Using High-Power UV-LED to Accelerate a Decatungstate-Anion-Catalyzed Reaction: A Model Study for the Quick Oxidation of Benzyl Alcohol to Benzoic Acid Using Molecular Oxygen
High-power UV-LED irradiation (365 nm) effectively accelerated the decatungstate-anion-catalyzed oxidation of benzyl alcohol <b>1</b> to benzoic acid <b>3</b> via benzaldehyde <b>2</b>. As the power of the UV-LED light increased, both the selectivity and yield of...
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| Format: | Article |
| Language: | English |
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MDPI AG
2021-10-01
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| Series: | Micromachines |
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| Online Access: | https://www.mdpi.com/2072-666X/12/11/1307 |
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| author | Mamoru Hyodo Hitomi Iwano Takayoshi Kasakado Takahide Fukuyama Ilhyong Ryu |
| author_facet | Mamoru Hyodo Hitomi Iwano Takayoshi Kasakado Takahide Fukuyama Ilhyong Ryu |
| author_sort | Mamoru Hyodo |
| collection | DOAJ |
| description | High-power UV-LED irradiation (365 nm) effectively accelerated the decatungstate-anion-catalyzed oxidation of benzyl alcohol <b>1</b> to benzoic acid <b>3</b> via benzaldehyde <b>2</b>. As the power of the UV-LED light increased, both the selectivity and yield of benzoic acid also increased. The reaction was finished within 1 h to give <b>3</b> in a 93% yield using 2 mol% of decatungstate anion catalyst. The combination of a flow photoreactor and high-power irradiation accelerated the oxidation reaction to an interval of only a few minutes. |
| first_indexed | 2024-03-10T05:15:33Z |
| format | Article |
| id | doaj.art-2f35f3f201ed42ebb78e7112e50d2c6e |
| institution | Directory Open Access Journal |
| issn | 2072-666X |
| language | English |
| last_indexed | 2024-03-10T05:15:33Z |
| publishDate | 2021-10-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Micromachines |
| spelling | doaj.art-2f35f3f201ed42ebb78e7112e50d2c6e2023-11-23T00:25:33ZengMDPI AGMicromachines2072-666X2021-10-011211130710.3390/mi12111307Using High-Power UV-LED to Accelerate a Decatungstate-Anion-Catalyzed Reaction: A Model Study for the Quick Oxidation of Benzyl Alcohol to Benzoic Acid Using Molecular OxygenMamoru Hyodo0Hitomi Iwano1Takayoshi Kasakado2Takahide Fukuyama3Ilhyong Ryu4Organization for Research Promotion, Osaka Prefecture University, Sakai, Osaka 599-8531, JapanOrganization for Research Promotion, Osaka Prefecture University, Sakai, Osaka 599-8531, JapanOrganization for Research Promotion, Osaka Prefecture University, Sakai, Osaka 599-8531, JapanDepartment of Chemistry, Osaka Prefecture University, Sakai, Osaka 599-8531, JapanOrganization for Research Promotion, Osaka Prefecture University, Sakai, Osaka 599-8531, JapanHigh-power UV-LED irradiation (365 nm) effectively accelerated the decatungstate-anion-catalyzed oxidation of benzyl alcohol <b>1</b> to benzoic acid <b>3</b> via benzaldehyde <b>2</b>. As the power of the UV-LED light increased, both the selectivity and yield of benzoic acid also increased. The reaction was finished within 1 h to give <b>3</b> in a 93% yield using 2 mol% of decatungstate anion catalyst. The combination of a flow photoreactor and high-power irradiation accelerated the oxidation reaction to an interval of only a few minutes.https://www.mdpi.com/2072-666X/12/11/1307molecular oxygenoxidationhigh power UV-LEDbenzyl alcoholbenzoic acid |
| spellingShingle | Mamoru Hyodo Hitomi Iwano Takayoshi Kasakado Takahide Fukuyama Ilhyong Ryu Using High-Power UV-LED to Accelerate a Decatungstate-Anion-Catalyzed Reaction: A Model Study for the Quick Oxidation of Benzyl Alcohol to Benzoic Acid Using Molecular Oxygen Micromachines molecular oxygen oxidation high power UV-LED benzyl alcohol benzoic acid |
| title | Using High-Power UV-LED to Accelerate a Decatungstate-Anion-Catalyzed Reaction: A Model Study for the Quick Oxidation of Benzyl Alcohol to Benzoic Acid Using Molecular Oxygen |
| title_full | Using High-Power UV-LED to Accelerate a Decatungstate-Anion-Catalyzed Reaction: A Model Study for the Quick Oxidation of Benzyl Alcohol to Benzoic Acid Using Molecular Oxygen |
| title_fullStr | Using High-Power UV-LED to Accelerate a Decatungstate-Anion-Catalyzed Reaction: A Model Study for the Quick Oxidation of Benzyl Alcohol to Benzoic Acid Using Molecular Oxygen |
| title_full_unstemmed | Using High-Power UV-LED to Accelerate a Decatungstate-Anion-Catalyzed Reaction: A Model Study for the Quick Oxidation of Benzyl Alcohol to Benzoic Acid Using Molecular Oxygen |
| title_short | Using High-Power UV-LED to Accelerate a Decatungstate-Anion-Catalyzed Reaction: A Model Study for the Quick Oxidation of Benzyl Alcohol to Benzoic Acid Using Molecular Oxygen |
| title_sort | using high power uv led to accelerate a decatungstate anion catalyzed reaction a model study for the quick oxidation of benzyl alcohol to benzoic acid using molecular oxygen |
| topic | molecular oxygen oxidation high power UV-LED benzyl alcohol benzoic acid |
| url | https://www.mdpi.com/2072-666X/12/11/1307 |
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