Effect of nitrogen content on grain boundary engineering and corrosion resistance of 316LN stainless steel

Nitrogen solid solution can effectively enhance the strength of steels, but its effect on grain boundary engineering and the corrosion mechanism of steels is still unclear and systematic investigation is needed. In this study, 316LN steel specimens with five nitrogen concentrations were melted and s...

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Main Authors: Yong Wang, Zhenhua Wang, Wei Wang, Minggui Qu
Format: Article
Language:English
Published: Elsevier 2024-03-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785424004332
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author Yong Wang
Zhenhua Wang
Wei Wang
Minggui Qu
author_facet Yong Wang
Zhenhua Wang
Wei Wang
Minggui Qu
author_sort Yong Wang
collection DOAJ
description Nitrogen solid solution can effectively enhance the strength of steels, but its effect on grain boundary engineering and the corrosion mechanism of steels is still unclear and systematic investigation is needed. In this study, 316LN steel specimens with five nitrogen concentrations were melted and subjected to compression and annealing. The grain boundary character distribution was investigated by electron backscatter diffraction. The corrosion behavior was investigated by the electrochemical polarization curves, electrical impedance spectroscopy, and X-ray photoelectron spectroscopy. The results showed that nitrogen promotes the formation of low-Σ boundaries when the pre-strain is not above 10%. The polarization resistance increases with increasing nitrogen content. The quantitative relationship between the nitrogen content and the pitting potential was obtained. Nitrogen favors the formation of oxides, hydroxides, and NH3/NH4+ on the passivated surface. The effect of planar slip on grain boundary engineering and the influence of NH4+ on the corrosion resistance are discussed.
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spelling doaj.art-2f7bb3ea18ca480d831bef85ea49ce402024-03-24T06:58:28ZengElsevierJournal of Materials Research and Technology2238-78542024-03-012939763989Effect of nitrogen content on grain boundary engineering and corrosion resistance of 316LN stainless steelYong Wang0Zhenhua Wang1Wei Wang2Minggui Qu3School of Mechanical Engineering, Yanshan University, Qinhuangdao, 066004, ChinaSchool of Mechanical Engineering, Yanshan University, Qinhuangdao, 066004, China; State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao, 066004, China; Corresponding author. School of Mechanical Engineering, Yanshan University, Qinhuangdao, 066004, China.State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao, 066004, ChinaShenzhen Research Institute of Yanshan University, Shenzhen, 518057, ChinaNitrogen solid solution can effectively enhance the strength of steels, but its effect on grain boundary engineering and the corrosion mechanism of steels is still unclear and systematic investigation is needed. In this study, 316LN steel specimens with five nitrogen concentrations were melted and subjected to compression and annealing. The grain boundary character distribution was investigated by electron backscatter diffraction. The corrosion behavior was investigated by the electrochemical polarization curves, electrical impedance spectroscopy, and X-ray photoelectron spectroscopy. The results showed that nitrogen promotes the formation of low-Σ boundaries when the pre-strain is not above 10%. The polarization resistance increases with increasing nitrogen content. The quantitative relationship between the nitrogen content and the pitting potential was obtained. Nitrogen favors the formation of oxides, hydroxides, and NH3/NH4+ on the passivated surface. The effect of planar slip on grain boundary engineering and the influence of NH4+ on the corrosion resistance are discussed.http://www.sciencedirect.com/science/article/pii/S2238785424004332316LN stainless steelElectron backscatter diffractionGrain boundary engineeringPlanar slipPitting
spellingShingle Yong Wang
Zhenhua Wang
Wei Wang
Minggui Qu
Effect of nitrogen content on grain boundary engineering and corrosion resistance of 316LN stainless steel
Journal of Materials Research and Technology
316LN stainless steel
Electron backscatter diffraction
Grain boundary engineering
Planar slip
Pitting
title Effect of nitrogen content on grain boundary engineering and corrosion resistance of 316LN stainless steel
title_full Effect of nitrogen content on grain boundary engineering and corrosion resistance of 316LN stainless steel
title_fullStr Effect of nitrogen content on grain boundary engineering and corrosion resistance of 316LN stainless steel
title_full_unstemmed Effect of nitrogen content on grain boundary engineering and corrosion resistance of 316LN stainless steel
title_short Effect of nitrogen content on grain boundary engineering and corrosion resistance of 316LN stainless steel
title_sort effect of nitrogen content on grain boundary engineering and corrosion resistance of 316ln stainless steel
topic 316LN stainless steel
Electron backscatter diffraction
Grain boundary engineering
Planar slip
Pitting
url http://www.sciencedirect.com/science/article/pii/S2238785424004332
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AT zhenhuawang effectofnitrogencontentongrainboundaryengineeringandcorrosionresistanceof316lnstainlesssteel
AT weiwang effectofnitrogencontentongrainboundaryengineeringandcorrosionresistanceof316lnstainlesssteel
AT mingguiqu effectofnitrogencontentongrainboundaryengineeringandcorrosionresistanceof316lnstainlesssteel