The effects of acetylation on properties of flax fibre and its polypropylene composites

Flax fibre was modified with acetylation. The influence of the acetylation on the structure and properties of flax fibre were investigated as well as modified flax fibre reinforced polypropylene composites were also prepared. The catalyst was used to accelerate acetylation reaction rate. Flax fibre...

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Format: Article
Language:English
Published: Budapest University of Technology 2008-06-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0000609&mi=cd
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collection DOAJ
description Flax fibre was modified with acetylation. The influence of the acetylation on the structure and properties of flax fibre were investigated as well as modified flax fibre reinforced polypropylene composites were also prepared. The catalyst was used to accelerate acetylation reaction rate. Flax fibre was characterised after modification. Surface morphology, moisture absorption property, components content, degree of polymerisation, crystallinity of cellulose and thermal stability of flax fibres were studied. Due to acetylation, the flax fibre surface morphology and moisture resistance properties improved remarkably. Flax fibre (modified and unmodified) reinforced polypropylene composites were fabricated with 30 wt% fibre loading. The mechanical properties were investigated for those composites. Tensile and flexural strengths of composites were found to increase with increasing degree of acetylation up to 18% and then decreased. Charpy impact strengths of composites were found to decrease with increasing degree of acetylation. Owing to addition of coupling agent (maleated polypropylene -MAH), the tensile and flexural strength properties were found to increase in between 20 to 35% depending on degree of acetylation.
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spelling doaj.art-2fba0a96658843b2a3ed68e2166041932022-12-22T02:50:56ZengBudapest University of TechnologyeXPRESS Polymer Letters1788-618X2008-06-012641342210.3144/expresspolymlett.2008.50The effects of acetylation on properties of flax fibre and its polypropylene compositesFlax fibre was modified with acetylation. The influence of the acetylation on the structure and properties of flax fibre were investigated as well as modified flax fibre reinforced polypropylene composites were also prepared. The catalyst was used to accelerate acetylation reaction rate. Flax fibre was characterised after modification. Surface morphology, moisture absorption property, components content, degree of polymerisation, crystallinity of cellulose and thermal stability of flax fibres were studied. Due to acetylation, the flax fibre surface morphology and moisture resistance properties improved remarkably. Flax fibre (modified and unmodified) reinforced polypropylene composites were fabricated with 30 wt% fibre loading. The mechanical properties were investigated for those composites. Tensile and flexural strengths of composites were found to increase with increasing degree of acetylation up to 18% and then decreased. Charpy impact strengths of composites were found to decrease with increasing degree of acetylation. Owing to addition of coupling agent (maleated polypropylene -MAH), the tensile and flexural strength properties were found to increase in between 20 to 35% depending on degree of acetylation.http://www.expresspolymlett.com/letolt.php?file=EPL-0000609&mi=cdReinforcementsMechanical propertiesflax fibreacetylationfibre characterisation
spellingShingle The effects of acetylation on properties of flax fibre and its polypropylene composites
eXPRESS Polymer Letters
Reinforcements
Mechanical properties
flax fibre
acetylation
fibre characterisation
title The effects of acetylation on properties of flax fibre and its polypropylene composites
title_full The effects of acetylation on properties of flax fibre and its polypropylene composites
title_fullStr The effects of acetylation on properties of flax fibre and its polypropylene composites
title_full_unstemmed The effects of acetylation on properties of flax fibre and its polypropylene composites
title_short The effects of acetylation on properties of flax fibre and its polypropylene composites
title_sort effects of acetylation on properties of flax fibre and its polypropylene composites
topic Reinforcements
Mechanical properties
flax fibre
acetylation
fibre characterisation
url http://www.expresspolymlett.com/letolt.php?file=EPL-0000609&mi=cd