Sorption of 2-Chlorophenol from aqueous solutions by functionalized cross-linked polymers

This manuscript describes the synthesis of three polymers based on styrene (STY), divinylbenzene (DVB) and two different vinyl monomers: methyl methacrylate (MMA) and acrylonitrile (AN). The STY-DVB, STY-DVB-MMA and STY-DVB-AN polymers were synthesized employing the aqueous suspension technique. Rea...

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Main Authors: Rodrigo Martins Fráguas, Alcino Palermo de Aguiar, Angela Cristina Jandrey
Format: Article
Language:English
Published: Associação Brasileira de Polímeros 2013-01-01
Series:Polímeros
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282013000600008&lng=en&tlng=en
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author Rodrigo Martins Fráguas
Alcino Palermo de Aguiar
Angela Cristina Jandrey
author_facet Rodrigo Martins Fráguas
Alcino Palermo de Aguiar
Angela Cristina Jandrey
author_sort Rodrigo Martins Fráguas
collection DOAJ
description This manuscript describes the synthesis of three polymers based on styrene (STY), divinylbenzene (DVB) and two different vinyl monomers: methyl methacrylate (MMA) and acrylonitrile (AN). The STY-DVB, STY-DVB-MMA and STY-DVB-AN polymers were synthesized employing the aqueous suspension technique. Reaction yields were 73%, 81% and 75%, respectively. They were morphological and chemically characterized using different techniques. The extraction capacity of the polymers was evaluated using 2-chlorophenol. The polymer extraction capacities were evaluated varying contact time the (1 h, 3 h and 5 h), temperature (30 °C, 35 °C and 40 °C), and pH (3, 5.6 and 8). The STY-DVB-AN polymer was the most efficient; it removed around 95% of the analyte using a contact time 50 h.
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spelling doaj.art-2f509fcaf402479ead85b070f19e80fb2022-12-22T02:47:16ZengAssociação Brasileira de PolímerosPolímeros1678-51692013-01-0123673874210.4322/polimeros.2014.002S0104-14282013000600008Sorption of 2-Chlorophenol from aqueous solutions by functionalized cross-linked polymersRodrigo Martins Fráguas0Alcino Palermo de Aguiar1Angela Cristina Jandrey2Instituto Militar de EngenhariaInstituto Militar de EngenhariaSouza Cruz S.AThis manuscript describes the synthesis of three polymers based on styrene (STY), divinylbenzene (DVB) and two different vinyl monomers: methyl methacrylate (MMA) and acrylonitrile (AN). The STY-DVB, STY-DVB-MMA and STY-DVB-AN polymers were synthesized employing the aqueous suspension technique. Reaction yields were 73%, 81% and 75%, respectively. They were morphological and chemically characterized using different techniques. The extraction capacity of the polymers was evaluated using 2-chlorophenol. The polymer extraction capacities were evaluated varying contact time the (1 h, 3 h and 5 h), temperature (30 °C, 35 °C and 40 °C), and pH (3, 5.6 and 8). The STY-DVB-AN polymer was the most efficient; it removed around 95% of the analyte using a contact time 50 h.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282013000600008&lng=en&tlng=en2-chlorophenolpolymerextraction
spellingShingle Rodrigo Martins Fráguas
Alcino Palermo de Aguiar
Angela Cristina Jandrey
Sorption of 2-Chlorophenol from aqueous solutions by functionalized cross-linked polymers
Polímeros
2-chlorophenol
polymer
extraction
title Sorption of 2-Chlorophenol from aqueous solutions by functionalized cross-linked polymers
title_full Sorption of 2-Chlorophenol from aqueous solutions by functionalized cross-linked polymers
title_fullStr Sorption of 2-Chlorophenol from aqueous solutions by functionalized cross-linked polymers
title_full_unstemmed Sorption of 2-Chlorophenol from aqueous solutions by functionalized cross-linked polymers
title_short Sorption of 2-Chlorophenol from aqueous solutions by functionalized cross-linked polymers
title_sort sorption of 2 chlorophenol from aqueous solutions by functionalized cross linked polymers
topic 2-chlorophenol
polymer
extraction
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282013000600008&lng=en&tlng=en
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AT alcinopalermodeaguiar sorptionof2chlorophenolfromaqueoussolutionsbyfunctionalizedcrosslinkedpolymers
AT angelacristinajandrey sorptionof2chlorophenolfromaqueoussolutionsbyfunctionalizedcrosslinkedpolymers