catena-Poly[[bis[aqua(1,10-phenanthroline)lead(II)]-bis(μ3-2-hydroxy-5-sulfonatobenzoato)] acetic acid monosolvate]
In the title compound, [Pb2(C7H4O6S)2(C12H8N2)2(H2O)2]·CH3COOH, the seven-coordinate PbII atom is chelated by two N atoms of one 1,10-phenanthroline ligand, four O atoms from three 5-sulfosalicylate dianions and one water O atom. Each dianion serves as a bridging ligand, connecting adja...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681202421X |
| _version_ | 1818321398880272384 |
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| author | Yuan-Zheng Cheng Wei-Wei Shi Xue-Dong Wang Shu-E Deng Li-Ping Zhang |
| author_facet | Yuan-Zheng Cheng Wei-Wei Shi Xue-Dong Wang Shu-E Deng Li-Ping Zhang |
| author_sort | Yuan-Zheng Cheng |
| collection | DOAJ |
| description | In the title compound, [Pb2(C7H4O6S)2(C12H8N2)2(H2O)2]·CH3COOH, the seven-coordinate PbII atom is chelated by two N atoms of one 1,10-phenanthroline ligand, four O atoms from three 5-sulfosalicylate dianions and one water O atom. Each dianion serves as a bridging ligand, connecting adjacent PbII atoms into a centrosymmetric polymeric chain extending parallel to [001]. There are π–π interactions between the aromatic systems of neighbouring dianions, with plane-to-plane distances of 3.371 (2) Å, and between phenanthroline ligands, with a centroid-to-centroid distance of 3.484 (2) Å. O—H...O hydrogen bonding additionally stabilizes the crystal packing. The acetic acid molecules are incorporated in the voids of this arrangement. They exhibit half-occupancy due to disorder around a centre of inversion. |
| first_indexed | 2024-12-13T10:40:17Z |
| format | Article |
| id | doaj.art-2f850f077c06479581978bc4e014bbdd |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:40:17Z |
| publishDate | 2012-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-2f850f077c06479581978bc4e014bbdd2022-12-21T23:50:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m878m87910.1107/S160053681202421Xcatena-Poly[[bis[aqua(1,10-phenanthroline)lead(II)]-bis(μ3-2-hydroxy-5-sulfonatobenzoato)] acetic acid monosolvate]Yuan-Zheng ChengWei-Wei ShiXue-Dong WangShu-E DengLi-Ping ZhangIn the title compound, [Pb2(C7H4O6S)2(C12H8N2)2(H2O)2]·CH3COOH, the seven-coordinate PbII atom is chelated by two N atoms of one 1,10-phenanthroline ligand, four O atoms from three 5-sulfosalicylate dianions and one water O atom. Each dianion serves as a bridging ligand, connecting adjacent PbII atoms into a centrosymmetric polymeric chain extending parallel to [001]. There are π–π interactions between the aromatic systems of neighbouring dianions, with plane-to-plane distances of 3.371 (2) Å, and between phenanthroline ligands, with a centroid-to-centroid distance of 3.484 (2) Å. O—H...O hydrogen bonding additionally stabilizes the crystal packing. The acetic acid molecules are incorporated in the voids of this arrangement. They exhibit half-occupancy due to disorder around a centre of inversion.http://scripts.iucr.org/cgi-bin/paper?S160053681202421X |
| spellingShingle | Yuan-Zheng Cheng Wei-Wei Shi Xue-Dong Wang Shu-E Deng Li-Ping Zhang catena-Poly[[bis[aqua(1,10-phenanthroline)lead(II)]-bis(μ3-2-hydroxy-5-sulfonatobenzoato)] acetic acid monosolvate] Acta Crystallographica Section E |
| title | catena-Poly[[bis[aqua(1,10-phenanthroline)lead(II)]-bis(μ3-2-hydroxy-5-sulfonatobenzoato)] acetic acid monosolvate] |
| title_full | catena-Poly[[bis[aqua(1,10-phenanthroline)lead(II)]-bis(μ3-2-hydroxy-5-sulfonatobenzoato)] acetic acid monosolvate] |
| title_fullStr | catena-Poly[[bis[aqua(1,10-phenanthroline)lead(II)]-bis(μ3-2-hydroxy-5-sulfonatobenzoato)] acetic acid monosolvate] |
| title_full_unstemmed | catena-Poly[[bis[aqua(1,10-phenanthroline)lead(II)]-bis(μ3-2-hydroxy-5-sulfonatobenzoato)] acetic acid monosolvate] |
| title_short | catena-Poly[[bis[aqua(1,10-phenanthroline)lead(II)]-bis(μ3-2-hydroxy-5-sulfonatobenzoato)] acetic acid monosolvate] |
| title_sort | catena poly bis aqua 1 10 phenanthroline lead ii bis amp 956 3 2 hydroxy 5 sulfonatobenzoato acetic acid monosolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681202421X |
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