Study on the nonlinear viscoelastic behavior of rubber composites filled with silica

Silica-filled rubber composites exhibit nonlinear viscoelastic behavior depending on filler dispersion and matrix interaction. This study investigated the effects of silane treatment on dynamic mechanical properties of precipitated and fumed silica-reinforced polybutadiene rubber composites. The sil...

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Main Authors: Pan Wang, Peijin Liu, Wen Ao
Format: Article
Language:English
Published: Elsevier 2024-06-01
Series:Alexandria Engineering Journal
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1110016824003260
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author Pan Wang
Peijin Liu
Wen Ao
author_facet Pan Wang
Peijin Liu
Wen Ao
author_sort Pan Wang
collection DOAJ
description Silica-filled rubber composites exhibit nonlinear viscoelastic behavior depending on filler dispersion and matrix interaction. This study investigated the effects of silane treatment on dynamic mechanical properties of precipitated and fumed silica-reinforced polybutadiene rubber composites. The silane coupling agent improved filler dispersion and interfacial adhesion as characterized by microscopy and bound rubber content. Payne effect measurements showed enhanced storage modulus and network stability for silanized composites due to better filler networking. Cyclic tensile loading displayed reduced stress-softening in treated composites attributable to minimized damage formation. Modeling using Kraus and damage mechanics approaches provided quantitative correlations between the microstructure and magnitude of nonlinear response. The results demonstrate that silane treatment optimizes the viscoelastic performance of silica-filled rubber composites.
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spelling doaj.art-2f2a7ae80fbc42808003ca7ad61445b52024-04-17T04:48:42ZengElsevierAlexandria Engineering Journal1110-01682024-06-019717Study on the nonlinear viscoelastic behavior of rubber composites filled with silicaPan Wang0Peijin Liu1Wen Ao2Corresponding author.; Science and Technology on Combustion, Internal Flow and Thermo-Structure Laboratory, Northwestern Polytechnical University, Xi’an, Shaanxi 710072, ChinaScience and Technology on Combustion, Internal Flow and Thermo-Structure Laboratory, Northwestern Polytechnical University, Xi’an, Shaanxi 710072, ChinaScience and Technology on Combustion, Internal Flow and Thermo-Structure Laboratory, Northwestern Polytechnical University, Xi’an, Shaanxi 710072, ChinaSilica-filled rubber composites exhibit nonlinear viscoelastic behavior depending on filler dispersion and matrix interaction. This study investigated the effects of silane treatment on dynamic mechanical properties of precipitated and fumed silica-reinforced polybutadiene rubber composites. The silane coupling agent improved filler dispersion and interfacial adhesion as characterized by microscopy and bound rubber content. Payne effect measurements showed enhanced storage modulus and network stability for silanized composites due to better filler networking. Cyclic tensile loading displayed reduced stress-softening in treated composites attributable to minimized damage formation. Modeling using Kraus and damage mechanics approaches provided quantitative correlations between the microstructure and magnitude of nonlinear response. The results demonstrate that silane treatment optimizes the viscoelastic performance of silica-filled rubber composites.http://www.sciencedirect.com/science/article/pii/S1110016824003260Silica-filled rubberSilane treatmentNonlinear viscoelasticityPayne effectMullins effectKraus model
spellingShingle Pan Wang
Peijin Liu
Wen Ao
Study on the nonlinear viscoelastic behavior of rubber composites filled with silica
Alexandria Engineering Journal
Silica-filled rubber
Silane treatment
Nonlinear viscoelasticity
Payne effect
Mullins effect
Kraus model
title Study on the nonlinear viscoelastic behavior of rubber composites filled with silica
title_full Study on the nonlinear viscoelastic behavior of rubber composites filled with silica
title_fullStr Study on the nonlinear viscoelastic behavior of rubber composites filled with silica
title_full_unstemmed Study on the nonlinear viscoelastic behavior of rubber composites filled with silica
title_short Study on the nonlinear viscoelastic behavior of rubber composites filled with silica
title_sort study on the nonlinear viscoelastic behavior of rubber composites filled with silica
topic Silica-filled rubber
Silane treatment
Nonlinear viscoelasticity
Payne effect
Mullins effect
Kraus model
url http://www.sciencedirect.com/science/article/pii/S1110016824003260
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AT wenao studyonthenonlinearviscoelasticbehaviorofrubbercompositesfilledwithsilica