Synthesis and structural characterization of a dimeric N,N-dimethylformamide solvate of isobutyltin(IV) dichloride hydroxide, [iBuSnCl2(OH)(DMF)]2
The title compound, isobutyltin(IV) dichloride hydroxide N,N-dimethylformamide solvate {[iBuSnCl2(OH)(DMF)]2}, an accidental side product from the reaction of isobutyltin(IV) trichloride with moisture in N,N-dimethylformamide, exhibits structural features similar to those of the corresponding hydrat...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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De Gruyter
2013-12-01
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| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc-2013-0037 |
| _version_ | 1819019397879037952 |
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| author | Reuter Hans Ye Fei |
| author_facet | Reuter Hans Ye Fei |
| author_sort | Reuter Hans |
| collection | DOAJ |
| description | The title compound, isobutyltin(IV) dichloride hydroxide N,N-dimethylformamide solvate {[iBuSnCl2(OH)(DMF)]2}, an accidental side product from the reaction of isobutyltin(IV) trichloride with moisture in N,N-dimethylformamide, exhibits structural features similar to those of the corresponding hydrates of monoorganotin(IV) dihalide hydroxides characterized by a central four-membered rhombic Sn-O ring and tin atoms with a distorted octahedral coordination. |
| first_indexed | 2024-12-21T03:34:40Z |
| format | Article |
| id | doaj.art-2f930dbce2f34b078483ce1bcdf8ff47 |
| institution | Directory Open Access Journal |
| issn | 0792-1241 2191-0219 |
| language | English |
| last_indexed | 2024-12-21T03:34:40Z |
| publishDate | 2013-12-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Main Group Metal Chemistry |
| spelling | doaj.art-2f930dbce2f34b078483ce1bcdf8ff472022-12-21T19:17:23ZengDe GruyterMain Group Metal Chemistry0792-12412191-02192013-12-01365-622522710.1515/mgmc-2013-0037Synthesis and structural characterization of a dimeric N,N-dimethylformamide solvate of isobutyltin(IV) dichloride hydroxide, [iBuSnCl2(OH)(DMF)]2Reuter Hans0Ye Fei1Institut für Chemie neuer Materialien, Universität Osnabrück, D-49069 Osnabrück, GermanyInstitut für Chemie neuer Materialien, Universität Osnabrück, D-49069 Osnabrück, GermanyThe title compound, isobutyltin(IV) dichloride hydroxide N,N-dimethylformamide solvate {[iBuSnCl2(OH)(DMF)]2}, an accidental side product from the reaction of isobutyltin(IV) trichloride with moisture in N,N-dimethylformamide, exhibits structural features similar to those of the corresponding hydrates of monoorganotin(IV) dihalide hydroxides characterized by a central four-membered rhombic Sn-O ring and tin atoms with a distorted octahedral coordination.https://doi.org/10.1515/mgmc-2013-0037crystal structureorganotin compoundssynthesis |
| spellingShingle | Reuter Hans Ye Fei Synthesis and structural characterization of a dimeric N,N-dimethylformamide solvate of isobutyltin(IV) dichloride hydroxide, [iBuSnCl2(OH)(DMF)]2 Main Group Metal Chemistry crystal structure organotin compounds synthesis |
| title | Synthesis and structural characterization of a dimeric N,N-dimethylformamide solvate of isobutyltin(IV) dichloride hydroxide, [iBuSnCl2(OH)(DMF)]2 |
| title_full | Synthesis and structural characterization of a dimeric N,N-dimethylformamide solvate of isobutyltin(IV) dichloride hydroxide, [iBuSnCl2(OH)(DMF)]2 |
| title_fullStr | Synthesis and structural characterization of a dimeric N,N-dimethylformamide solvate of isobutyltin(IV) dichloride hydroxide, [iBuSnCl2(OH)(DMF)]2 |
| title_full_unstemmed | Synthesis and structural characterization of a dimeric N,N-dimethylformamide solvate of isobutyltin(IV) dichloride hydroxide, [iBuSnCl2(OH)(DMF)]2 |
| title_short | Synthesis and structural characterization of a dimeric N,N-dimethylformamide solvate of isobutyltin(IV) dichloride hydroxide, [iBuSnCl2(OH)(DMF)]2 |
| title_sort | synthesis and structural characterization of a dimeric n n dimethylformamide solvate of isobutyltin iv dichloride hydroxide ibusncl2 oh dmf 2 |
| topic | crystal structure organotin compounds synthesis |
| url | https://doi.org/10.1515/mgmc-2013-0037 |
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