High efficiency bifacial Cu2ZnSnSe4 thin-film solar cells on transparent conducting oxide glass substrates

In this work, transparent conducting oxides (TCOs) have been employed as a back contact instead of Mo on Cu2ZnSnSe4 (CZTSe) thin-film solar cells in order to examine the feasibility of bifacial Cu2ZnSn(S,Se)4 (CZTSSe) solar cells based on a vacuum process. It is found that the interfacial reaction b...

Full description

Bibliographic Details
Main Authors: Jung-Sik Kim, Jin-Kyu Kang, Dae-Kue Hwang
Format: Article
Language:English
Published: AIP Publishing LLC 2016-09-01
Series:APL Materials
Online Access:http://dx.doi.org/10.1063/1.4962145
_version_ 1818417268107771904
author Jung-Sik Kim
Jin-Kyu Kang
Dae-Kue Hwang
author_facet Jung-Sik Kim
Jin-Kyu Kang
Dae-Kue Hwang
author_sort Jung-Sik Kim
collection DOAJ
description In this work, transparent conducting oxides (TCOs) have been employed as a back contact instead of Mo on Cu2ZnSnSe4 (CZTSe) thin-film solar cells in order to examine the feasibility of bifacial Cu2ZnSn(S,Se)4 (CZTSSe) solar cells based on a vacuum process. It is found that the interfacial reaction between flourine doped tin oxide (FTO) or indium tin oxide (ITO) and the CZTSe precursor is at odds with the conventional CZTSe/Mo reaction. While there is no interfacial reaction on CZTSe/FTO, indium in CZTSe/ITO was significantly diffused into the CZTSe layers; consequently, a SnO2 layer was formed on the ITO substrate. Under bifacial illumination, we achieved a power efficiency of 6.05% and 4.31% for CZTSe/FTO and CZTSe/ITO, respectively.
first_indexed 2024-12-14T12:04:05Z
format Article
id doaj.art-2f99075253a346feb0c99e3e6e13463f
institution Directory Open Access Journal
issn 2166-532X
language English
last_indexed 2024-12-14T12:04:05Z
publishDate 2016-09-01
publisher AIP Publishing LLC
record_format Article
series APL Materials
spelling doaj.art-2f99075253a346feb0c99e3e6e13463f2022-12-21T23:01:54ZengAIP Publishing LLCAPL Materials2166-532X2016-09-0149096101096101-610.1063/1.4962145002609APMHigh efficiency bifacial Cu2ZnSnSe4 thin-film solar cells on transparent conducting oxide glass substratesJung-Sik Kim0Jin-Kyu Kang1Dae-Kue Hwang2Convergence Research Center for Solar Energy, Daegu Gyeongbuk Institute of Science and Technology (DGIST), 333 Techno Jungang-daero, Dalsung-gun, Daegu 711-873, South KoreaConvergence Research Center for Solar Energy, Daegu Gyeongbuk Institute of Science and Technology (DGIST), 333 Techno Jungang-daero, Dalsung-gun, Daegu 711-873, South KoreaConvergence Research Center for Solar Energy, Daegu Gyeongbuk Institute of Science and Technology (DGIST), 333 Techno Jungang-daero, Dalsung-gun, Daegu 711-873, South KoreaIn this work, transparent conducting oxides (TCOs) have been employed as a back contact instead of Mo on Cu2ZnSnSe4 (CZTSe) thin-film solar cells in order to examine the feasibility of bifacial Cu2ZnSn(S,Se)4 (CZTSSe) solar cells based on a vacuum process. It is found that the interfacial reaction between flourine doped tin oxide (FTO) or indium tin oxide (ITO) and the CZTSe precursor is at odds with the conventional CZTSe/Mo reaction. While there is no interfacial reaction on CZTSe/FTO, indium in CZTSe/ITO was significantly diffused into the CZTSe layers; consequently, a SnO2 layer was formed on the ITO substrate. Under bifacial illumination, we achieved a power efficiency of 6.05% and 4.31% for CZTSe/FTO and CZTSe/ITO, respectively.http://dx.doi.org/10.1063/1.4962145
spellingShingle Jung-Sik Kim
Jin-Kyu Kang
Dae-Kue Hwang
High efficiency bifacial Cu2ZnSnSe4 thin-film solar cells on transparent conducting oxide glass substrates
APL Materials
title High efficiency bifacial Cu2ZnSnSe4 thin-film solar cells on transparent conducting oxide glass substrates
title_full High efficiency bifacial Cu2ZnSnSe4 thin-film solar cells on transparent conducting oxide glass substrates
title_fullStr High efficiency bifacial Cu2ZnSnSe4 thin-film solar cells on transparent conducting oxide glass substrates
title_full_unstemmed High efficiency bifacial Cu2ZnSnSe4 thin-film solar cells on transparent conducting oxide glass substrates
title_short High efficiency bifacial Cu2ZnSnSe4 thin-film solar cells on transparent conducting oxide glass substrates
title_sort high efficiency bifacial cu2znsnse4 thin film solar cells on transparent conducting oxide glass substrates
url http://dx.doi.org/10.1063/1.4962145
work_keys_str_mv AT jungsikkim highefficiencybifacialcu2znsnse4thinfilmsolarcellsontransparentconductingoxideglasssubstrates
AT jinkyukang highefficiencybifacialcu2znsnse4thinfilmsolarcellsontransparentconductingoxideglasssubstrates
AT daekuehwang highefficiencybifacialcu2znsnse4thinfilmsolarcellsontransparentconductingoxideglasssubstrates