Efficient Organic Light Emitting Diodes Using Solution-Processed Alkali Metal Carbonate Doped ZnO as Electron Injection Layer

In this study, we demonstrate highly efficient, inverted organic light-emitting diodes (IOLEDs) using solution-processed alkali metal carbonate doped ZnO as an electron injection layer (EIL) and tris-(8-hydroxyquinoline) aluminum (Alq3) as an emitter layer. In order to enhance the electron injection...

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Main Authors: Guo Chen, Feiyang Liu, Zhitian Ling, Pengpeng Zhang, Bin Wei, Wenqing Zhu
Format: Article
Language:English
Published: Frontiers Media S.A. 2019-04-01
Series:Frontiers in Chemistry
Subjects:
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2019.00226/full
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author Guo Chen
Feiyang Liu
Zhitian Ling
Pengpeng Zhang
Bin Wei
Wenqing Zhu
author_facet Guo Chen
Feiyang Liu
Zhitian Ling
Pengpeng Zhang
Bin Wei
Wenqing Zhu
author_sort Guo Chen
collection DOAJ
description In this study, we demonstrate highly efficient, inverted organic light-emitting diodes (IOLEDs) using solution-processed alkali metal carbonate doped ZnO as an electron injection layer (EIL) and tris-(8-hydroxyquinoline) aluminum (Alq3) as an emitter layer. In order to enhance the electron injection efficiency of the IOLEDs, the ZnO EIL layers were modified by doping various alkali metal carbonate materials, including Li2CO3, Na2CO3, K2CO3, and Cs2CO3, using the low-temperature wet-chemical method. Compared to the control neat ZnO EIL-based IOLEDs, the alkali metal carbonate doped ZnO EIL-based IOLEDs possess obviously improved device performance. An optimal current efficiency of 6.04 cd A−1 were realized from the K2CO3 doped ZnO EIL based IOLED, which is 54% improved compared to that of the neat ZnO EIL based device. The enhancement is ascribed to the increased electron mobility and reduced barrier height for more efficient electron injection. Our results indicate that alkali metal carbonate doped ZnO has promising potential for application in highly efficient solution-processed OLEDs.
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spelling doaj.art-2f4f5fed7c6d4c66b1764fb99d2907bb2022-12-22T03:09:52ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462019-04-01710.3389/fchem.2019.00226451779Efficient Organic Light Emitting Diodes Using Solution-Processed Alkali Metal Carbonate Doped ZnO as Electron Injection LayerGuo ChenFeiyang LiuZhitian LingPengpeng ZhangBin WeiWenqing ZhuIn this study, we demonstrate highly efficient, inverted organic light-emitting diodes (IOLEDs) using solution-processed alkali metal carbonate doped ZnO as an electron injection layer (EIL) and tris-(8-hydroxyquinoline) aluminum (Alq3) as an emitter layer. In order to enhance the electron injection efficiency of the IOLEDs, the ZnO EIL layers were modified by doping various alkali metal carbonate materials, including Li2CO3, Na2CO3, K2CO3, and Cs2CO3, using the low-temperature wet-chemical method. Compared to the control neat ZnO EIL-based IOLEDs, the alkali metal carbonate doped ZnO EIL-based IOLEDs possess obviously improved device performance. An optimal current efficiency of 6.04 cd A−1 were realized from the K2CO3 doped ZnO EIL based IOLED, which is 54% improved compared to that of the neat ZnO EIL based device. The enhancement is ascribed to the increased electron mobility and reduced barrier height for more efficient electron injection. Our results indicate that alkali metal carbonate doped ZnO has promising potential for application in highly efficient solution-processed OLEDs.https://www.frontiersin.org/article/10.3389/fchem.2019.00226/fullorganic light emitting diodes (OLED)solution processelectron injection layerdoped ZnOalkali metal carbonate
spellingShingle Guo Chen
Feiyang Liu
Zhitian Ling
Pengpeng Zhang
Bin Wei
Wenqing Zhu
Efficient Organic Light Emitting Diodes Using Solution-Processed Alkali Metal Carbonate Doped ZnO as Electron Injection Layer
Frontiers in Chemistry
organic light emitting diodes (OLED)
solution process
electron injection layer
doped ZnO
alkali metal carbonate
title Efficient Organic Light Emitting Diodes Using Solution-Processed Alkali Metal Carbonate Doped ZnO as Electron Injection Layer
title_full Efficient Organic Light Emitting Diodes Using Solution-Processed Alkali Metal Carbonate Doped ZnO as Electron Injection Layer
title_fullStr Efficient Organic Light Emitting Diodes Using Solution-Processed Alkali Metal Carbonate Doped ZnO as Electron Injection Layer
title_full_unstemmed Efficient Organic Light Emitting Diodes Using Solution-Processed Alkali Metal Carbonate Doped ZnO as Electron Injection Layer
title_short Efficient Organic Light Emitting Diodes Using Solution-Processed Alkali Metal Carbonate Doped ZnO as Electron Injection Layer
title_sort efficient organic light emitting diodes using solution processed alkali metal carbonate doped zno as electron injection layer
topic organic light emitting diodes (OLED)
solution process
electron injection layer
doped ZnO
alkali metal carbonate
url https://www.frontiersin.org/article/10.3389/fchem.2019.00226/full
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