Impact of Initial Cyclic Loading on Mechanical Properties and Performance of Nafion

Nafion possesses many interesting properties such as a high ion-conductivity, hydrophilicity, and thermal and chemical stability that make this material highly suitable for many applications including fuel cells and various (bio-)chemical and physical sensors. However, the mechanical properties of a...

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Main Authors: David Vokoun, Sneha Samal, Ivo Stachiv
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/23/3/1488
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author David Vokoun
Sneha Samal
Ivo Stachiv
author_facet David Vokoun
Sneha Samal
Ivo Stachiv
author_sort David Vokoun
collection DOAJ
description Nafion possesses many interesting properties such as a high ion-conductivity, hydrophilicity, and thermal and chemical stability that make this material highly suitable for many applications including fuel cells and various (bio-)chemical and physical sensors. However, the mechanical properties of a Nafion membrane that are known to be affected by the viscoplastic characteristics of the material itself have a strong impact on the performance of Nafion-based sensors. In this study, the mechanical properties of Nafion under the cyclic loading have been investigated in detail. After cyclic tensile loading (i.e., maximum elongation about 25% at a room temperature and relative humidity about 40%) a time-dependent recovery comes into play. This recovery process is also shown being strain-rate dependent. Our results reveal that the recovery behavior weakens after performing several stress–strain cycles. Present findings can be of a great importance in future design of various chemical and biological microsensors and nanosensors such as hydrogen or glucose ones.
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spelling doaj.art-2f8a6f083f9349e3a3b6e2224fa6babb2023-11-16T18:01:47ZengMDPI AGSensors1424-82202023-01-01233148810.3390/s23031488Impact of Initial Cyclic Loading on Mechanical Properties and Performance of NafionDavid Vokoun0Sneha Samal1Ivo Stachiv2Department of Functional Materials, Institute of Physics, Czech Academy of Sciences, Na Slovance 2, 18221 Prague, Czech RepublicDepartment of Functional Materials, Institute of Physics, Czech Academy of Sciences, Na Slovance 2, 18221 Prague, Czech RepublicDepartment of Functional Materials, Institute of Physics, Czech Academy of Sciences, Na Slovance 2, 18221 Prague, Czech RepublicNafion possesses many interesting properties such as a high ion-conductivity, hydrophilicity, and thermal and chemical stability that make this material highly suitable for many applications including fuel cells and various (bio-)chemical and physical sensors. However, the mechanical properties of a Nafion membrane that are known to be affected by the viscoplastic characteristics of the material itself have a strong impact on the performance of Nafion-based sensors. In this study, the mechanical properties of Nafion under the cyclic loading have been investigated in detail. After cyclic tensile loading (i.e., maximum elongation about 25% at a room temperature and relative humidity about 40%) a time-dependent recovery comes into play. This recovery process is also shown being strain-rate dependent. Our results reveal that the recovery behavior weakens after performing several stress–strain cycles. Present findings can be of a great importance in future design of various chemical and biological microsensors and nanosensors such as hydrogen or glucose ones.https://www.mdpi.com/1424-8220/23/3/1488Nafionmechanical testsviscoplastic propertiescyclic loadingmechanical properties
spellingShingle David Vokoun
Sneha Samal
Ivo Stachiv
Impact of Initial Cyclic Loading on Mechanical Properties and Performance of Nafion
Sensors
Nafion
mechanical tests
viscoplastic properties
cyclic loading
mechanical properties
title Impact of Initial Cyclic Loading on Mechanical Properties and Performance of Nafion
title_full Impact of Initial Cyclic Loading on Mechanical Properties and Performance of Nafion
title_fullStr Impact of Initial Cyclic Loading on Mechanical Properties and Performance of Nafion
title_full_unstemmed Impact of Initial Cyclic Loading on Mechanical Properties and Performance of Nafion
title_short Impact of Initial Cyclic Loading on Mechanical Properties and Performance of Nafion
title_sort impact of initial cyclic loading on mechanical properties and performance of nafion
topic Nafion
mechanical tests
viscoplastic properties
cyclic loading
mechanical properties
url https://www.mdpi.com/1424-8220/23/3/1488
work_keys_str_mv AT davidvokoun impactofinitialcyclicloadingonmechanicalpropertiesandperformanceofnafion
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