
institution | Directory Open Access Journal |
issn | 1110-0168 |
language | English |
last_indexed | 2024-04-24T08:13:41Z |
publishDate | 2024-06-01 |
publisher | Elsevier |
record_format | Article |
series | Alexandria Engineering Journal |
spelling | doaj.art-2f2a7ae80fbc42808003ca7ad61445b52024-04-17T04:48:42ZengElsevierAlexandria Engineering Journal1110-01682024-06-019717Study on the nonlinear viscoelastic behavior of rubber composites filled with silicaPan Wang0Peijin Liu1Wen Ao2Corresponding author.; Science and Technology on Combustion, Internal Flow and Thermo-Structure Laboratory, Northwestern Polytechnical University, Xi’an, Shaanxi 710072, ChinaScience and Technology on Combustion, Internal Flow and Thermo-Structure Laboratory, Northwestern Polytechnical University, Xi’an, Shaanxi 710072, ChinaScience and Technology on Combustion, Internal Flow and Thermo-Structure Laboratory, Northwestern Polytechnical University, Xi’an, Shaanxi 710072, ChinaSilica-filled rubber composites exhibit nonlinear viscoelastic behavior depending on filler dispersion and matrix interaction. This study investigated the effects of silane treatment on dynamic mechanical properties of precipitated and fumed silica-reinforced polybutadiene rubber composites. The silane coupling agent improved filler dispersion and interfacial adhesion as characterized by microscopy and bound rubber content. Payne effect measurements showed enhanced storage modulus and network stability for silanized composites due to better filler networking. Cyclic tensile loading displayed reduced stress-softening in treated composites attributable to minimized damage formation. Modeling using Kraus and damage mechanics approaches provided quantitative correlations between the microstructure and magnitude of nonlinear response. The results demonstrate that silane treatment optimizes the viscoelastic performance of silica-filled rubber composites.http://www.sciencedirect.com/science/article/pii/S1110016824003260Silica-filled rubberSilane treatmentNonlinear viscoelasticityPayne effectMullins effectKraus model |
spellingShingle | Pan Wang Peijin Liu Wen Ao Study on the nonlinear viscoelastic behavior of rubber composites filled with silica Alexandria Engineering Journal Silica-filled rubber Silane treatment Nonlinear viscoelasticity Payne effect Mullins effect Kraus model |
title | Study on the nonlinear viscoelastic behavior of rubber composites filled with silica |
title_full | Study on the nonlinear viscoelastic behavior of rubber composites filled with silica |
title_fullStr | Study on the nonlinear viscoelastic behavior of rubber composites filled with silica |
title_full_unstemmed | Study on the nonlinear viscoelastic behavior of rubber composites filled with silica |
title_short | Study on the nonlinear viscoelastic behavior of rubber composites filled with silica |
title_sort | study on the nonlinear viscoelastic behavior of rubber composites filled with silica |
topic | Silica-filled rubber Silane treatment Nonlinear viscoelasticity Payne effect Mullins effect Kraus model |
url | http://www.sciencedirect.com/science/article/pii/S1110016824003260 |
work_keys_str_mv | AT panwang studyonthenonlinearviscoelasticbehaviorofrubbercompositesfilledwithsilica AT peijinliu studyonthenonlinearviscoelasticbehaviorofrubbercompositesfilledwithsilica AT wenao studyonthenonlinearviscoelasticbehaviorofrubbercompositesfilledwithsilica |