Synthesis and structural characterization of a dimeric N,N-dimethylformamide solvate of isobutyltin(IV) dichloride hydroxide, [iBuSnCl2(OH)(DMF)]2
The title compound, isobutyltin(IV) dichloride hydroxide N,N-dimethylformamide solvate {[iBuSnCl2(OH)(DMF)]2}, an accidental side product from the reaction of isobutyltin(IV) trichloride with moisture in N,N-dimethylformamide, exhibits structural features similar to those of the corresponding hydrat...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2013-12-01
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| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc-2013-0037 |
| Summary: | The title compound, isobutyltin(IV) dichloride hydroxide N,N-dimethylformamide solvate {[iBuSnCl2(OH)(DMF)]2}, an accidental side product from the reaction of isobutyltin(IV) trichloride with moisture in N,N-dimethylformamide, exhibits structural features similar to those of the corresponding hydrates of monoorganotin(IV) dihalide hydroxides characterized by a central four-membered rhombic Sn-O ring and tin atoms with a distorted octahedral coordination. |
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| ISSN: | 0792-1241 2191-0219 |