Chemical composition and photochemical reactivity of exhaust from aircraft turbine engines

Assessment of the environmental impact of aircraft emissions is required by planners and policy makers. Seveal areas of concern are: 1. exposure of airport workers and urban residents to toxic chemicals emitted when the engines operate at low power (idle and taxi) on the ground; 2. contributions to...

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Main Authors: T. F. Lyon, R. M. Riggin, M. W. Holdren, C. W. Spicer
Format: Article
Language:English
Published: Copernicus Publications
Series:Annales Geophysicae
Online Access:http://www.ann-geophys.net/12/944/1994/angeo-12-944-1994.html
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author T. F. Lyon
R. M. Riggin
M. W. Holdren
C. W. Spicer
author_facet T. F. Lyon
R. M. Riggin
M. W. Holdren
C. W. Spicer
author_sort T. F. Lyon
collection DOAJ
description Assessment of the environmental impact of aircraft emissions is required by planners and policy makers. Seveal areas of concern are: 1. exposure of airport workers and urban residents to toxic chemicals emitted when the engines operate at low power (idle and taxi) on the ground; 2. contributions to urban photochemical air pollution of aircraft volatile organic and nitrogen oxides emissions from operations around airports; and 3. emissions of nitrogen oxides and particles during high-altitude operation. The environmental impact of chemicals emitted from jet aircraft turbine engines has not been firmly established due to lack of data regarding emission rates and identities of the compounds emitted. This paper describes an experimental study of two different aircraft turbine engines designed to determine detailed organic emissions, as well as emissions of inorganic gases. Emissions were measured at several engine power settings. Measurements were made of detailed organic composition from C<sub>1</sub> through C<sub>17</sub>, CO, CO<sub>2</sub>, NO, NO<sub><i>x</i></sub>, and polycyclic aromatic hydrocarbons. Measurements were made using a multi-port sampling pro be positioned directly behind the engine in the exhaust exit plane. The emission measurements have been used to determine the organic distribution by carbon number and the distribution by compound class at each engine power level. The sum of the organic species was compared with an independent measurement of total organic carbon to assess the carbon mass balance. A portion of the exhaust was captured and irradiated in outdoor smog chambers to assess the photochemical reactivity of the emissions with respect to ozone formation. The reactivity of emissions from the two engines was apportioned by chemical compound class.
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spelling doaj.art-2fa766d56b0c4e0f808d225a95332d8e2022-12-22T02:41:17ZengCopernicus PublicationsAnnales Geophysicae0992-76891432-05761210/11944955Chemical composition and photochemical reactivity of exhaust from aircraft turbine enginesT. F. LyonR. M. RigginM. W. HoldrenC. W. SpicerAssessment of the environmental impact of aircraft emissions is required by planners and policy makers. Seveal areas of concern are: 1. exposure of airport workers and urban residents to toxic chemicals emitted when the engines operate at low power (idle and taxi) on the ground; 2. contributions to urban photochemical air pollution of aircraft volatile organic and nitrogen oxides emissions from operations around airports; and 3. emissions of nitrogen oxides and particles during high-altitude operation. The environmental impact of chemicals emitted from jet aircraft turbine engines has not been firmly established due to lack of data regarding emission rates and identities of the compounds emitted. This paper describes an experimental study of two different aircraft turbine engines designed to determine detailed organic emissions, as well as emissions of inorganic gases. Emissions were measured at several engine power settings. Measurements were made of detailed organic composition from C<sub>1</sub> through C<sub>17</sub>, CO, CO<sub>2</sub>, NO, NO<sub><i>x</i></sub>, and polycyclic aromatic hydrocarbons. Measurements were made using a multi-port sampling pro be positioned directly behind the engine in the exhaust exit plane. The emission measurements have been used to determine the organic distribution by carbon number and the distribution by compound class at each engine power level. The sum of the organic species was compared with an independent measurement of total organic carbon to assess the carbon mass balance. A portion of the exhaust was captured and irradiated in outdoor smog chambers to assess the photochemical reactivity of the emissions with respect to ozone formation. The reactivity of emissions from the two engines was apportioned by chemical compound class.http://www.ann-geophys.net/12/944/1994/angeo-12-944-1994.html
spellingShingle T. F. Lyon
R. M. Riggin
M. W. Holdren
C. W. Spicer
Chemical composition and photochemical reactivity of exhaust from aircraft turbine engines
Annales Geophysicae
title Chemical composition and photochemical reactivity of exhaust from aircraft turbine engines
title_full Chemical composition and photochemical reactivity of exhaust from aircraft turbine engines
title_fullStr Chemical composition and photochemical reactivity of exhaust from aircraft turbine engines
title_full_unstemmed Chemical composition and photochemical reactivity of exhaust from aircraft turbine engines
title_short Chemical composition and photochemical reactivity of exhaust from aircraft turbine engines
title_sort chemical composition and photochemical reactivity of exhaust from aircraft turbine engines
url http://www.ann-geophys.net/12/944/1994/angeo-12-944-1994.html
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AT cwspicer chemicalcompositionandphotochemicalreactivityofexhaustfromaircraftturbineengines